This page summarizes the optical absorption and emission data of Bis(5-phenyldipyrrinato)zinc that
is available in the PhotochemCAD
package, version 2.1a (Du 1998, Dixon 2005). I reworked their data to
produce these interactive graphs and to provide direct links to text files
containing the raw and manipulated data. Although I have tried to be careful, I
may have introduced some errors; the cautious user is advised to compare these
results with the original sources.
You can resize any of the graphs by clicking and dragging a rectangle. If you hover the mouse over the graph, you will see a pop-up showing the coordinates. One of the icons in the upper right corner will let you export the graph in other formats.
Absorption
This optical absorption measurement of Bis(5-phenyldipyrrinato)zinc were made by D. Holten on 09-15-2004 using a .
These measurements were scaled to make the molar extinction coefficient match the value of 115,000cm-1/M at 485.0nm (Sazanovich, 2004).
Original Data | Extinction Data
Fluorescence
The fluorescence emission spectrum of Bis(5-phenyldipyrrinato)zinc dissolved in toluene. The quantum yield of this molecule is 0.006 (Sazanovich, 2004). This spectrum was collected by on 09-15-2004 using a .
References
Dixon, J. M., M. Taniguchi and J. S. Lindsey (2005), "PhotochemCAD 2. A Refined Program with Accompanying Spectral Databases for Photochemical Calculations, Photochem. Photobiol., 81, 212-213.
Du, H., R.-C. A. Fuh, J. Li, L. A. Corkan and J. S. Lindsey (1998) PhotochemCAD: A computer-aided design and research tool in photochemistry. Photochem. Photobiol. 68, 141-142.
Sazanovich, I. V., C. Kirmaier, E. Hindin, L. Yu, D. Bocian, J. S. Lindsey and D. Holten (2004) Structural control of the excited-state dynamics of bis(dipyrrinato)zinc complexes: self-assembling chromophores for light-harvesting architecture. J. Am. Chem. Soc. 126, 2664-2665.