# Optical absorption spectrum of TBP-beta-octa(COOBu)-Zn in DMF # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by O. Finikova on 10-16-2004 using a PerkinElmer Lambda 35. # # # These measurements were scaled to make the molar extinction coefficient match # the value of 460000 cm-1/M at 452.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Finikova, O. S., A. V. Cheprakov, I. P. Beletskaya, P. J. Carroll and S. A. Vinogradov (2004) Novel versatile synthesis of substituted tetrabenzoporphyrins. J. Org. Chem. 69, 522-535. # ##Wavelength (nm) Molar Extinction (cm-1/M) 350 12648 351 12397 352 12244 353 12084 354 11941 355 11745 356 11606 357 11526 358 11383 359 11261 360 11062 361 11041 362 10870 363 10710 364 10598 365 10354 366 10177 367 9905 368 9668 369 9486 370 9336 371 9075 372 8925 373 8649 374 8458 375 8297 376 8133 377 8088 378 7973 379 7872 380 7875 381 7928 382 7715 383 7820 384 7663 385 7872 386 7977 387 8078 388 8266 389 8440 390 8709 391 8988 392 9354 393 9762 394 10180 395 10571 396 10964 397 11393 398 11822 399 12119 400 12499 401 12770 402 13130 403 13391 404 13740 405 13980 406 14339 407 14702 408 15225 409 15863 410 16787 411 17917 412 19433 413 21386 414 23833 415 26751 416 30255 417 34143 418 38295 419 42639 420 47018 421 51056 422 54605 423 57398 424 59346 425 60242 426 60295 427 59559 428 58332 429 56763 430 55198 431 53904 432 53046 433 52872 434 53486 435 55041 436 57694 437 61913 438 67780 439 76176 440 87604 441 103098 442 123083 443 148935 444 180687 445 218644 446 261214 447 307211 448 353222 449 394966 450 428820 451 450802 452 460000 453 455464 454 439286 455 413326 456 380553 457 343900 458 305792 459 268365 460 232468 461 199311 462 169035 463 142405 464 119018 465 98984 466 81758 467 67313 468 55156 469 45010 470 36527 471 29774 472 24196 473 19831 474 16243 475 13450 476 11132 477 9315 478 7837 479 6627 480 5662 481 4863 482 4232 483 3706 484 3308 485 2939 486 2667 487 2444 488 2308 489 2151 490 2043 491 1931 492 1900 493 1854 494 1816 495 1816 496 1799 497 1809 498 1819 499 1767 500 1812 501 1785 502 1785 503 1812 504 1837 505 1816 506 1819 507 1830 508 1875 509 1868 510 1893 511 1865 512 1847 513 1837 514 1816 515 1823 516 1812 517 1805 518 1785 519 1732 520 1729 521 1704 522 1771 523 1809 524 1788 525 1799 526 1928 527 2015 528 2105 529 2262 530 2412 531 2499 532 2566 533 2642 534 2691 535 2824 536 2872 537 2939 538 3029 539 3036 540 3075 541 3033 542 2987 543 3068 544 3036 545 3040 546 3050 547 3047 548 3005 549 3043 550 3057 551 3106 552 3085 553 3075 554 3040 555 3064 556 3050 557 3040 558 3012 559 2998 560 2932 561 2960 562 2932 563 2953 564 2935 565 3005 566 3061 567 3137 568 3259 569 3392 570 3584 571 3887 572 4225 573 4738 574 5337 575 6153 576 7074 577 8102 578 9190 579 10222 580 11153 581 12007 582 12840 583 13858 584 14754 585 15678 586 16456 587 17198 588 17777 589 18422 590 19015 591 19747 592 20326 593 20723 594 20950 595 20852 596 20580 597 20092 598 19587 599 19050 600 18446 601 17819 602 17143 603 16267 604 15357 605 14385 606 13562 607 12791 608 12146 609 11592 610 11142 611 10818 612 10644 613 10550 614 10581 615 10693 616 10992 617 11198 618 11536 619 11972 620 12579 621 13478 622 14740 623 16421 624 18732 625 21794 626 25775 627 30872 628 37385 629 45899 630 56474 631 69429 632 83727 633 98074 634 110546 635 119614 636 125314 637 128166 638 129725 639 131137 640 133295 641 136304 642 139455 643 141512 644 141352 645 137656 646 130617 647 120294 648 108049 649 94727 650 81475 651 69049 652 57673 653 47716 654 39181 655 32033 656 26023 657 21138 658 17167 659 13959 660 11414 661 9382 662 7729 663 6509 664 5470 665 4692 666 4075 667 3524 668 3057 669 2702 670 2398 671 2133 672 1959 673 1753 674 1617 675 1530 676 1412 677 1296 678 1202 679 1167 680 1094 681 1049 682 958 683 983 684 882 685 843 686 847 687 815 688 780 689 777 690 718 691 770 692 742 693 739 694 714 695 686 696 679 697 711 698 665 699 665 700 735 701 676 702 638 703 634 704 631 705 592 706 599 707 589 708 603 709 571 710 564 711 568 712 592 713 592 714 557 715 564 716 550 717 509 718 575 719 502 720 515 721 519 722 446 723 509 724 460 725 470 726 460 727 407 728 432 729 425 730 428 731 376 732 439 733 400 734 421 735 355 736 313 737 324 738 331 739 369 740 338 741 338 742 324 743 320 744 338 745 324 746 285 747 257 748 306 749 282 750 289 751 278 752 320 753 240 754 278 755 271 756 261 757 226 758 240 759 219 760 191 761 226 762 219 763 226 764 223 765 191 766 181 767 184 768 240 769 202 770 160 771 202 772 212 773 170 774 188 775 174 776 142 777 212 778 167 779 212 780 181 781 167 782 108 783 156 784 149 785 142 786 139 787 167 788 128 789 142 790 153 791 139 792 94 793 125 794 97 795 97 796 83 797 76 798 69 799 83 800 59 801 59 802 62 803 24 804 31 805 41 806 59 807 38 808 38 809 38 810 13 811 31 812 13 813 45 814 6 815 31 816 20 817 34 818 -13 819 3 820 13 821 -3 822 3 823 6 824 -6 825 -3 826 13 827 3 828 6 829 13 830 10 831 10 832 20 833 10 834 6 835 -13 836 -31 837 38 838 6 839 -6 840 3 841 -27 842 -27 843 -3 844 41 845 -3 846 6 847 0 848 0 849 3 850 -10