# Optical absorption spectrum of TBP-meso-tetra(4-COOMe-phenyl)-Zn in DMF # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by O. Finikova on 10-24-2004 using a PerkinElmer Lambda 35. # # # These measurements were scaled to make the molar extinction coefficient match # the value of 300000 cm-1/M at 471.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Finikova, O. S., A. V. Cheprakov, I. P. Beletskaya, P. J. Carroll and S. A. Vinogradov (2004) Novel versatile synthesis of substituted tetrabenzoporphyrins. J. Org. Chem. 69, 522-535. # ##Wavelength (nm) Molar Extinction (cm-1/M) 350 12612 351 12367 352 12099 353 11839 354 11636 355 11468 356 11267 357 11182 358 11034 359 10928 360 10860 361 10778 362 10787 363 10739 364 10757 365 10798 366 10804 367 10846 368 10860 369 10975 370 11129 371 11202 372 11199 373 11294 374 11332 375 11432 376 11465 377 11568 378 11580 379 11698 380 11760 381 11789 382 11754 383 11851 384 11878 385 11760 386 11763 387 11633 388 11612 389 11524 390 11512 391 11394 392 11341 393 11250 394 11205 395 11093 396 11073 397 10966 398 10928 399 10863 400 10857 401 10837 402 10837 403 10837 404 10896 405 10905 406 10984 407 11081 408 11140 409 11282 410 11456 411 11562 412 11701 413 11851 414 12049 415 12243 416 12488 417 12712 418 13045 419 13390 420 13794 421 14331 422 14897 423 15555 424 16369 425 17286 426 18359 427 19571 428 20904 429 22393 430 23980 431 25749 432 27533 433 29385 434 31308 435 33195 436 34994 437 36811 438 38447 439 40019 440 41443 441 42800 442 44009 443 45177 444 46324 445 47627 446 49004 447 50738 448 52864 449 55672 450 59249 451 63693 452 69231 453 76102 454 84435 455 94211 456 105632 457 118598 458 132915 459 148456 460 164905 461 182117 462 199696 463 217050 464 233841 465 249544 466 263743 467 275898 468 285895 469 293326 470 298151 471 300000 472 299283 473 295992 474 290259 475 282153 476 272171 477 260296 478 246999 479 232538 480 217413 481 201772 482 186084 483 170528 484 155303 485 140553 486 126425 487 113116 488 100666 489 89062 490 78437 491 68738 492 59953 493 52083 494 45003 495 38795 496 33363 497 28633 498 24584 499 21111 500 18185 501 15679 502 13582 503 11866 504 10430 505 9221 506 8283 507 7460 508 6862 509 6351 510 6009 511 5653 512 5479 513 5310 514 5195 515 5145 516 5128 517 5148 518 5148 519 5169 520 5249 521 5319 522 5334 523 5417 524 5467 525 5476 526 5464 527 5476 528 5476 529 5414 530 5366 531 5299 532 5169 533 5080 534 4995 535 4853 536 4712 537 4609 538 4467 539 4390 540 4252 541 4190 542 4149 543 4078 544 4063 545 4019 546 3992 547 3989 548 3969 549 3992 550 3989 551 4004 552 4010 553 3989 554 3995 555 4010 556 4016 557 4007 558 3992 559 3992 560 3948 561 3942 562 3930 563 3954 564 3877 565 3898 566 3871 567 3866 568 3833 569 3839 570 3824 571 3792 572 3804 573 3765 574 3733 575 3730 576 3694 577 3680 578 3680 579 3733 580 3706 581 3730 582 3753 583 3871 584 3951 585 4057 586 4234 587 4426 588 4632 589 4977 590 5349 591 5697 592 6136 593 6629 594 7130 595 7732 596 8357 597 9026 598 9695 599 10391 600 11111 601 11889 602 12633 603 13379 604 14116 605 14841 606 15558 607 16198 608 16841 609 17410 610 17929 611 18348 612 18731 613 18972 614 19141 615 19215 616 19185 617 19064 618 18867 619 18480 620 18144 621 17604 622 17141 623 16540 624 15980 625 15334 626 14732 627 14145 628 13561 629 13042 630 12562 631 12178 632 11889 633 11674 634 11642 635 11665 636 11857 637 12264 638 12771 639 13556 640 14514 641 15726 642 17136 643 18743 644 20580 645 22632 646 24844 647 27200 648 29589 649 32078 650 34522 651 36949 652 39176 653 41275 654 43133 655 44746 656 46055 657 46999 658 47624 659 47916 660 47813 661 47406 662 46598 663 45513 664 44156 665 42582 666 40795 667 38828 668 36645 669 34472 670 32201 671 29916 672 27642 673 25425 674 23252 675 21170 676 19185 677 17351 678 15611 679 13998 680 12521 681 11182 682 9984 683 8870 684 7852 685 6921 686 6148 687 5405 688 4780 689 4219 690 3733 691 3335 692 2960 693 2651 694 2370 695 2155 696 1913 697 1739 698 1604 699 1462 700 1347 701 1220 702 1158 703 1111 704 1011 705 949 706 893 707 887 708 846 709 822 710 763 711 734 712 751 713 719 714 704 715 669 716 678 717 663 718 642 719 610 720 595 721 598 722 592 723 554 724 554 725 560 726 530 727 533 728 551 729 524 730 477 731 498 732 516 733 468 734 483 735 430 736 471 737 445 738 483 739 483 740 442 741 421 742 457 743 415 744 439 745 430 746 409 747 389 748 406 749 389 750 403 751 421 752 403 753 383 754 383 755 374 756 409 757 409 758 395 759 401 760 356 761 406 762 368 763 395 764 386 765 427 766 412 767 421 768 424 769 383 770 415 771 439 772 383 773 436 774 439 775 409 776 418 777 442 778 421 779 421 780 398 781 442 782 424 783 445 784 468 785 468 786 471 787 454 788 486 789 483 790 468 791 486 792 483 793 501 794 489 795 510 796 477 797 486 798 513 799 510 800 477 801 516 802 536 803 530 804 533 805 533 806 560 807 539 808 557 809 563 810 577 811 548 812 586 813 569 814 583 815 586 816 595 817 583 818 580 819 613 820 648 821 616 822 651 823 616 824 654 825 645 826 657 827 648 828 669 829 678 830 687 831 672 832 687 833 681 834 707 835 698 836 713 837 687 838 716 839 722 840 737 841 692 842 716 843 725 844 704 845 707 846 722 847 743 848 728 849 728 850 704