This page summarizes the optical absorption and emission data of TBP-meso-tetra(4-COOMe-phenyl)-Pd that
is available in the PhotochemCAD
package, version 2.1a (Du 1998, Dixon 2005). I reworked their data to
produce these interactive graphs and to provide direct links to text files
containing the raw and manipulated data. Although I have tried to be careful, I
may have introduced some errors; the cautious user is advised to compare these
results with the original sources.
You can resize any of the graphs by clicking and dragging a rectangle. If you hover the mouse over the graph, you will see a pop-up showing the coordinates. One of the icons in the upper right corner will let you export the graph in other formats.
Absorption
This optical absorption measurement of TBP-meso-tetra(4-COOMe-phenyl)-Pd were made by O. Finikova on 10-16-2004 using a PerkinElmer Lambda 35.
These measurements were scaled to make the molar extinction coefficient match the value of 240,000cm-1/M at 443.0nm (Finikova, 2004).
Original Data | Extinction Data
Fluorescence
The fluorescence emission spectrum of TBP-meso-tetra(4-COOMe-phenyl)-Pd dissolved in DMF. The quantum yield of this molecule is 0.05 (Finikova, 2004). This spectrum was collected by on 10-16-2004 using a Fluorolog-2,R2658P.
Notes
See (Finikova, 2004) for photophysical properties of tetrabenzoporphyrins.References
Dixon, J. M., M. Taniguchi and J. S. Lindsey (2005), "PhotochemCAD 2. A Refined Program with Accompanying Spectral Databases for Photochemical Calculations, Photochem. Photobiol., 81, 212-213.
Du, H., R.-C. A. Fuh, J. Li, L. A. Corkan and J. S. Lindsey (1998) PhotochemCAD: A computer-aided design and research tool in photochemistry. Photochem. Photobiol. 68, 141-142.
Finikova, O. S., A. V. Cheprakov, I. P. Beletskaya, P. J. Carroll and S. A. Vinogradov (2004) Novel versatile synthesis of substituted tetrabenzoporphyrins. J. Org. Chem. 69, 522-535.