# Emission spectrum of in methanol # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on on 12-11-1997 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 600 20786 601 22982 602 24737 603 27783 604 30402 605 33121 606 36458 607 39278 608 42190 609 45837 610 48959 611 52177 612 54922 613 59106 614 64337 615 68522 616 73877 617 78666 618 85670 619 91633 620 99217 621 109639 622 119289 623 130717 624 144562 625 161307 626 181470 627 203736 628 232894 629 261293 630 299851 631 346545 632 396061 633 463378 634 540485 635 646063 636 769623 637 927617 638 1115225 639 1349835 640 1633047 641 2003267 642 2435535 643 2962147 644 3606504 645 4338174 646 5226389 647 6237366 648 7413775 649 8781768 650 10274220 651 11899290 652 13663080 653 15494320 654 17344540 655 19245310 656 21095460 657 23102830 658 25074310 659 27123380 660 29116540 661 31178250 662 33072780 663 34918910 664 36622110 665 38173670 666 39638360 667 40908320 668 41889410 669 42599870 670 43064510 671 43252110 672 43094280 673 42587660 674 41788000 675 40602260 676 39191400 677 37564950 678 35794230 679 33890060 680 32022770 681 30012520 682 28119700 683 26200440 684 24393030 685 22638970 686 21204180 687 19823770 688 18673050 689 17561250 690 16641260 691 15837300 692 15136580 693 14574920 694 14074970 695 13667460 696 13297970 697 13003200 698 12782890 699 12595830 700 12434630 701 12375390 702 12343640 703 12332340 704 12355470 705 12422420 706 12503620 707 12592930 708 12708270 709 12860350 710 13012530 711 13172520 712 13372430 713 13534480 714 13707780 715 13854840 716 14000010 717 14077030 718 14169200 719 14205770 720 14178130 721 14127140 722 14046740 723 13867660 724 13699200 725 13438130 726 13178830 727 12890260 728 12557840 729 12213020 730 11812130 731 11402290 732 10980060 733 10573740 734 10170910 735 9717760 736 9338133 737 8941632 738 8590854 739 8216653 740 7868422 741 7558775 742 7226572 743 6905526 744 6579508 745 6267933 746 6001092 747 5699383 748 5446116 749 5193727 750 4954932 751 4705318 752 4491984 753 4285898 754 4068493 755 3847887 756 3685878 757 3481897 758 3324028 759 3161071 760 3017044 761 2870704 762 2755319 763 2632548 764 2524484 765 2428663 766 2340027 767 2232400 768 2145814 769 2062947 770 1987875 771 1918994 772 1856451 773 1790958 774 1758838 775 1701694 776 1662837 777 1618954 778 1581214 779 1534799 780 1505923 781 1473308 782 1451811 783 1411900 784 1369480 785 1339429 786 1318009 787 1288135 788 1268096 789 1235680 790 1215672 791 1186706 792 1166303 793 1130628 794 1112656 795 1093751 796 1060367 797 1042057 798 1034654 799 1007525 800 981908