# Optical absorption spectrum of Perylene-monoimide(OR)3, [PMI(OR)3] in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by M. Taniguchi on 10-02-2004 using a HP 8453. #The absorption values were collected using a spectral bandwidth of 1.0 nm. # # These measurements were scaled to make the molar extinction coefficient match # the value of 32000 cm-1/M at 479.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Tomizaki, K., R. S. Loewe, C. Kirmaier, J. K. Schwartz, J. L. Retsek, D. F. Bocian, D. Holten and J. S. Lindsey (2002) Synthesis and photophysical properties of light-harvesting arrays comprised of a porphyrin bearing multiple perylene-monoimide accessory pigments. J. Org. Chem. 67, 6519-6534. # ##Wavelength (nm) Molar Extinction (cm-1/M) 300 21818 301 21146 302 20544 303 20021 304 19526 305 19035 306 18548 307 18092 308 17632 309 17199 310 16788 311 16423 312 16091 313 15783 314 15508 315 15251 316 15019 317 14797 318 14573 319 14349 320 14133 321 13909 322 13684 323 13459 324 13242 325 13026 326 12803 327 12601 328 12411 329 12210 330 12035 331 11864 332 11716 333 11567 334 11442 335 11326 336 11226 337 11132 338 11061 339 10990 340 10918 341 10870 342 10821 343 10777 344 10721 345 10675 346 10640 347 10596 348 10569 349 10552 350 10519 351 10508 352 10493 353 10466 354 10452 355 10412 356 10376 357 10329 358 10274 359 10162 360 10073 361 9991 362 9966 363 9989 364 10001 365 9943 366 9792 367 9565 368 9368 369 9253 370 9247 371 9313 372 9354 373 9354 374 9312 375 9257 376 9215 377 9143 378 9077 379 8968 380 8882 381 8810 382 8763 383 8715 384 8702 385 8740 386 8785 387 8867 388 8996 389 9111 390 9262 391 9454 392 9643 393 9790 394 9922 395 10064 396 10202 397 10323 398 10467 399 10540 400 10648 401 10783 402 10887 403 11023 404 11191 405 11405 406 11597 407 11779 408 12030 409 12236 410 12428 411 12614 412 12752 413 12824 414 12799 415 12744 416 12562 417 12314 418 11990 419 11609 420 11148 421 10670 422 10168 423 9699 424 9208 425 8750 426 8354 427 7999 428 7723 429 7510 430 7366 431 7283 432 7267 433 7312 434 7411 435 7543 436 7741 437 7935 438 8175 439 8428 440 8702 441 9034 442 9325 443 9655 444 10003 445 10349 446 10727 447 11101 448 11490 449 11934 450 12369 451 12830 452 13302 453 13774 454 14316 455 14843 456 15403 457 16024 458 16622 459 17254 460 17907 461 18569 462 19244 463 20006 464 20765 465 21476 466 22174 467 22906 468 23692 469 24404 470 25207 471 25970 472 26740 473 27487 474 28182 475 28952 476 29692 477 30405 478 31185 479 32000 480 32810 481 33630 482 34489 483 35370 484 36330 485 37547 486 38358 487 38948 488 40519 489 41644 490 42786 491 44048 492 45288 493 46521 494 47751 495 48914 496 50221 497 51243 498 52369 499 53430 500 54411 501 55345 502 56022 503 56763 504 57308 505 57856 506 58375 507 58716 508 59049 509 59185 510 59355 511 59366 512 59693 513 59841 514 59991 515 60247 516 60407 517 60685 518 61124 519 61459 520 61928 521 62672 522 63259 523 64090 524 64902 525 65715 526 66831 527 67743 528 68772 529 69701 530 70563 531 71458 532 72191 533 72971 534 73541 535 73738 536 74158 537 74016 538 73751 539 73297 540 72496 541 71573 542 70400 543 68900 544 67215 545 65389 546 63254 547 61000 548 58564 549 56028 550 53451 551 50670 552 47858 553 45061 554 42336 555 39565 556 36808 557 34232 558 31693 559 29208 560 26790 561 24550 562 22464 563 20481 564 18589 565 16908 566 15303 567 13803 568 12439 569 11160 570 10069 571 9049 572 8161 573 7366 574 6601 575 5986 576 5442 577 4870 578 4446 579 4077 580 3725 581 3365 582 3137 583 2960 584 2740 585 2527 586 2404 587 2282 588 2168 589 2073 590 2008 591 1925 592 1858 593 1798 594 1753 595 1719 596 1691 597 1672 598 1639 599 1606 600 1591 601 1569 602 1569 603 1546 604 1536 605 1530 606 1520 607 1513 608 1507 609 1509 610 1494 611 1491 612 1496 613 1493 614 1481 615 1482 616 1485 617 1479 618 1486 619 1486 620 1481 621 1485 622 1488 623 1473 624 1479 625 1481 626 1481 627 1486 628 1475 629 1481 630 1487 631 1491 632 1495 633 1495 634 1487 635 1489 636 1486 637 1473 638 1463 639 1474 640 1477 641 1489 642 1482 643 1480 644 1484 645 1492 646 1491 647 1477 648 1479 649 1464 650 1485 651 1481 652 1475 653 1466 654 1498 655 1360 656 1307 657 1460 658 1481 659 1487 660 1490 661 1482 662 1470 663 1477 664 1477 665 1469 666 1478 667 1488 668 1478 669 1478 670 1469 671 1465 672 1455 673 1457 674 1466 675 1472 676 1463 677 1460 678 1463 679 1456 680 1458 681 1453 682 1452 683 1459 684 1448 685 1452 686 1447 687 1448 688 1451 689 1448 690 1449 691 1451 692 1450 693 1448 694 1457 695 1453 696 1460 697 1448 698 1448 699 1454 700 1456 701 1455 702 1448 703 1449 704 1450 705 1449 706 1450 707 1437 708 1426 709 1442 710 1439 711 1444 712 1436 713 1440 714 1430 715 1429 716 1429 717 1431 718 1432 719 1428 720 1430 721 1429 722 1428 723 1429 724 1429 725 1421 726 1426 727 1423 728 1429 729 1420 730 1417 731 1409 732 1418 733 1417 734 1414 735 1415 736 1414 737 1420 738 1430 739 1422 740 1420 741 1425 742 1418 743 1422 744 1422 745 1418 746 1421 747 1420 748 1420 749 1416 750 1400 751 1405 752 1406 753 1399 754 1402 755 1404 756 1391 757 1386 758 1385 759 1398 760 1383 761 1389 762 1392 763 1388 764 1388 765 1380 766 1391 767 1403 768 1389 769 1393 770 1402 771 1395 772 1400 773 1403 774 1396 775 1404 776 1403 777 1408 778 1396 779 1399 780 1395 781 1390 782 1391 783 1388 784 1395 785 1392 786 1389 787 1391 788 1382 789 1382 790 1390 791 1379 792 1391 793 1382 794 1364 795 1372 796 1380 797 1379 798 1375 799 1379 800 1380