# Emission spectrum of in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on on 06-17-1997 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 570 5500 571 5556 572 5266 573 5338 574 5276 575 5174 576 4961 577 5188 578 5076 579 5004 580 5155 581 5133 582 5055 583 5517 584 5613 585 5995 586 5762 587 5959 588 5916 589 6385 590 6562 591 6687 592 6856 593 7197 594 7756 595 8278 596 8552 597 9030 598 9033 599 8885 600 8504 601 8340 602 7797 603 7680 604 7357 605 7239 606 7556 607 7085 608 7522 609 7422 610 7360 611 6941 612 7026 613 7163 614 7123 615 7280 616 7087 617 7261 618 7123 619 6882 620 7292 621 7204 622 7765 623 8052 624 8642 625 8718 626 8834 627 9826 628 10854 629 10915 630 12164 631 13173 632 14839 633 15806 634 18490 635 20289 636 23430 637 27044 638 30582 639 35446 640 40573 641 44844 642 51797 643 57404 644 61597 645 62005 646 65212 647 63773 648 64606 649 64439 650 62677 651 59859 652 60506 653 58402 654 57308 655 57896 656 57385 657 56263 658 55358 659 55311 660 53973 661 52560 662 49424 663 50373 664 48851 665 47259 666 46255 667 45373 668 44056 669 44624 670 45028 671 46272 672 47567 673 48286 674 49649 675 51357 676 54662 677 56010 678 60579 679 62880 680 67010 681 71828 682 75545 683 80467 684 84536 685 90316 686 95631 687 100426 688 102100 689 105401 690 109161 691 113855 692 117009 693 122114 694 129804 695 138025 696 149117 697 162250 698 175276 699 193554 700 208970 701 226583 702 240964 703 252945 704 269487 705 279185 706 294705 707 306692 708 317482 709 327326 710 343152 711 354396 712 370120 713 380462 714 386976 715 391323 716 392374 717 389497 718 373074 719 361564 720 332406 721 309540 722 282565 723 256787 724 229212 725 208751 726 185721 727 168430 728 152640 729 141949 730 129081 731 116550 732 107412 733 98214 734 90364 735 83360 736 76792 737 70380 738 63380 739 57710 740 53703 741 48702 742 43812 743 40797 744 36543 745 33284 746 31636 747 28382 748 28861 749 25560 750 25002 751 24077 752 23485 753 22096 754 21568 755 21423 756 20308 757 21309 758 20032 759 23190 760 21549 761 21619 762 20903 763 18853 764 19320 765 19656 766 18745 767 17592 768 16442 769 16409 770 17704 771 18145 772 16965 773 17017 774 18241 775 16451 776 15805 777 16424 778 16964 779 18131 780 17889 781 16309 782 17027 783 17572 784 17122 785 16380 786 18804 787 17421 788 15935 789 16667 790 15926 791 16920 792 17692 793 17111 794 13136 795 13274 796 13782 797 12943 798 13200 799 14671 800 12197