# Optical absorption spectrum of 5,10-Diaryl Mg-oxochlorin in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by M. Taniguchi on 10-02-2004 using a HP 8453. #The absorption values were collected using a spectral bandwidth of 1.0 nm. # # These measurements were scaled to make the molar extinction coefficient match # the value of 191000 cm-1/M at 425.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Taniguchi, M., H.-J. Kim, D. Ra, J. K. Schwartz, C. Kirmaier, E. Hindin, J. R. Diers, S. Prathapan, D. F. Bocian, D. Holten and J. S. Lindsey (2002) Synthesis and electronic properties of regioisomerically pure oxochlorins. J. Org. Chem. 67, 7329-7342. # ##Wavelength (nm) Molar Extinction (cm-1/M) 350 13602 351 13472 352 13387 353 13308 354 13230 355 13168 356 13136 357 13085 358 13075 359 12994 360 12927 361 12833 362 12717 363 12817 364 13060 365 13289 366 13291 367 13168 368 13190 369 13452 370 13648 371 13806 372 13937 373 14013 374 14139 375 14276 376 14431 377 14560 378 14680 379 14831 380 15007 381 15210 382 15485 383 15726 384 15952 385 16199 386 16438 387 16666 388 16849 389 17091 390 17421 391 17873 392 18515 393 19315 394 20541 395 22093 396 24090 397 26570 398 29559 399 32591 400 35900 401 39460 402 42602 403 45350 404 47407 405 48716 406 49354 407 49277 408 48654 409 47595 410 46612 411 45809 412 45519 413 46347 414 48463 415 52239 416 57748 417 65644 418 77044 419 93081 420 114424 421 139726 422 163287 423 179748 424 189335 425 190999 426 186499 427 179332 428 171887 429 164073 430 156320 431 148388 432 138236 433 125324 434 111885 435 97969 436 83235 437 69587 438 56748 439 45650 440 36381 441 28383 442 22648 443 18213 444 14819 445 12371 446 10517 447 9256 448 8338 449 7630 450 7140 451 6785 452 6474 453 6187 454 6022 455 5822 456 5650 457 5501 458 5392 459 5265 460 5172 461 5058 462 4975 463 4835 464 4738 465 4644 466 4559 467 4505 468 4407 469 4314 470 4297 471 4212 472 4161 473 4086 474 4011 475 4035 476 3984 477 3950 478 3939 479 3916 480 3931 481 3945 482 3957 483 3974 484 3987 485 4024 486 3978 487 4055 488 4174 489 4133 490 4135 491 4177 492 4198 493 4209 494 4236 495 4278 496 4279 497 4285 498 4351 499 4363 500 4389 501 4408 502 4406 503 4446 504 4503 505 4558 506 4617 507 4689 508 4740 509 4817 510 4906 511 4990 512 5123 513 5256 514 5370 515 5517 516 5640 517 5773 518 5928 519 6034 520 6124 521 6277 522 6350 523 6513 524 6668 525 6795 526 6870 527 6971 528 7059 529 7050 530 7033 531 7000 532 6924 533 6877 534 6807 535 6716 536 6650 537 6599 538 6554 539 6471 540 6443 541 6400 542 6337 543 6365 544 6348 545 6372 546 6422 547 6491 548 6588 549 6738 550 6889 551 7072 552 7229 553 7380 554 7521 555 7653 556 7745 557 7889 558 8102 559 8363 560 8668 561 9088 562 9606 563 10188 564 10702 565 11079 566 11359 567 11477 568 11440 569 11295 570 11103 571 10827 572 10504 573 10155 574 9721 575 9341 576 8961 577 8499 578 8115 579 7772 580 7343 581 6850 582 6527 583 6236 584 5839 585 5559 586 5440 587 5307 588 5236 589 5207 590 5188 591 5195 592 5263 593 5386 594 5615 595 5916 596 6322 597 6802 598 7348 599 7882 600 8373 601 8794 602 9101 603 9234 604 9274 605 9234 606 9206 607 9382 608 9814 609 10777 610 12392 611 14922 612 18386 613 22846 614 27592 615 31748 616 34248 617 34537 618 32635 619 29135 620 24679 621 20544 622 16324 623 12931 624 10266 625 8175 626 6749 627 5692 628 4970 629 4469 630 4125 631 3880 632 3660 633 3502 634 3342 635 3236 636 3140 637 3067 638 3026 639 3003 640 2963 641 2950 642 2925 643 2874 644 2841 645 2873 646 2835 647 2799 648 2774 649 2774 650 2761 651 2730 652 2689 653 2686 654 2739 655 2585 656 2534 657 2975 658 2797 659 2652 660 2652 661 2618 662 2583 663 2587 664 2554 665 2527 666 2526 667 2496 668 2472 669 2441 670 2421 671 2397 672 2362 673 2367 674 2358 675 2333 676 2312 677 2293 678 2276 679 2260 680 2242 681 2223 682 2218 683 2209 684 2169 685 2166 686 2172 687 2152 688 2135 689 2104 690 2075 691 2074 692 2055 693 2034 694 2026 695 1991 696 1998 697 1942 698 1941 699 1930 700 1907 701 1876 702 1841 703 1837 704 1824 705 1772 706 1765 707 1721 708 1715 709 1707 710 1679 711 1662 712 1634 713 1626 714 1596 715 1577 716 1569 717 1543 718 1531 719 1519 720 1506 721 1481 722 1469 723 1471 724 1451 725 1415 726 1416 727 1406 728 1416 729 1390 730 1380 731 1360 732 1371 733 1355 734 1343 735 1363 736 1332 737 1326 738 1341 739 1328 740 1313 741 1313 742 1299 743 1295 744 1297 745 1272 746 1280 747 1278 748 1272 749 1258 750 1234 751 1238 752 1238 753 1217 754 1220 755 1228 756 1207 757 1201 758 1179 759 1216 760 1177 761 1178 762 1194 763 1171 764 1156 765 1143 766 1191 767 1191 768 1151 769 1145 770 1179 771 1152 772 1184 773 1167 774 1151 775 1178 776 1163 777 1165 778 1168 779 1153 780 1156 781 1164 782 1149 783 1163 784 1157 785 1158 786 1150 787 1153 788 1130 789 1145 790 1151 791 1136 792 1135 793 1129 794 1108 795 1103 796 1128 797 1125 798 1090 799 1100 800 1083