# Optical absorption spectrum of N,N'-Difluoroboryl-1,9-dimethyl-5-[(4-(2-trimethylsilylethynyl)pheny]dipyrrin in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by R. W. Wagner in 1994 using a Cary 3. # The absorption values were collected using a spectral bandwidth of 1.0 nm, a signal averaging time of 0.133 sec, a data interval of 0.25 nm, and a scan rate of 112.5 nm/min. # # These measurements were scaled to make the molar extinction coefficient match # the value of 48800 cm-1/M at 515.8 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Wagner, R. W. and J. S. Lindsey (1996) Boron-dipyrromethene dyes for incorporation in synthetic multi-pigment light-harvesting arrays. Pure Appl. Chem. 68, 1373-1380. # ##Wavelength (nm) Molar Extinction (cm-1/M) 349.75 11377 350 11433 350.25 11361 350.5 11488 350.75 11685 351 11524 351.25 11325 351.5 11631 351.75 11586 352 11654 352.25 11876 352.5 11695 352.75 11883 353 11756 353.25 11597 353.5 11960 353.75 11977 354 11685 354.25 11956 354.5 11771 354.75 11687 355 11827 355.25 11885 355.5 11648 355.75 11975 356 11904 356.25 11712 356.5 11641 356.75 12088 357 11837 357.25 11625 357.5 11688 357.75 11700 358 11886 358.25 11899 358.5 11531 358.75 11929 359 11644 359.25 11501 359.5 11539 359.75 11417 360 11478 360.25 11479 360.5 11437 360.75 11612 361 11680 361.25 11211 361.5 11438 361.75 11274 362 11339 362.25 11365 362.5 11428 362.75 11286 363 11270 363.25 11210 363.5 11180 363.75 11009 364 10899 364.25 10803 364.5 11084 364.75 10908 365 10758 365.25 10815 365.5 10782 365.75 10842 366 10588 366.25 10564 366.5 10429 366.75 10487 367 10300 367.25 10262 367.5 10189 367.75 10283 368 10212 368.25 10062 368.5 10065 368.75 10032 369 9921 369.25 9903 369.5 9993 369.75 9833 370 9962 370.25 9531 370.5 9537 370.75 9217 371 9438 371.25 9264 371.5 9160 371.75 9108 372 9146 372.25 9129 372.5 8867 372.75 8821 373 8739 373.25 8663 373.5 8437 373.75 8723 374 8571 374.25 8527 374.5 8433 374.75 8380 375 8183 375.25 8176 375.5 8079 375.75 8228 376 7815 376.25 7938 376.5 7743 376.75 7904 377 7722 377.25 7549 377.5 7698 377.75 7329 378 7298 378.25 7257 378.5 7164 378.75 6991 379 7185 379.25 6737 379.5 6572 379.75 6744 380 6757 380.25 6611 380.5 6504 380.75 6442 381 6283 381.25 6175 381.5 6047 381.75 6049 382 5969 382.25 5872 382.5 5886 382.75 5699 383 5537 383.25 5575 383.5 5387 383.75 5395 384 5283 384.25 5068 384.5 5137 384.75 5174 385 4917 385.25 4808 385.5 4788 385.75 4612 386 4614 386.25 4497 386.5 4479 386.75 4319 387 4411 387.25 4309 387.5 4136 387.75 4103 388 3962 388.25 3907 388.5 3770 388.75 3815 389 3737 389.25 3596 389.5 3535 389.75 3342 390 3255 390.25 3403 390.5 3242 390.75 3214 391 2965 391.25 2984 391.5 2964 391.75 2991 392 2934 392.25 2934 392.5 2801 392.75 2734 393 2697 393.25 2623 393.5 2663 393.75 2435 394 2282 394.25 2167 394.5 2328 394.75 2211 395 2212 395.25 2067 395.5 2054 395.75 1908 396 1796 396.25 1770 396.5 1767 396.75 1679 397 1626 397.25 1764 397.5 1585 397.75 1483 398 1529 398.25 1596 398.5 1681 398.75 1289 399 1364 399.25 1410 399.5 1336 399.75 1322 400 1353 400.25 1273 400.5 1212 400.75 1231 401 1184 401.25 1203 401.5 1121 401.75 1261 402 1253 402.25 1157 402.5 960 402.75 1147 403 1140 403.25 1129 403.5 999 403.75 1113 404 960 404.25 897 404.5 831 404.75 860 405 812 405.25 799 405.5 1005 405.75 814 406 864 406.25 857 406.5 760 406.75 815 407 739 407.25 713 407.5 787 407.75 589 408 672 408.25 745 408.5 731 408.75 626 409 693 409.25 665 409.5 586 409.75 571 410 629 410.25 643 410.5 857 410.75 743 411 735 411.25 816 411.5 794 411.75 801 412 701 412.25 802 412.5 777 412.75 887 413 813 413.25 718 413.5 802 413.75 888 414 784 414.25 834 414.5 937 414.75 763 415 876 415.25 938 415.5 856 415.75 1070 416 905 416.25 985 416.5 978 416.75 1031 417 1163 417.25 1136 417.5 1145 417.75 1200 418 1176 418.25 1260 418.5 1208 418.75 1064 419 1136 419.25 1224 419.5 1169 419.75 1193 420 1270 420.25 1183 420.5 1283 420.75 1274 421 1245 421.25 1295 421.5 1213 421.75 1195 422 1288 422.25 1307 422.5 1255 422.75 1239 423 1307 423.25 1282 423.5 1195 423.75 1098 424 1138 424.25 1133 424.5 1144 424.75 1112 425 1020 425.25 1090 425.5 992 425.75 1102 426 1085 426.25 956 426.5 1011 426.75 939 427 904 427.25 906 427.5 894 427.75 891 428 879 428.25 845 428.5 905 428.75 778 429 809 429.25 825 429.5 749 429.75 870 430 720 430.25 837 430.5 857 430.75 680 431 726 431.25 815 431.5 767 431.75 728 432 693 432.25 706 432.5 697 432.75 661 433 788 433.25 667 433.5 676 433.75 676 434 731 434.25 704 434.5 799 434.75 864 435 719 435.25 786 435.5 749 435.75 805 436 756 436.25 775 436.5 758 436.75 693 437 800 437.25 848 437.5 819 437.75 798 438 866 438.25 805 438.5 778 438.75 975 439 913 439.25 980 439.5 941 439.75 927 440 1048 440.25 1002 440.5 964 440.75 1014 441 942 441.25 1052 441.5 1024 441.75 1073 442 1167 442.25 1025 442.5 1087 442.75 1204 443 1191 443.25 1151 443.5 1211 443.75 1222 444 1138 444.25 1276 444.5 1262 444.75 1274 445 1374 445.25 1269 445.5 1348 445.75 1498 446 1347 446.25 1391 446.5 1478 446.75 1452 447 1462 447.25 1630 447.5 1639 447.75 1659 448 1605 448.25 1641 448.5 1653 448.75 1737 449 1766 449.25 1792 449.5 1767 449.75 1835 450 1902 450.25 1875 450.5 1942 450.75 1898 451 2044 451.25 1985 451.5 1923 451.75 1983 452 2120 452.25 1996 452.5 2161 452.75 2169 453 2187 453.25 2179 453.5 2205 453.75 2259 454 2314 454.25 2369 454.5 2338 454.75 2308 455 2466 455.25 2430 455.5 2462 455.75 2530 456 2549 456.25 2494 456.5 2609 456.75 2570 457 2595 457.25 2691 457.5 2710 457.75 2781 458 2734 458.25 2746 458.5 2917 458.75 2772 459 2886 459.25 2951 459.5 2951 459.75 3004 460 3088 460.25 3008 460.5 3089 460.75 3125 461 3182 461.25 3169 461.5 3261 461.75 3207 462 3421 462.25 3370 462.5 3373 462.75 3479 463 3490 463.25 3503 463.5 3495 463.75 3553 464 3624 464.25 3649 464.5 3653 464.75 3776 465 3800 465.25 3933 465.5 3892 465.75 3898 466 4007 466.25 4083 466.5 4055 466.75 4150 467 4185 467.25 4241 467.5 4358 467.75 4355 468 4519 468.25 4641 468.5 4662 468.75 4688 469 4819 469.25 4832 469.5 4908 469.75 5062 470 5128 470.25 5200 470.5 5394 470.75 5444 471 5508 471.25 5699 471.5 5770 471.75 5877 472 5924 472.25 6097 472.5 6162 472.75 6270 473 6394 473.25 6546 473.5 6720 473.75 6827 474 6982 474.25 7049 474.5 7213 474.75 7307 475 7499 475.25 7661 475.5 7846 475.75 8038 476 8271 476.25 8383 476.5 8605 476.75 8798 477 8924 477.25 9035 477.5 9164 477.75 9346 478 9394 478.25 9621 478.5 9736 478.75 9775 479 10024 479.25 10098 479.5 10379 479.75 10500 480 10656 480.25 10785 480.5 10837 480.75 11016 481 11214 481.25 11339 481.5 11339 481.75 11471 482 11726 482.25 11698 482.5 11888 482.75 12102 483 12145 483.25 12289 483.5 12331 483.75 12462 484 12586 484.25 12715 484.5 12733 484.75 12942 485 12884 485.25 13024 485.5 13052 485.75 13085 486 13312 486.25 13363 486.5 13510 486.75 13570 487 13680 487.25 13658 487.5 13549 487.75 13746 488 13751 488.25 13902 488.5 13851 488.75 13829 489 14011 489.25 14021 489.5 14008 489.75 14079 490 14206 490.25 14272 490.5 14228 490.75 14259 491 14208 491.25 14303 491.5 14401 491.75 14516 492 14534 492.25 14566 492.5 14775 492.75 14704 493 14802 493.25 14775 493.5 14831 493.75 14933 494 15109 494.25 15033 494.5 15129 494.75 15253 495 15299 495.25 15308 495.5 15463 495.75 15518 496 15689 496.25 15879 496.5 15933 496.75 16124 497 16267 497.25 16418 497.5 16642 497.75 16866 498 16944 498.25 17232 498.5 17494 498.75 17598 499 17853 499.25 18065 499.5 18453 499.75 18732 500 18986 500.25 19297 500.5 19720 500.75 19956 501 20358 501.25 20745 501.5 21067 501.75 21573 502 21947 502.25 22302 502.5 22739 502.75 23290 503 23737 503.25 24198 503.5 24725 503.75 25192 504 25555 504.25 26334 504.5 26766 504.75 27388 505 27866 505.25 28675 505.5 29067 505.75 29735 506 30494 506.25 31044 506.5 31636 506.75 32175 507 32961 507.25 33460 507.5 34085 507.75 34747 508 35540 508.25 35959 508.5 36791 508.75 37468 509 38084 509.25 38715 509.5 39472 509.75 40063 510 40439 510.25 41108 510.5 41696 510.75 42272 511 42933 511.25 43477 511.5 44093 511.75 44391 512 44969 512.25 45338 512.5 45883 512.75 46281 513 46602 513.25 46952 513.5 47166 513.75 47408 514 47752 514.25 47931 514.5 48348 514.75 48198 515 48542 515.25 48525 515.5 48593 515.75 48800 516 48689 516.25 48507 516.5 48562 516.75 48251 517 48231 517.25 48057 517.5 47677 517.75 47432 518 47268 518.25 46843 518.5 46708 518.75 46190 519 45745 519.25 45418 519.5 45047 519.75 44389 520 44183 520.25 43565 520.5 43059 520.75 42290 521 41886 521.25 41243 521.5 40862 521.75 40272 522 39512 522.25 38699 522.5 38337 522.75 37590 523 37063 523.25 36147 523.5 35514 523.75 34874 524 34423 524.25 33589 524.5 32883 524.75 32160 525 31623 525.25 30921 525.5 30163 525.75 29470 526 28724 526.25 27964 526.5 27457 526.75 26616 527 26007 527.25 25426 527.5 24715 527.75 24030 528 23324 528.25 22817 528.5 22208 528.75 21470 529 20741 529.25 20047 529.5 19587 529.75 19117 530 18473 530.25 17946 530.5 17279 530.75 16786 531 16218 531.25 15700 531.5 15199 531.75 14676 532 14160 532.25 13789 532.5 13331 532.75 12848 533 12371 533.25 11886 533.5 11448 533.75 11040 534 10734 534.25 10473 534.5 10422 534.75 10068 535 9737 535.25 9395 535.5 9027 535.75 8670 536 8342 536.25 8106 536.5 7832 536.75 7371 537 7144 537.25 6934 537.5 6600 537.75 6359 538 6106 538.25 5829 538.5 5639 538.75 5377 539 5189 539.25 5030 539.5 4810 539.75 4636 540 4394 540.25 4192 540.5 4043 540.75 3844 541 3694 541.25 3524 541.5 3362 541.75 3282 542 3144 542.25 2948 542.5 2864 542.75 2804 543 2662 543.25 2497 543.5 2355 543.75 2397 544 2159 544.25 2163 544.5 2011 544.75 1943 545 1873 545.25 1810 545.5 1801 545.75 1631 546 1560 546.25 1502 546.5 1436 546.75 1382 547 1358 547.25 1257 547.5 1240 547.75 1237 548 1143 548.25 1054 548.5 1061 548.75 961 549 991 549.25 878 549.5 818 549.75 857 550 871 550.25 841 550.5 757 550.75 807 551 743 551.25 737 551.5 633 551.75 558 552 548 552.25 594 552.5 554 552.75 512 553 500 553.25 506 553.5 418 553.75 407 554 577 554.25 512 554.5 386 554.75 323 555 371 555.25 407 555.5 341 555.75 366 556 318 556.25 217 556.5 290 556.75 226 557 300 557.25 340 557.5 241 557.75 264 558 198 558.25 216 558.5 179 558.75 155 559 208 559.25 297 559.5 206 559.75 167 560 161 560.25 134 560.5 161 560.75 278 561 129 561.25 119 561.5 167 561.75 165 562 131 562.25 159 562.5 160 562.75 207 563 165 563.25 149 563.5 162 563.75 139 564 91 564.25 151 564.5 207 564.75 81 565 91 565.25 61 565.5 97 565.75 131 566 135 566.25 58 566.5 102 566.75 29 567 124 567.25 42 567.5 144 567.75 38 568 122 568.25 55 568.5 127 568.75 69 569 -19 569.25 58 569.5 -68 569.75 128 570 79 570.25 133 570.5 91 570.75 75 571 -25 571.25 133 571.5 28 571.75 -14 572 99 572.25 75 572.5 60 572.75 30 573 13 573.25 188 573.5 91 573.75 7 574 167 574.25 -3 574.5 53 574.75 17 575 52 575.25 130 575.5 60 575.75 60 576 44 576.25 57 576.5 89 576.75 28 577 -32 577.25 160 577.5 0 577.75 43 578 91 578.25 74 578.5 32 578.75 113 579 181 579.25 42 579.5 12 579.75 -7 580 88 580.25 29 580.5 -29 580.75 140 581 85 581.25 122 581.5 53 581.75 38 582 80 582.25 46 582.5 49 582.75 52 583 132 583.25 94 583.5 174 583.75 69 584 148 584.25 59 584.5 139 584.75 2 585 85 585.25 103 585.5 43 585.75 40 586 74 586.25 68 586.5 -16 586.75 65 587 94 587.25 37 587.5 13 587.75 -20 588 46 588.25 91 588.5 14 588.75 99 589 41 589.25 104 589.5 45 589.75 91 590 96 590.25 64 590.5 36 590.75 21 591 44 591.25 176 591.5 49 591.75 74 592 139 592.25 56 592.5 130 592.75 53 593 97 593.25 17 593.5 111 593.75 70 594 62 594.25 154 594.5 10 594.75 129 595 84 595.25 96 595.5 119 595.75 -2 596 58 596.25 63 596.5 106 596.75 68 597 107 597.25 96 597.5 97 597.75 107 598 82 598.25 22 598.5 -7 598.75 103 599 132 599.25 66 599.5 128 599.75 81 600 34 600.25 61 600.5 96 600.75 68 601 56 601.25 131 601.5 119 601.75 -56 602 3 602.25 57 602.5 40 602.75 123 603 71 603.25 89 603.5 -52 603.75 55 604 124 604.25 6 604.5 106 604.75 120 605 72 605.25 28 605.5 17 605.75 77 606 114 606.25 -50 606.5 93 606.75 -69 607 44 607.25 44 607.5 125 607.75 -5 608 -2 608.25 97 608.5 -16 608.75 46 609 43 609.25 -31 609.5 99 609.75 -29 610 23 610.25 49 610.5 -2 610.75 59 611 93 611.25 -1 611.5 -7 611.75 185 612 115 612.25 127 612.5 -4 612.75 43 613 96 613.25 140 613.5 43 613.75 -30 614 -17 614.25 55 614.5 50 614.75 90 615 130 615.25 68 615.5 -6 615.75 6 616 43 616.25 66 616.5 40 616.75 69 617 106 617.25 12 617.5 -39 617.75 39 618 46 618.25 -64 618.5 60 618.75 -16 619 132 619.25 40 619.5 79 619.75 43 620 121 620.25 173 620.5 43 620.75 50 621 20 621.25 203 621.5 112 621.75 78 622 -24 622.25 81 622.5 1 622.75 -5 623 13 623.25 38 623.5 14 623.75 159 624 29 624.25 6 624.5 127 624.75 63 625 34 625.25 89 625.5 -34 625.75 5 626 52 626.25 28 626.5 -34 626.75 80 627 67 627.25 8 627.5 166 627.75 103 628 26 628.25 114 628.5 120 628.75 59 629 66 629.25 115 629.5 -1 629.75 18 630 74 630.25 93 630.5 110 630.75 11 631 72 631.25 59 631.5 18 631.75 75 632 60 632.25 104 632.5 43 632.75 -8 633 90 633.25 121 633.5 133 633.75 46 634 71 634.25 -20 634.5 -21 634.75 129 635 -2 635.25 66 635.5 73 635.75 74 636 73 636.25 90 636.5 14 636.75 17 637 128 637.25 66 637.5 -9 637.75 -15 638 32 638.25 1 638.5 3 638.75 184 639 82 639.25 48 639.5 -40 639.75 -92 640 -2 640.25 79 640.5 43 640.75 144 641 109 641.25 120 641.5 48 641.75 71 642 114 642.25 123 642.5 96 642.75 81 643 62 643.25 48 643.5 32 643.75 16 644 103 644.25 162 644.5 69 644.75 197 645 -10 645.25 20 645.5 146 645.75 127 646 163 646.25 79 646.5 23 646.75 -47 647 -54 647.25 91 647.5 -9 647.75 65 648 41 648.25 62 648.5 76 648.75 73 649 94 649.25 117 649.5 14 649.75 -39 650 7 650.25 54 650.5 56 650.75 86 651 129 651.25 157 651.5 101 651.75 87 652 63 652.25 87 652.5 71 652.75 87 653 136 653.25 165 653.5 108 653.75 143 654 42 654.25 42 654.5 -16 654.75 54 655 66 655.25 131 655.5 -50 655.75 96 656 -69 656.25 83 656.5 132 656.75 46 657 24 657.25 8 657.5 135 657.75 191 658 144 658.25 26 658.5 140 658.75 2 659 99 659.25 154 659.5 68 659.75 0 660 152 660.25 -35 660.5 132 660.75 53 661 -19 661.25 76 661.5 86 661.75 20 662 62 662.25 -2 662.5 43 662.75 60 663 71 663.25 21 663.5 94 663.75 30 664 109 664.25 88 664.5 77 664.75 169 665 135 665.25 63 665.5 -46 665.75 36 666 31 666.25 26 666.5 0 666.75 250 667 -44 667.25 122 667.5 57 667.75 -16 668 135 668.25 -48 668.5 204 668.75 89 669 68 669.25 74 669.5 42 669.75 -13 670 9 670.25 111 670.5 44 670.75 -17 671 116 671.25 155 671.5 -3 671.75 20 672 110 672.25 -69 672.5 122 672.75 0 673 49 673.25 24 673.5 48 673.75 25 674 56 674.25 64 674.5 63 674.75 -35 675 -61 675.25 -19 675.5 -73 675.75 107 676 149 676.25 14 676.5 127 676.75 -21 677 52 677.25 42 677.5 84 677.75 167 678 69 678.25 -52 678.5 30 678.75 97 679 28 679.25 57 679.5 55 679.75 34 680 78 680.25 84 680.5 -63 680.75 84 681 110 681.25 -25 681.5 49 681.75 101 682 39 682.25 105 682.5 -4 682.75 30 683 59 683.25 23 683.5 100 683.75 136 684 -18 684.25 -21 684.5 118 684.75 -51 685 -6 685.25 50 685.5 64 685.75 87 686 50 686.25 -12 686.5 43 686.75 147 687 148 687.25 -38 687.5 94 687.75 70 688 35 688.25 -49 688.5 -6 688.75 92 689 40 689.25 71 689.5 -34 689.75 50 690 -31 690.25 26 690.5 66 690.75 104 691 88 691.25 145 691.5 60 691.75 52 692 71 692.25 -65 692.5 44 692.75 162 693 55 693.25 125 693.5 26 693.75 34 694 62 694.25 28 694.5 -4 694.75 3 695 -72 695.25 74 695.5 21 695.75 30 696 19 696.25 82 696.5 43 696.75 146 697 71 697.25 23 697.5 -45 697.75 15 698 21 698.25 13 698.5 50 698.75 -37 699 -69 699.25 -58 699.5 18 699.75 -118 700 -81