# Emission spectrum of in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on in 1995 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 570 173918 571 180100 572 185944 573 192397 574 197706 575 200969 576 204656 577 206787 578 208099 579 208086 580 209801 581 211611 582 213918 583 222374 584 233843 585 249396 586 272898 587 303541 588 346211 589 393540 590 460710 591 538293 592 654881 593 796013 594 1002642 595 1260599 596 1643383 597 2103024 598 2740153 599 3412417 600 4251738 601 5118785 602 5960705 603 6560121 604 7009219 605 7201701 606 7207970 607 7067292 608 6753823 609 6375105 610 5937629 611 5531991 612 5108215 613 4763068 614 4422590 615 4170621 616 3935083 617 3726169 618 3512441 619 3333077 620 3121838 621 2953518 622 2761908 623 2613343 624 2449386 625 2317840 626 2200114 627 2123271 628 2077831 629 2068962 630 2069702 631 2101623 632 2148857 633 2209092 634 2278989 635 2350630 636 2431361 637 2523532 638 2628894 639 2745340 640 2878303 641 3042173 642 3222685 643 3399199 644 3604872 645 3835310 646 4110286 647 4421523 648 4815948 649 5262024 650 5819649 651 6393871 652 7048183 653 7662818 654 8311499 655 8843328 656 9398332 657 9939135 658 10467860 659 10938890 660 11420060 661 11826660 662 12168590 663 12335580 664 12371970 665 12224130 666 11914270 667 11482950 668 10851440 669 10191020 670 9386173 671 8650351 672 7809674 673 7050094 674 6307777 675 5688997 676 5080460 677 4589715 678 4117992 679 3764683 680 3394131 681 3088219 682 2801171 683 2554689 684 2296362 685 2067985 686 1860965 687 1707622 688 1535373 689 1388955 690 1255073 691 1146409 692 1052446 693 975171 694 898666 695 839474 696 778334 697 736619 698 695798 699 665993 700 639522 701 619703 702 601587 703 594175 704 583156 705 582077 706 569643 707 572245 708 573621 709 572081 710 572882 711 570183 712 576511 713 582258 714 582846 715 586809 716 592529 717 591134 718 592561 719 596867 720 598161 721 606244 722 601534 723 593994 724 590458 725 587250 726 585753 727 575496 728 573199 729 556701 730 554745 731 539973 732 521650 733 509254 734 489961 735 473199 736 456886 737 433854 738 416139 739 391352 740 378851 741 357395 742 337499 743 317490 744 296194 745 278845 746 257806 747 241875 748 221245 749 209181 750 191062 751 183302 752 170023 753 159740 754 147598 755 136403 756 128745 757 121438 758 113453 759 108410 760 103657 761 96377 762 90412 763 86912 764 82837 765 79346 766 77374 767 74065 768 70904 769 69186 770 67562 771 63636 772 62464 773 60323 774 59210 775 58570 776 57279 777 58287 778 55242 779 54703 780 50995 781 51895 782 54386 783 54268 784 50318 785 51602 786 50965 787 50614 788 50231 789 49293 790 48976 791 50021 792 48076 793 50379 794 48688 795 48204 796 49072 797 48822 798 46767 799 47106 800 44072