# Optical absorption spectrum of TBP-beta-octa(COOBu)-Pd in DMF # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by O. Finikova on 10-16-2004 using a PerkinElmer Lambda 35. # # # These measurements were scaled to make the molar extinction coefficient match # the value of 305000 cm-1/M at 426.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Finikova, O. S., A. V. Cheprakov, I. P. Beletskaya, P. J. Carroll and S. A. Vinogradov (2004) Novel versatile synthesis of substituted tetrabenzoporphyrins. J. Org. Chem. 69, 522-535. # ##Wavelength (nm) Molar Extinction (cm-1/M) 350 10042 351 10245 352 10417 353 10685 354 10904 355 11130 356 11328 357 11458 358 11619 359 11812 360 11940 361 12182 362 12340 363 12572 364 12801 365 13124 366 13428 367 13855 368 14240 369 14745 370 15273 371 15742 372 16265 373 16809 374 17337 375 17858 376 18316 377 18831 378 19351 379 19885 380 20444 381 21173 382 21930 383 22833 384 23802 385 25386 386 26828 387 28416 388 30219 389 32192 390 34516 391 37071 392 39926 393 43015 394 46339 395 49662 396 53032 397 56108 398 58784 399 60920 400 62487 401 63419 402 63903 403 63981 404 63926 405 63874 406 64220 407 65037 408 66547 409 68933 410 72298 411 76637 412 82021 413 88543 414 96447 415 106052 416 117664 417 131738 418 148462 419 168324 420 190796 421 215324 422 240373 423 264427 424 284521 425 298436 426 305000 427 302345 428 291420 429 272794 430 248997 431 221497 432 192815 433 164719 434 138323 435 114903 436 94495 437 77545 438 63434 439 51955 440 42565 441 35190 442 29220 443 24515 444 20614 445 17506 446 14940 447 12832 448 11096 449 9678 450 8468 451 7448 452 6568 453 5852 454 5186 455 4676 456 4187 457 3804 458 3388 459 3128 460 2847 461 2615 462 2318 463 2201 464 1990 465 1821 466 1675 467 1543 468 1433 469 1353 470 1249 471 1150 472 1077 473 999 474 957 475 913 476 848 477 791 478 765 479 731 480 637 481 640 482 624 483 598 484 549 485 536 486 520 487 499 488 512 489 481 490 471 491 437 492 418 493 416 494 374 495 385 496 359 497 346 498 348 499 301 500 291 501 296 502 301 503 301 504 327 505 348 506 392 507 465 508 515 509 640 510 679 511 775 512 892 513 962 514 1004 515 1072 516 1139 517 1171 518 1262 519 1293 520 1348 521 1402 522 1454 523 1491 524 1553 525 1608 526 1686 527 1696 528 1751 529 1793 530 1842 531 1878 532 1957 533 2003 534 2084 535 2167 536 2253 537 2339 538 2480 539 2519 540 2610 541 2748 542 2906 543 3070 544 3258 545 3469 546 3711 547 4059 548 4510 549 5043 550 5707 551 6529 552 7557 553 8806 554 10152 555 11648 556 13069 557 14334 558 15331 559 15916 560 16333 561 16679 562 17051 563 17405 564 17722 565 17894 566 17860 567 17769 568 17623 569 17465 570 17355 571 17293 572 17137 573 16895 574 16543 575 16127 576 15630 577 15252 578 15008 579 14722 580 14599 581 14654 582 14729 583 15047 584 15437 585 16007 586 16564 587 17202 588 17878 589 18714 590 19638 591 20637 592 21701 593 22841 594 23955 595 25173 596 26490 597 28057 598 30079 599 32790 600 36280 601 40868 602 46487 603 53503 604 61972 605 72335 606 84811 607 99379 608 115296 609 130906 610 144340 611 153820 612 159483 613 161914 614 162853 615 163605 616 164943 617 166885 618 168495 619 168345 620 165292 621 158359 622 147913 623 134549 624 119634 625 104264 626 89579 627 76028 628 63921 629 53613 630 44920 631 37696 632 31799 633 27010 634 23128 635 20049 636 17584 637 15547 638 13850 639 12478 640 11315 641 10279 642 9431 643 8629 644 7963 645 7318 646 6763 647 6230 648 5730 649 5282 650 4897 651 4543 652 4171 653 3849 654 3575 655 3297 656 3065 657 2870 658 2633 659 2472 660 2290 661 2167 662 2001 663 1902 664 1787 665 1691 666 1579 667 1509 668 1402 669 1353 670 1243 671 1220 672 1155 673 1093 674 1007 675 991 676 929 677 877 678 843 679 837 680 754 681 736 682 689 683 679 684 663 685 634 686 611 687 593 688 510 689 538 690 494 691 473 692 460 693 429 694 405 695 437 696 411 697 343 698 385 699 338 700 320 701 304 702 325 703 312 704 283 705 283 706 262 707 252 708 242 709 195 710 187 711 234 712 195 713 187 714 174 715 145 716 166 717 109 718 130 719 132 720 91 721 109 722 96 723 106 724 85 725 83 726 96 727 83 728 70 729 31 730 36 731 20 732 44 733 26 734 20 735 20 736 -7 737 15 738 -2 739 -26 740 -10 741 10 742 -20 743 -39 744 -5 745 -33 746 -39 747 -44 748 -7 749 -18 750 -28 751 -33 752 -78 753 -54 754 -52 755 -31 756 -31 757 -41 758 -52 759 -65 760 -65 761 -52 762 -67 763 -80 764 -83 765 -85 766 -65 767 -98 768 -88 769 -72 770 -101 771 -80 772 -101 773 -96 774 -124 775 -109 776 -67 777 -80 778 -130 779 -85 780 -122 781 -33 782 -52 783 -62 784 -65 785 -65 786 -119 787 -117 788 -117 789 -96 790 -114 791 -67 792 -122 793 -101 794 -119 795 -91 796 -85 797 -101 798 -114 799 -93 800 -85 801 -70 802 -104 803 -93 804 -114 805 -93 806 -101 807 -75 808 -101 809 -98 810 -91 811 -85 812 -104 813 -96 814 -93 815 -83 816 -75 817 -83 818 -57 819 -93 820 -72 821 -88 822 -93 823 -85 824 -65 825 -80 826 -75 827 -67 828 -96 829 -78 830 -59 831 -59 832 -44 833 -67 834 -36 835 -54 836 -44 837 -36 838 -23 839 -33 840 -28 841 -41 842 -41 843 -39 844 13 845 -7 846 5 847 -28 848 -10 849 -5 850 -5