# Emission spectrum of in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on in 1994 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 570 81448 571 84477 572 89953 573 95334 574 104696 575 113845 576 127970 577 147237 578 174163 579 207690 580 248023 581 293513 582 349121 583 402985 584 467733 585 531514 586 597150 587 653113 588 706742 589 749328 590 785963 591 811705 592 832637 593 848310 594 852232 595 854404 596 849274 597 843183 598 833452 599 822391 600 804316 601 785414 602 765209 603 742708 604 720141 605 705204 606 686004 607 675755 608 664213 609 658788 610 655017 611 657150 612 661452 613 672486 614 684974 615 702823 616 723481 617 750571 618 778987 619 810081 620 851431 621 895591 622 947733 623 1002349 624 1063793 625 1135364 626 1220481 627 1308476 628 1422068 629 1533317 630 1671592 631 1801891 632 1944863 633 2100560 634 2252774 635 2400873 636 2563252 637 2720863 638 2868585 639 2989574 640 3114111 641 3216597 642 3285453 643 3313782 644 3302126 645 3267759 646 3189996 647 3088646 648 2949214 649 2800878 650 2621257 651 2467290 652 2284092 653 2122208 654 1952406 655 1820291 656 1684791 657 1542578 658 1416207 659 1303765 660 1186161 661 1088091 662 989946 663 913768 664 831169 665 754475 666 685779 667 629094 668 574356 669 527465 670 477009 671 438766 672 402277 673 369068 674 336681 675 314690 676 291481 677 270415 678 251816 679 237004 680 228219 681 215623 682 206984 683 199411 684 191061 685 185372 686 177896 687 175768 688 171878 689 168804 690 164886 691 164482 692 163251 693 161486 694 159180 695 158420 696 154728 697 153923 698 152182 699 151675 700 148663 701 148249 702 146236 703 144267 704 140705 705 140386 706 137061 707 134113 708 130909 709 124651 710 123393 711 119358 712 116418 713 113162 714 106678 715 102037 716 98609 717 96383 718 90401 719 86687 720 81933 721 77766 722 72925 723 69722 724 65835 725 61632 726 57218 727 56008 728 52097 729 48660 730 47535 731 43834 732 41875 733 40398 734 36082 735 35122 736 35257 737 32045 738 30722 739 28121 740 27532 741 26769 742 26086 743 26759 744 23675 745 22552 746 21860 747 20542 748 21580 749 19805 750 19715 751 19627 752 18762 753 18236 754 18170 755 16480 756 17073 757 16077 758 16969 759 16402 760 15761 761 15784 762 16188 763 15731 764 15321 765 15448 766 14414 767 15628 768 14331 769 14609 770 13444 771 14649 772 14006 773 14922 774 13338 775 13921 776 12442 777 13700 778 13407 779 13847 780 13650 781 12391 782 12271 783 12257 784 11591 785 12408 786 11683 787 11572 788 11189 789 11398 790 10399 791 11264 792 11347 793 10588 794 10319 795 9676 796 9405 797 9271 798 11133 799 7991 800 8929