# Optical absorption spectrum of TBP-meso-tetra(4-COOMe-phenyl)-Fb in DMF # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by O. Finikova on 10-24-2004 using a PerkinElmer Lambda 35. # # # These measurements were scaled to make the molar extinction coefficient match # the value of 220000 cm-1/M at 469.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Finikova, O. S., A. V. Cheprakov, I. P. Beletskaya, P. J. Carroll and S. A. Vinogradov (2004) Novel versatile synthesis of substituted tetrabenzoporphyrins. J. Org. Chem. 69, 522-535. # ##Wavelength (nm) Molar Extinction (cm-1/M) 350 17161 351 16980 352 16892 353 16795 354 16715 355 16639 356 16578 357 16554 358 16528 359 16514 360 16506 361 16530 362 16470 363 16538 364 16556 365 16556 366 16601 367 16659 368 16667 369 16711 370 16757 371 16781 372 16822 373 16900 374 16936 375 17016 376 17071 377 17119 378 17181 379 17265 380 17298 381 17368 382 17368 383 17438 384 17384 385 17488 386 17492 387 17506 388 17551 389 17537 390 17549 391 17514 392 17521 393 17474 394 17464 395 17396 396 17396 397 17356 398 17324 399 17286 400 17243 401 17255 402 17288 403 17332 404 17424 405 17551 406 17784 407 17968 408 18310 409 18641 410 19033 411 19565 412 20164 413 20744 414 21443 415 22182 416 22956 417 23767 418 24617 419 25422 420 26220 421 27045 422 27837 423 28636 424 29421 425 30229 426 31022 427 31882 428 32800 429 33786 430 34873 431 36052 432 37374 433 38850 434 40453 435 42178 436 44046 437 46105 438 48322 439 50781 440 53495 441 56524 442 59892 443 63636 444 67778 445 72321 446 77182 447 82428 448 87918 449 93705 450 99636 451 105706 452 111852 453 118085 454 124631 455 131338 456 138338 457 145810 458 153684 459 161764 460 170078 461 178568 462 186835 463 194719 464 201846 465 208095 466 213200 467 216874 468 219148 469 220000 470 219544 471 217702 472 214757 473 210882 474 206106 475 200596 476 194492 477 187880 478 180904 479 173569 480 166006 481 158398 482 150743 483 142994 484 135271 485 127602 486 119927 487 112435 488 105085 489 97883 490 90953 491 84220 492 77762 493 71512 494 65624 495 60035 496 54772 497 49879 498 45320 499 41116 500 37277 501 33752 502 30599 503 27710 504 25089 505 22707 506 20638 507 18730 508 17042 509 15522 510 14180 511 13005 512 11971 513 11051 514 10261 515 9540 516 8912 517 8373 518 7893 519 7469 520 7094 521 6793 522 6521 523 6282 524 6067 525 5889 526 5752 527 5642 528 5553 529 5497 530 5445 531 5421 532 5399 533 5429 534 5443 535 5465 536 5525 537 5591 538 5634 539 5710 540 5760 541 5836 542 5901 543 5985 544 6049 545 6132 546 6186 547 6238 548 6288 549 6349 550 6369 551 6383 552 6407 553 6415 554 6415 555 6387 556 6361 557 6365 558 6329 559 6304 560 6284 561 6290 562 6304 563 6329 564 6333 565 6437 566 6513 567 6660 568 6785 569 6961 570 7172 571 7381 572 7642 573 7913 574 8201 575 8500 576 8811 577 9147 578 9484 579 9840 580 10163 581 10535 582 10900 583 11248 584 11579 585 11915 586 12230 587 12531 588 12770 589 13003 590 13182 591 13304 592 13413 593 13441 594 13421 595 13363 596 13254 597 13122 598 12909 599 12694 600 12463 601 12236 602 11963 603 11734 604 11495 605 11298 606 11099 607 10985 608 10876 609 10838 610 10912 611 11013 612 11242 613 11577 614 11985 615 12559 616 13230 617 14016 618 14885 619 15861 620 16882 621 17950 622 19039 623 20075 624 21068 625 21966 626 22807 627 23534 628 24203 629 24776 630 25274 631 25700 632 26095 633 26405 634 26718 635 26953 636 27162 637 27389 638 27497 639 27640 640 27726 641 27752 642 27762 643 27714 644 27576 645 27387 646 27124 647 26768 648 26332 649 25790 650 25175 651 24454 652 23697 653 22837 654 21935 655 21001 656 20039 657 19055 658 18089 659 17123 660 16193 661 15261 662 14359 663 13501 664 12694 665 11929 666 11226 667 10537 668 9866 669 9297 670 8745 671 8221 672 7731 673 7291 674 6887 675 6525 676 6192 677 5923 678 5676 679 5477 680 5296 681 5158 682 5081 683 5043 684 5005 685 5069 686 5125 687 5240 688 5368 689 5575 690 5770 691 6011 692 6240 693 6493 694 6710 695 6935 696 7142 697 7311 698 7435 699 7502 700 7598 701 7588 702 7550 703 7506 704 7383 705 7243 706 7080 707 6877 708 6656 709 6395 710 6152 711 5921 712 5646 713 5379 714 5121 715 4864 716 4597 717 4384 718 4151 719 3916 720 3705 721 3470 722 3314 723 3081 724 2912 725 2729 726 2575 727 2422 728 2271 729 2155 730 1974 731 1867 732 1735 733 1645 734 1528 735 1442 736 1347 737 1275 738 1231 739 1144 740 1092 741 1028 742 986 743 923 744 871 745 815 746 769 747 739 748 701 749 668 750 656 751 612 752 598 753 586 754 572 755 546 756 498 757 496 758 472 759 474 760 451 761 445 762 425 763 439 764 383 765 411 766 377 767 389 768 379 769 321 770 365 771 345 772 323 773 355 774 299 775 331 776 313 777 291 778 301 779 289 780 275 781 289 782 297 783 287 784 257 785 279 786 267 787 261 788 263 789 259 790 251 791 255 792 228 793 253 794 226 795 228 796 220 797 237 798 224 799 230 800 218 801 220 802 224 803 222 804 198 805 214 806 204 807 198 808 198 809 204 810 192 811 208 812 196 813 192 814 186 815 182 816 174 817 162 818 178 819 148 820 154 821 164 822 184 823 150 824 166 825 148 826 146 827 134 828 146 829 132 830 136 831 140 832 118 833 122 834 118 835 108 836 118 837 122 838 106 839 88 840 96 841 86 842 82 843 76 844 64 845 74 846 96 847 68 848 58 849 50 850 28