# Optical absorption spectrum of N,N'-Difluoroboryl-1,9-dimethyl-5-(4-iodophenyl)dipyrrin in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by R. W. Wagner in 1994 using a Cary 3. # The absorption values were collected using a spectral bandwidth of 1.0 nm, a signal averaging time of 0.133 sec, a data interval of 0.25 nm, and a scan rate of 112.5 nm/min. # # These measurements were scaled to make the molar extinction coefficient match # the value of 59000 cm-1/M at 515.5 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Wagner, R. W. and J. S. Lindsey (1996) Boron-dipyrromethene dyes for incorporation in synthetic multi-pigment light-harvesting arrays. Pure Appl. Chem. 68, 1373-1380. # ##Wavelength (nm) Molar Extinction (cm-1/M) 349.74 11477 349.99 11326 350.24 11635 350.49 11800 350.74 11314 351 11581 351.24 11777 351.49 11800 351.74 11503 352 11343 352.24 11137 352.49 11246 352.74 11285 353 11559 353.24 11446 353.49 10967 353.74 11107 354 11278 354.24 11089 354.49 11207 354.74 10937 355 10861 355.24 11064 355.49 10987 355.74 10713 355.99 10407 356.24 10542 356.49 10714 356.74 10788 357 10805 357.24 10142 357.49 10322 357.74 10753 357.99 10534 358.24 10468 358.49 10307 358.74 10391 358.99 10109 359.24 9901 359.49 10199 359.74 9886 359.99 9879 360.24 10107 360.49 9888 360.74 9603 361 9324 361.24 9357 361.49 9473 361.74 9536 362 8939 362.24 9357 362.49 9555 362.74 9142 363 9128 363.24 8915 363.49 9022 363.74 8886 364 8607 364.24 8962 364.49 8807 364.74 8564 365 8223 365.24 8366 365.49 8609 365.74 8285 365.99 8241 366.24 8095 366.49 7994 366.74 7987 367 7858 367.24 7815 367.49 7835 367.74 7845 367.99 7584 368.24 7362 368.49 7193 368.74 7367 368.99 7096 369.24 7265 369.49 6962 369.74 6906 369.99 6827 370.24 6668 370.49 6598 370.74 6294 371 6677 371.24 6461 371.49 6419 371.74 6552 372 6191 372.24 6077 372.49 6008 372.74 6008 373 6098 373.24 6098 373.49 5740 373.74 5565 374 5747 374.24 5540 374.49 5573 374.74 5491 375 5417 375.24 5480 375.49 5488 375.74 5141 375.99 5086 376.24 4880 376.49 5032 376.74 4862 377 4718 377.24 4754 377.49 4583 377.74 4696 377.99 4473 378.24 4350 378.49 4337 378.74 4126 378.99 4096 379.24 4520 379.49 4335 379.74 4016 379.99 4086 380.24 4103 380.49 4237 380.74 3671 381 3732 381.24 3865 381.49 3646 381.74 3552 382 3523 382.24 3560 382.49 3315 382.74 3380 383 3031 383.24 3384 383.49 3050 383.74 3012 384 2890 384.24 2957 384.49 2890 384.74 2881 385 2817 385.24 2836 385.49 2902 385.74 2747 385.99 2659 386.24 2804 386.49 2485 386.74 2506 387 2605 387.24 2294 387.49 2449 387.74 2366 387.99 2102 388.24 2183 388.49 2381 388.74 2186 388.99 2130 389.24 2168 389.49 1963 389.74 2159 389.99 1882 390.24 1879 390.49 1855 390.74 1799 391 1765 391.24 1738 391.49 1431 391.74 1705 392 1368 392.24 1556 392.49 1490 392.74 1484 393 1154 393.24 1284 393.49 1453 393.74 1500 394 1353 394.24 1124 394.49 1324 394.74 1280 395 1171 395.24 1084 395.49 795 395.74 1065 395.99 1038 396.24 883 396.49 863 396.74 648 397 904 397.24 884 397.49 754 397.74 861 397.99 909 398.24 925 398.49 879 398.74 811 398.99 852 399.24 856 399.49 397 399.74 571 399.99 710 400.24 823 400.49 546 400.74 583 401 397 401.24 704 401.49 863 401.74 736 402 336 402.24 586 402.49 336 402.74 345 403 236 403.24 232 403.49 413 403.74 442 404 231 404.24 482 404.49 354 404.74 398 405 507 405.24 341 405.49 342 405.74 368 405.99 317 406.24 270 406.49 249 406.74 246 407 271 407.24 488 407.49 351 407.74 97 407.99 555 408.24 482 408.49 316 408.74 346 408.99 134 409.24 530 409.49 421 409.74 237 409.99 294 410.24 384 410.49 248 410.74 428 411 385 411.24 207 411.49 424 411.74 266 412 203 412.24 274 412.49 387 412.74 416 413 325 413.24 413 413.49 416 413.74 333 414 164 414.24 215 414.49 453 414.74 438 415 484 415.24 403 415.49 411 415.74 209 415.99 498 416.24 180 416.49 404 416.74 157 417 376 417.24 533 417.49 540 417.74 511 417.99 232 418.24 658 418.49 418 418.74 364 418.99 464 419.24 385 419.49 385 419.74 495 419.99 450 420.24 416 420.49 445 420.74 506 421 541 421.24 517 421.49 229 421.74 637 422 565 422.24 462 422.49 511 422.74 551 423 539 423.24 669 423.49 602 423.74 523 424 540 424.24 619 424.49 578 424.74 383 425 534 425.24 571 425.49 568 425.74 670 425.99 608 426.24 736 426.49 571 426.74 551 427 685 427.24 722 427.49 747 427.74 531 427.99 870 428.24 656 428.49 658 428.74 629 428.99 787 429.24 892 429.49 810 429.74 739 429.99 915 430.24 931 430.49 546 430.74 702 431 636 431.24 555 431.49 623 431.74 848 432 742 432.24 988 432.49 803 432.74 721 433 890 433.24 757 433.49 748 433.74 796 434 804 434.24 821 434.49 875 434.74 836 435 890 435.24 900 435.49 1024 435.74 813 435.99 871 436.24 1010 436.49 794 436.74 1139 437 978 437.24 885 437.49 1060 437.74 1065 437.99 1052 438.24 1095 438.49 1195 438.74 1336 438.99 1099 439.24 944 439.49 1113 439.74 1281 439.99 983 440.24 1024 440.49 1193 440.74 1321 441 1150 441.24 1126 441.49 1312 441.74 1230 442 1481 442.24 1321 442.49 1288 442.74 1473 443 1475 443.24 1327 443.49 1379 443.74 1404 444 1430 444.24 1653 444.49 1536 444.74 1486 445 1709 445.24 1556 445.49 1565 445.74 1647 445.99 1818 446.24 1716 446.49 1733 446.74 1852 447 1853 447.24 1686 447.49 1936 447.74 1995 447.99 1944 448.24 1883 448.49 2074 448.74 2101 448.99 2085 449.24 2114 449.49 2140 449.74 2128 449.99 2033 450.24 2137 450.49 2221 450.74 2338 451 2373 451.24 2243 451.49 2374 451.74 2434 452 2428 452.24 2477 452.49 2420 452.74 2591 453 2527 453.24 2653 453.49 2515 453.74 2821 454 2941 454.24 2796 454.49 2910 454.74 2659 455 2959 455.24 2766 455.49 3001 455.74 3014 455.99 2945 456.24 2972 456.49 2931 456.74 3222 457 3230 457.24 2962 457.49 3175 457.74 3204 457.99 3307 458.24 3211 458.49 3255 458.74 3376 458.99 3368 459.24 3433 459.49 3420 459.74 3495 459.99 3513 460.24 3533 460.49 3519 460.74 3508 461 3549 461.24 3490 461.49 3718 461.74 3757 462 3850 462.24 3999 462.49 3869 462.74 4084 463 3917 463.24 4086 463.49 4086 463.74 4287 464 4078 464.24 4138 464.49 4300 464.74 4201 465 4408 465.24 4445 465.49 4482 465.74 4538 465.99 4795 466.24 4560 466.49 4607 466.74 5015 467 4619 467.24 4910 467.49 4936 467.74 4877 467.99 5161 468.24 5412 468.49 5293 468.74 5530 468.99 5688 469.24 5782 469.49 5952 469.74 5926 469.99 6018 470.24 6176 470.49 6066 470.74 6202 471 6482 471.24 6677 471.49 6744 471.74 6946 472 7149 472.24 7198 472.49 7103 472.74 7571 473 7536 473.24 7563 473.49 7817 473.74 8190 474 8094 474.24 8352 474.49 8571 474.74 8670 475 8822 475.24 8933 475.49 9295 475.74 9354 475.99 9610 476.24 9994 476.49 9954 476.74 10328 477 10332 477.24 10621 477.49 10703 477.74 11014 477.99 11074 478.24 11138 478.49 11476 478.74 11531 478.99 11936 479.24 11977 479.49 12154 479.74 12165 479.99 12466 480.24 12727 480.49 12726 480.74 12898 481 13019 481.24 13246 481.49 13290 481.74 13572 482 13756 482.24 13810 482.49 14118 482.74 13968 483 14054 483.24 14265 483.49 14466 483.74 14690 484 14689 484.24 14706 484.49 15036 484.74 14970 485 14989 485.24 15300 485.49 15549 485.74 15335 485.99 15464 486.24 15765 486.49 15681 486.74 15645 487 15733 487.24 15693 487.49 15858 487.74 15856 487.99 15890 488.24 16067 488.49 16255 488.74 16042 488.99 15952 489.24 16260 489.49 16287 489.74 16125 489.99 16045 490.24 16209 490.49 16324 490.74 16329 491 16130 491.24 16489 491.49 16489 491.74 16670 492 16524 492.24 16512 492.49 16871 492.74 16701 493 16671 493.24 16774 493.49 16656 493.74 16875 494 17126 494.24 17284 494.49 17130 494.74 17433 495 17456 495.24 17447 495.49 17359 495.74 17671 495.99 17865 496.24 18026 496.49 18426 496.74 18495 497 18583 497.24 18721 497.49 19105 497.74 19093 497.99 19502 498.24 19453 498.49 20026 498.74 20503 498.99 20625 499.24 20983 499.49 21167 499.74 21483 499.99 22122 500.24 22396 500.49 22733 500.74 23336 501 23626 501.24 23920 501.49 24489 501.74 24969 502 25458 502.24 26066 502.49 26630 502.74 27229 503 27921 503.24 28378 503.49 28920 503.74 29689 504 30384 504.24 30925 504.49 31540 504.74 32361 505 33272 505.24 33974 505.49 34758 505.74 35465 505.99 35978 506.24 37058 506.49 37850 506.74 38592 507 39418 507.24 40221 507.49 40979 507.74 41813 507.99 42706 508.24 43412 508.49 44505 508.74 45283 508.99 46057 509.24 46863 509.49 47610 509.74 48552 509.99 49113 510.24 49830 510.49 50591 510.74 51262 511 51986 511.24 52747 511.49 53419 511.74 54259 512 54959 512.24 55356 512.49 55764 512.74 56287 513 57180 513.24 57305 513.49 57450 513.74 57745 514 58387 514.24 58495 514.49 58732 514.74 58744 515 58863 515.24 58924 515.49 59000 515.74 58774 515.99 58579 516.24 58388 516.49 58145 516.74 57877 517 57822 517.24 57220 517.49 56949 517.74 56504 517.99 55915 518.24 55591 518.49 54775 518.74 54167 518.99 53536 519.24 52745 519.49 52401 519.74 51797 519.99 51045 520.24 50386 520.49 49206 520.74 48881 521 47987 521.24 47007 521.49 46256 521.74 45559 522 44734 522.24 43724 522.49 43028 522.74 42169 523 41088 523.24 40321 523.49 39313 523.74 38226 524 37556 524.24 36731 524.49 35779 524.74 34859 525 33996 525.24 33168 525.49 32443 525.74 31331 525.99 30453 526.24 29515 526.49 29009 526.74 28108 527 27162 527.24 26308 527.49 25263 527.74 24928 527.99 23879 528.24 23026 528.49 22574 528.74 21973 528.99 21334 529.24 20102 529.49 19569 529.74 18969 529.99 18092 530.24 17522 530.49 16953 530.74 16459 531 15974 531.24 15179 531.49 14713 531.74 14084 532 13662 532.24 13060 532.49 12506 532.74 12085 533 11941 533.24 11222 533.49 10762 533.74 10378 534 9931 534.24 9885 534.49 9494 534.74 9183 535 8842 535.24 8590 535.49 8096 535.74 7884 535.99 7388 536.24 7151 536.49 6858 536.74 6421 537 6309 537.24 6035 537.49 5762 537.74 5481 537.99 5298 538.24 4967 538.49 4938 538.74 4593 538.99 4357 539.24 4373 539.49 4015 539.74 3920 539.99 3795 540.24 3398 540.49 3363 540.74 3226 541 3066 541.24 2878 541.49 2687 541.74 2646 542 2568 542.24 2405 542.49 2354 542.74 2304 543 2139 543.24 1959 543.49 1776 543.74 1858 544 1687 544.24 1756 544.49 1571 544.74 1747 545 1291 545.24 1452 545.49 1308 545.74 1285 545.99 1403 546.24 938 546.49 1143 546.74 1045 547 1073 547.24 1132 547.49 1045 547.74 1059 547.99 801 548.24 885 548.49 765 548.74 834 548.99 708 549.24 701 549.49 514 549.74 783 549.99 510 550.24 453 550.49 536 550.74 530 551 218 551.24 508 551.49 417 551.74 353 552 234 552.24 280 552.49 207 552.74 169 553 171 553.24 342 553.49 431 553.74 156 554 65 554.24 299 554.49 154 554.74 56 555 382 555.24 24 555.49 236 555.74 189 555.99 225 556.24 48 556.49 71 556.74 113 557 150 557.24 0 557.49 80 557.74 251 557.99 137 558.24 52 558.49 83 558.74 -56 558.99 83 559.24 -68 559.49 -94 559.74 -3 559.99 367 560.24 -122 560.49 91 560.74 -87 561 265 561.24 40 561.49 43 561.74 69 562 -66 562.24 166 562.49 -203 562.74 -54 563 83 563.24 193 563.49 59 563.74 -232 564 57 564.24 -122 564.49 135 564.74 -92 565 -25 565.24 78 565.49 11 565.74 60 565.99 -129 566.24 -100 566.49 -226 566.74 -80 567 -47 567.24 10 567.49 -213 567.74 -103 567.99 -9 568.24 -232 568.49 -224 568.74 -85 568.99 67 569.24 -9 569.49 184 569.74 -95 569.99 -58 570.24 -405 570.49 -186 570.74 -135 571 -533 571.24 -294 571.49 -280 571.74 -336 572 -289 572.24 -125 572.49 -314 572.74 -257 573 -338 573.24 -357 573.49 -345 573.74 -346 574 -295 574.24 -467 574.49 -173 574.74 -299 575 -328 575.24 -56 575.49 -329 575.74 -393 575.99 -387 576.24 -282 576.49 -98 576.74 -160 577 -292 577.24 -226 577.49 -295 577.74 -489 578 -310 578.24 -496 578.49 -144 578.74 -227 578.99 -343 579.24 -342 579.49 -310 579.74 -193 579.99 -377 580.24 -42 580.49 -342 580.74 -226 581 -343 581.24 -297 581.49 -257 581.74 -232 582 -270 582.24 -318 582.49 -316 582.74 -164 583 -290 583.24 -366 583.49 -202 583.74 -221 584 -426 584.24 -222 584.49 -187 584.74 -491 585 -256 585.24 -48 585.49 -285 585.74 -213 585.99 -388 586.24 -87 586.49 -288 586.74 -135 587 -227 587.24 -322 587.49 -328 587.74 -307 588 -368 588.24 -135 588.49 -246 588.74 -308 588.99 -132 589.24 -538 589.49 -441 589.74 -300 589.99 -447 590.24 -252 590.49 -426 590.74 -228 591 -272 591.24 -147 591.49 -156 591.74 -371 592 -242 592.24 -276 592.49 -317 592.74 -158 593 -200 593.24 -294 593.49 -368 593.74 -532 594 -444 594.24 -149 594.49 -201 594.74 -172 595 -236 595.24 -156 595.49 -612 595.74 -378 595.99 -432 596.24 -270 596.49 -216 596.74 -362 597 -387 597.24 -410 597.49 -177 597.74 -406 598 -132 598.24 -287 598.49 -226 598.74 -213 598.99 -58 599.24 -87 599.49 -237 599.74 -209 599.99 -338 600.24 -323 600.49 -321 600.74 -448 601 -235 601.24 -334 601.49 -380 601.74 -251 602 -464 602.24 -282 602.49 38 602.74 -439 603 -48 603.24 -80 603.49 -249 603.74 -204 604 -503 604.24 -418 604.49 -411 604.74 -91 605 -396 605.24 -148 605.49 -283 605.74 -163 605.99 -317 606.24 -397 606.49 -47 606.74 -435 607 20 607.24 -260 607.49 -233 607.74 -400 608 -123 608.24 -194 608.49 -213 608.74 -127 608.99 -350 609.24 -113 609.49 -260 609.74 -65 609.99 -221 610.24 -328 610.49 -246 610.74 -290 611 -125 611.24 -287 611.49 -168 611.74 -358 612 -105 612.24 -161 612.49 -351 612.74 -393 613 -301 613.24 -226 613.49 -325 613.74 -132 614 -279 614.24 -302 614.49 -298 614.74 -183 615 -161 615.24 -153 615.49 -124 615.74 -136 615.99 -140 616.24 -291 616.49 -334 616.74 -81 617 -159 617.24 -75 617.49 -50 617.74 -271 618 -242 618.24 -138 618.49 47 618.74 -142 618.99 -235 619.24 -135 619.49 -182 619.74 -379 619.99 -371 620.24 -229 620.49 -286 620.74 -292 621 -127 621.24 -137 621.49 -242 621.74 -132 622 -311 622.24 -260 622.49 -378 622.74 -35 623 -288 623.24 205 623.49 -268 623.74 -509 624 -263 624.24 -116 624.49 -239 624.74 -80 625 -120 625.24 -175 625.49 -77 625.74 -148 625.99 -424 626.24 -297 626.49 -224 626.74 -96 627 -366 627.24 -35 627.49 -137 627.74 -101 628 -275 628.24 -343 628.49 -228 628.74 -228 628.99 102 629.24 -394 629.49 -152 629.74 -190 629.99 -125 630.24 -340 630.49 -155 630.74 -157 631 -318 631.24 -158 631.49 -172 631.74 -185 632 -175 632.24 -101 632.49 -232 632.74 -420 633 -7 633.24 -13 633.49 -59 633.74 -224 634 -169 634.24 -193 634.49 -197 634.74 -140 635 -185 635.24 -77 635.49 5 635.74 -175 635.99 -286 636.24 -211 636.49 -437 636.74 -117 637 -251 637.24 -146 637.49 -96 637.74 -301 638 -155 638.24 -412 638.49 -106 638.74 -171 638.99 -312 639.24 -289 639.49 -135 639.74 -108 639.99 -272 640.24 -352 640.49 -232 640.74 -204 641 -345 641.24 -184 641.49 -84 641.74 -37 642 -251 642.24 -306 642.49 -115 642.74 -464 643 -115 643.24 -248 643.49 -84 643.74 -133 644 -277 644.24 -246 644.49 -276 644.74 -359 645 -262 645.24 -172 645.49 -226 645.74 -96 645.99 -172 646.24 12 646.49 -213 646.74 -185 647 -470 647.24 -289 647.49 -212 647.74 -68 648 -242 648.24 -193 648.49 -271 648.74 -77 648.99 -463 649.24 -134 649.49 -320 649.74 -279 649.99 -13 650.24 -153 650.49 -261 650.74 -104 651 -171 651.24 -163 651.49 -203 651.74 -183 652 -47 652.24 -152 652.49 -270 652.74 -240 653 -474 653.24 13 653.49 -308 653.74 -171 654 -235 654.24 -1 654.49 -299 654.74 -264 655 -76 655.24 -276 655.49 -406 655.74 -245 655.99 -280 656.24 -387 656.49 -309 656.74 -138 657 -172 657.24 -360 657.49 -55 657.74 -97 658 -135 658.25 -327 658.5 -185 658.75 -234 659 -307 659.25 -110 659.5 -67 659.75 -212 660 -96 660.25 -221 660.5 65 660.75 -349 661 -339 661.25 -374 661.5 -86 661.75 -220 662 -376 662.25 -236 662.5 -183 662.75 -279 663 -251 663.25 -87 663.5 -210 663.75 -64 664 -99 664.25 -382 664.5 -184 664.75 -54 665 -162 665.25 -297 665.5 -170 665.75 -239 666 -217 666.25 -119 666.5 -143 666.75 -195 667 -108 667.25 -280 667.5 -103 667.75 -242 668 -218 668.25 -199 668.5 -145 668.75 -135 669 -405 669.25 -233 669.5 -9 669.75 -274 670 -162 670.25 -125 670.5 -156 670.75 -156 671 -416 671.25 -116 671.5 -129 671.75 -142 672 -204 672.25 -63 672.5 -88 672.75 -300 673 -168 673.25 -202 673.5 -132 673.75 -339 674 -72 674.25 -358 674.5 -354 674.75 -349 675 -308 675.25 -169 675.5 -64 675.75 -205 676 -113 676.25 -267 676.5 -191 676.75 -311 677 -330 677.25 -114 677.5 -165 677.75 -203 678 -156 678.25 -327 678.5 -325 678.75 -123 679 -125 679.25 -346 679.5 -228 679.75 -160 680 -319 680.25 -92 680.5 -38 680.75 -265 681 1 681.25 -272 681.5 -190 681.75 -251 682 -126 682.25 -108 682.5 -193 682.75 -233 683 -125 683.25 -34 683.5 -172 683.75 -248 684 -144 684.25 -133 684.5 -87 684.75 -226 685 -306 685.25 -120 685.5 -131 685.75 -136 686 -103 686.25 -106 686.5 -166 686.75 -285 687 -175 687.25 -200 687.5 -326 687.75 -165 688 -344 688.25 -37 688.5 -268 688.75 -31 689 -5 689.25 -25 689.5 -118 689.75 -294 690 -87 690.25 -128 690.5 12 690.75 -133 691 -84 691.25 -309 691.5 -213 691.75 -129 692 -186 692.25 -240 692.5 -17 692.75 -199 693 -204 693.25 -159 693.5 -104 693.75 -270 694 -300 694.25 9 694.5 -170 694.75 -295 695 -60 695.25 -116 695.5 -58 695.75 -153 696 -148 696.25 -77 696.5 -44 696.75 -100 697 -289 697.25 -3 697.5 174 697.75 38 698 3 698.25 15 698.5 -25 698.75 -95 699 -15 699.25 -175 699.5 -32 699.75 -21 700 -77