# Optical absorption spectrum of TBP-meso-tetra(4-COOMe-phenyl)-Pd in DMF # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by O. Finikova on 10-16-2004 using a PerkinElmer Lambda 35. # # # These measurements were scaled to make the molar extinction coefficient match # the value of 240000 cm-1/M at 443.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Finikova, O. S., A. V. Cheprakov, I. P. Beletskaya, P. J. Carroll and S. A. Vinogradov (2004) Novel versatile synthesis of substituted tetrabenzoporphyrins. J. Org. Chem. 69, 522-535. # ##Wavelength (nm) Molar Extinction (cm-1/M) 350 9624 351 9410 352 9171 353 9006 354 8828 355 8658 356 8501 357 8383 358 8303 359 8208 360 8129 361 8172 362 8235 363 8301 364 8362 365 8562 366 8674 367 8838 368 9029 369 9246 370 9412 371 9617 372 9817 373 10078 374 10355 375 10632 376 10951 377 11280 378 11639 379 11994 380 12432 381 12818 382 13271 383 13616 384 14095 385 14654 386 15098 387 15527 388 15918 389 16302 390 16707 391 17093 392 17520 393 17968 394 18452 395 18969 396 19603 397 20281 398 21078 399 21996 400 23012 401 24182 402 25509 403 26970 404 28638 405 30411 406 32371 407 34428 408 36620 409 38847 410 41072 411 43171 412 45098 413 46735 414 48173 415 49230 416 50056 417 50556 418 50893 419 51138 420 51415 421 51838 422 52547 423 53715 424 55417 425 57762 426 60934 427 65085 428 70191 429 76558 430 84173 431 93261 432 103850 433 116209 434 130038 435 145185 436 161141 437 177408 438 193230 439 208028 440 220872 441 230743 442 237421 443 239999 444 238796 445 233559 446 225108 447 213426 448 199670 449 184362 450 168267 451 151918 452 136119 453 121149 454 107168 455 94500 456 83120 457 73064 458 64210 459 56633 460 49975 461 44208 462 39141 463 34759 464 30888 465 27472 466 24460 467 21790 468 19408 469 17277 470 15320 471 13616 472 12101 473 10748 474 9576 475 8556 476 7611 477 6826 478 6118 479 5520 480 4982 481 4532 482 4123 483 3807 484 3488 485 3220 486 2993 487 2812 488 2621 489 2461 490 2318 491 2193 492 2086 493 1989 494 1886 495 1819 496 1735 497 1684 498 1618 499 1575 500 1521 501 1507 502 1455 503 1434 504 1425 505 1393 506 1375 507 1375 508 1364 509 1366 510 1351 511 1350 512 1351 513 1362 514 1368 515 1373 516 1387 517 1412 518 1441 519 1464 520 1485 521 1532 522 1614 523 1660 524 1734 525 1785 526 1855 527 1902 528 1964 529 1994 530 2027 531 2050 532 2096 533 2130 534 2153 535 2178 536 2211 537 2207 538 2266 539 2250 540 2271 541 2286 542 2303 543 2314 544 2303 545 2309 546 2336 547 2343 548 2352 549 2353 550 2382 551 2375 552 2418 553 2462 554 2477 555 2511 556 2595 557 2673 558 2784 559 2877 560 3048 561 3230 562 3441 563 3704 564 4018 565 4395 566 4784 567 5281 568 5813 569 6356 570 6940 571 7494 572 8056 573 8628 574 9138 575 9631 576 10067 577 10476 578 10839 579 11144 580 11410 581 11642 582 11808 583 11935 584 11966 585 11989 586 11948 587 11817 588 11680 589 11496 590 11316 591 11114 592 10878 593 10673 594 10473 595 10335 596 10176 597 10092 598 9997 599 9992 600 10019 601 10096 602 10224 603 10440 604 10721 605 11055 606 11491 607 12053 608 12714 609 13546 610 14521 611 15723 612 17111 613 18765 614 20688 615 22921 616 25495 617 28472 618 31831 619 35571 620 39666 621 44117 622 48821 623 53726 624 58610 625 63336 626 67805 627 71805 628 75242 629 77971 630 79924 631 81005 632 81307 633 80742 634 79414 635 77346 636 74695 637 71452 638 67790 639 63772 640 59566 641 55251 642 50907 643 46594 644 42424 645 38402 646 34637 647 31085 648 27802 649 24802 650 22098 651 19651 652 17481 653 15502 654 13766 655 12226 656 10882 657 9687 658 8599 659 7686 660 6876 661 6154 662 5527 663 4982 664 4513 665 4098 666 3713 667 3398 668 3086 669 2839 670 2598 671 2403 672 2218 673 2050 674 1912 675 1773 676 1648 677 1543 678 1455 679 1357 680 1269 681 1191 682 1139 683 1071 684 1012 685 959 686 903 687 875 688 816 689 776 690 730 691 707 692 684 693 628 694 605 695 630 696 573 697 555 698 544 699 512 700 478 701 484 702 494 703 475 704 430 705 425 706 408 707 421 708 398 709 387 710 387 711 401 712 389 713 383 714 398 715 373 716 392 717 358 718 373 719 382 720 366 721 378 722 383 723 383 724 364 725 385 726 398 727 400 728 394 729 392 730 376 731 391 732 417 733 412 734 410 735 419 736 410 737 430 738 423 739 423 740 425 741 439 742 455 743 451 744 460 745 448 746 444 747 453 748 471 749 469 750 467 751 476 752 444 753 451 754 457 755 450 756 459 757 453 758 462 759 453 760 482 761 482 762 484 763 494 764 485 765 457 766 484 767 473 768 476 769 455 770 448 771 439 772 419 773 412 774 408 775 419 776 407 777 391 778 380 779 385 780 394 781 421 782 376 783 369 784 346 785 348 786 325 787 319 788 310 789 314 790 307 791 312 792 283 793 282 794 264 795 228 796 226 797 225 798 208 799 192 800 201 801 198 802 189 803 178 804 144 805 144 806 130 807 148 808 133 809 114 810 101 811 101 812 82 813 87 814 73 815 73 816 64 817 53 818 71 819 50 820 46 821 41 822 28 823 26 824 26 825 26 826 32 827 19 828 -1 829 8 830 21 831 16 832 8 833 7 834 14 835 3 836 7 837 3 838 1 839 1 840 0 841 7 842 -14 843 3 844 10 845 7 846 -5 847 -5 848 3 849 8 850 5