# Emission spectrum of in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on in 1994 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 490 515762 491 214753 492 79902 493 29695 494 22443 495 21588 496 23437 497 26581 498 31043 499 36341 500 44918 501 55498 502 67312 503 86453 504 109723 505 143829 506 181710 507 233904 508 293589 509 372064 510 450940 511 554325 512 661076 513 801123 514 934426 515 1111396 516 1279569 517 1477234 518 1673293 519 1888791 520 2092513 521 2324670 522 2539739 523 2767557 524 2984875 525 3205871 526 3393563 527 3575186 528 3734314 529 3896199 530 4015589 531 4118560 532 4191105 533 4243029 534 4273762 535 4281043 536 4282899 537 4245582 538 4209152 539 4145753 540 4089741 541 3995066 542 3907778 543 3797798 544 3691077 545 3574251 546 3468563 547 3341732 548 3225416 549 3114962 550 2990921 551 2875679 552 2776752 553 2652723 554 2552146 555 2445759 556 2358336 557 2263991 558 2190893 559 2113254 560 2049597 561 1982657 562 1928251 563 1866471 564 1817630 565 1761837 566 1720357 567 1676163 568 1644494 569 1594605 570 1554834 571 1512089 572 1472588 573 1433215 574 1397890 575 1359552 576 1323106 577 1282688 578 1246238 579 1206887 580 1174232 581 1136083 582 1107659 583 1069561 584 1039032 585 1002901 586 971512 587 938844 588 907683 589 871202 590 840947 591 810422 592 783313 593 753497 594 725672 595 699805 596 673291 597 642850 598 620634 599 596300 600 575399 601 549612 602 529962 603 505044 604 485863 605 465871 606 450420 607 433462 608 418961 609 403050 610 390089 611 374841 612 363067 613 350643 614 339275 615 323481 616 316383 617 305335 618 297796 619 286966 620 278210 621 270269 622 263539 623 255636 624 248072 625 241033 626 232973 627 225360 628 219150 629 211249 630 203612 631 201083 632 193151 633 187369 634 182919 635 175774 636 172311 637 166066 638 160608 639 155694 640 152092 641 146203 642 141854 643 137706 644 133768 645 130630 646 126532 647 122206 648 118544 649 114354 650 110634 651 106338 652 102929 653 100887 654 97717 655 93327 656 91128 657 88130 658 85443 659 82995 660 79949 661 78200 662 76049 663 74035 664 71459 665 68476 666 68355 667 64442 668 63306 669 61895 670 61399 671 59030 672 57765 673 56238 674 55315 675 54673 676 51995 677 51779 678 51035 679 48214 680 48854 681 46816 682 46954 683 45896 684 44569 685 42271 686 42905 687 41518 688 40658 689 40012 690 39651 691 38791 692 38199 693 37348 694 37723 695 36416 696 35625 697 35367 698 34522 699 34090 700 34025 701 33908 702 31712 703 32938 704 31798 705 32375 706 31748 707 30843 708 30804 709 30528 710 29773 711 28954 712 28368 713 28938 714 27556 715 27726 716 28161 717 27449 718 27709 719 27764 720 26409 721 26666 722 26746 723 27013 724 26321 725 25848 726 26197 727 26584 728 25218 729 25442 730 24594 731 25599 732 24665 733 25340 734 24229 735 24931 736 23592 737 24277 738 23886 739 24223 740 23808 741 23819 742 23919 743 24314 744 21929 745 23035 746 23455 747 21967 748 23327 749 22691 750 21606 751 23539 752 22981 753 22030 754 23226 755 21644 756 22279 757 21367 758 23391 759 21302 760 21550 761 22176 762 21185 763 22138 764 21901 765 22171 766 20795 767 21595 768 21368 769 21546 770 21481 771 22370 772 20186 773 21468 774 21934 775 19794 776 22663 777 21345 778 19889 779 21158 780 20071 781 19829 782 19888 783 19155 784 21947 785 20669 786 19674 787 20849 788 20160 789 20153 790 19382 791 21689 792 19403 793 20041 794 19412 795 20403 796 19231 797 19927 798 19833 799 17777 800 20186