# Emission spectrum of in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on on 10-01-2004 # using a PTI QM-4/2003 SE. The excitation and emission monochromators were set at 0.25 mm, giving a spectral bandwidth of 1 nm. The data interval was 1 nm and the integration time was 1 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 500 5399 501 5704 502 6123 503 6792 504 7333 505 8257 506 9309 507 11454 508 13190 509 15882 510 19841 511 24528 512 30284 513 38721 514 49503 515 61621 516 78364 517 101276 518 127140 519 162719 520 203669 521 258443 522 322957 523 400899 524 486862 525 594542 526 708761 527 842084 528 981318 529 1128910 530 1275360 531 1422120 532 1551450 533 1669210 534 1759870 535 1828210 536 1859760 537 1863390 538 1835890 539 1776840 540 1710020 541 1623620 542 1526170 543 1417990 544 1316100 545 1214100 546 1121910 547 1025140 548 946965 549 865525 550 796306 551 732294 552 680142 553 625194 554 585794 555 544153 556 512663 557 486877 558 464405 559 449724 560 440966 561 439704 562 444846 563 456828 564 472344 565 496424 566 527811 567 564382 568 601157 569 640367 570 688698 571 732411 572 780379 573 819552 574 858407 575 893132 576 917198 577 938395 578 949178 579 953491 580 948843 581 938311 582 924690 583 896572 584 869193 585 836298 586 798315 587 759534 588 718370 589 678328 590 637939 591 593313 592 555158 593 514567 594 481161 595 441084 596 412558 597 380270 598 353257 599 325957 600 303406 601 279555 602 261265 603 245098 604 230569 605 216355 606 204472 607 194046 608 186226 609 178949 610 173710 611 171310 612 169492 613 168375 614 168968 615 169066 616 172741 617 174127 618 178114 619 180310 620 183293 621 188068 622 189269 623 192643 624 193963 625 197063 626 198562 627 197963 628 198985 629 197380 630 196551 631 194119 632 189223 633 187075 634 184370 635 178149 636 172464 637 166465 638 160382 639 153648 640 147451 641 140415 642 134981 643 127663 644 122332 645 115177 646 108269 647 101578 648 97322 649 90521 650 86168 651 81015 652 76944 653 71759 654 67899 655 64249 656 60762 657 56948 658 54618 659 51036 660 49228 661 46957 662 43956 663 41505 664 40911 665 38478 666 37751 667 36452 668 35046 669 33682 670 33277 671 32786 672 31735 673 31765 674 31450 675 30717 676 30051 677 29919 678 29893 679 29514 680 29501 681 29013 682 29450 683 29299 684 29508 685 28867 686 28355 687 28785 688 28367 689 28774 690 27980 691 27701 692 27443 693 27324 694 26147 695 25244 696 25854 697 25224 698 24558 699 23638 700 23054 701 23080 702 22931 703 21445 704 21351 705 20998 706 19767 707 19167 708 19180 709 18050 710 17985 711 17046 712 17187 713 15922 714 16117 715 15274 716 14687 717 14309 718 14194 719 14406 720 13369 721 13137 722 12884 723 12555 724 12147 725 11857 726 12042 727 11600 728 11526 729 10627 730 11757 731 10730 732 10297 733 10105 734 10647 735 10464 736 10380 737 10621 738 10495 739 10761 740 10989 741 10275 742 10716 743 10475 744 9420 745 10220 746 10205 747 10711 748 10332 749 10539 750 10874 751 10353 752 10500 753 10402 754 10070 755 10549 756 10621 757 10232 758 10353 759 10937 760 11119 761 11152 762 10666 763 10632 764 11276 765 11391 766 11363 767 11319 768 11526 769 11762 770 11285 771 11362 772 11425 773 11147 774 11280 775 12392 776 12268 777 12238 778 11764 779 12043 780 12080 781 11320 782 11916 783 12555 784 11917 785 11461 786 12454 787 12391 788 12218 789 12358 790 12738 791 12674 792 12015 793 12588 794 13020 795 12620 796 12530 797 13789 798 12492 799 13218 800 12520 0 0