# Optical absorption spectrum of Zinc tetramesitylporphyrin, [ZnTMP] in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by R. W. Wagner in 1994 using a Cary 3. # The absorption values were collected using a spectral bandwidth of 1.0 nm, a signal averaging time of 0.133 sec, a data interval of 0.25 nm, and a scan rate of 112.5 nm/min. # # These measurements were scaled to make the molar extinction coefficient match # the value of 385000 cm-1/M at 420.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Dixon, J. M., M. Taniguchi and J. S. Lindsey (2005), "PhotochemCAD 2. A Refined Program with Accompanying Spectral Databases for Photochemical Calculations, Photochem. Photobiol., 81, 212-213. # ##Wavelength (nm) Molar Extinction (cm-1/M) 349.75 9772 350 9320 350.25 6715 350.5 7773 350.75 9453 351 10084 351.25 8785 351.5 9195 351.75 7455 352 7454 352.25 9168 352.5 9501 352.75 10090 353 7150 353.25 7826 353.5 11125 353.75 8753 354 8334 354.25 8158 354.5 9016 354.75 8914 355 8548 355.25 9874 355.5 8594 355.75 8199 356 6422 356.25 8093 356.5 10152 356.75 8823 357 7680 357.25 6607 357.5 8756 357.75 8643 358 7020 358.25 7249 358.5 7703 358.75 7645 359 8028 359.25 7444 359.5 8337 359.75 7675 360 6320 360.25 7818 360.5 6530 360.75 8119 361 6850 361.25 6321 361.5 5120 361.75 5911 362 7661 362.25 7844 362.5 5401 362.75 7651 363 7529 363.25 8043 363.5 7494 363.75 6715 364 6316 364.25 5414 364.5 7478 364.75 6589 365 5614 365.25 7451 365.5 6041 365.75 7032 366 6494 366.25 5691 366.5 7098 366.75 7063 367 5340 367.25 6235 367.5 5150 367.75 6162 368 6381 368.25 4583 368.5 4856 368.75 5945 369 4873 369.25 5338 369.5 6360 369.75 7564 370 6216 370.25 5735 370.5 6302 370.75 5383 371 4415 371.25 7324 371.5 6441 371.75 6461 372 5226 372.25 4342 372.5 6261 372.75 4952 373 6086 373.25 7074 373.5 5153 373.75 4480 374 7420 374.25 5071 374.5 6316 374.75 6219 375 5205 375.25 5003 375.5 7345 375.75 4825 376 5789 376.25 4378 376.5 6408 376.75 5218 377 6433 377.25 6669 377.5 5166 377.75 6470 378 6799 378.25 6198 378.5 6102 378.75 6249 379 4544 379.25 5254 379.5 4325 379.75 6657 380 6177 380.25 4648 380.5 6454 380.75 5486 381 6936 381.25 4586 381.5 5516 381.75 5922 382 3919 382.25 5249 382.5 6476 382.75 6347 383 6263 383.25 7020 383.5 5800 383.75 5805 384 7185 384.25 5514 384.5 6099 384.75 6093 385 6728 385.25 6243 385.5 7110 385.75 5796 386 7540 386.25 7389 386.5 5791 386.75 6023 387 6939 387.25 6944 387.5 7651 387.75 6879 388 5536 388.25 8440 388.5 8703 388.75 6733 389 8353 389.25 8713 389.5 8586 389.75 10546 390 9034 390.25 9523 390.5 8861 390.75 11280 391 11097 391.25 10156 391.5 10895 391.75 11389 392 11306 392.25 12930 392.5 13155 392.75 13230 393 13709 393.25 14657 393.5 16417 393.75 15671 394 16205 394.25 17203 394.5 18543 394.75 18611 395 18538 395.25 19862 395.5 21241 395.75 22482 396 25204 396.25 24888 396.5 24520 396.75 25530 397 25689 397.25 28266 397.5 26555 397.75 26710 398 26945 398.25 28269 398.5 27498 398.75 29233 399 29310 399.25 29887 399.5 29770 399.75 30984 400 30560 400.25 29772 400.5 32353 400.75 28933 401 30931 401.25 29722 401.5 29853 401.75 31932 402 29926 402.25 29527 402.5 30049 402.75 29990 403 28834 403.25 28089 403.5 28510 403.75 27758 404 28246 404.25 28418 404.5 28495 404.75 28446 405 29403 405.25 28713 405.5 29147 405.75 29319 406 30115 406.25 30583 406.5 30080 406.75 31560 407 31706 407.25 31196 407.5 33747 407.75 33871 408 35351 408.25 37172 408.5 37059 408.75 37547 409 40817 409.25 44243 409.5 46155 409.75 48622 410 49934 410.25 53257 410.5 56037 410.75 60071 411 63235 411.25 66683 411.5 70096 411.75 74708 412 78162 412.25 84644 412.5 88220 412.75 91498 413 97114 413.25 103765 413.5 106689 413.75 113755 414 120554 414.25 125434 414.5 131948 414.75 137187 415 143718 415.25 149619 415.5 158551 415.75 166687 416 177700 416.25 189173 416.5 201666 416.75 213601 417 226833 417.25 241428 417.5 256023 417.75 269757 418 284623 418.25 298573 418.5 314524 418.75 328704 419 341074 419.25 352879 419.5 365086 419.75 376012 420 385000 420.25 393661 420.5 397632 420.75 403871 421 409430 421.25 409433 421.5 411217 421.75 408976 422 406635 422.25 403045 422.5 396848 422.75 392646 423 382576 423.25 376255 423.5 365407 423.75 353358 424 340978 424.25 328720 424.5 315304 424.75 303519 425 290605 425.25 275083 425.5 264492 425.75 251046 426 237261 426.25 224980 426.5 213230 426.75 200319 427 188191 427.25 176596 427.5 167850 427.75 156913 428 149127 428.25 137508 428.5 128781 428.75 121502 429 114602 429.25 107793 429.5 101934 429.75 93937 430 88124 430.25 81761 430.5 77315 430.75 72466 431 66831 431.25 64718 431.5 59252 431.75 57055 432 53531 432.25 49015 432.5 47110 432.75 43418 433 41001 433.25 39183 433.5 36371 433.75 34283 434 32272 434.25 30227 434.5 30460 434.75 26910 435 25878 435.25 23520 435.5 21404 435.75 20344 436 19037 436.25 17513 436.5 16006 436.75 14366 437 14678 437.25 14019 437.5 12754 437.75 12873 438 11635 438.25 13113 438.5 10235 438.75 11475 439 9543 439.25 9694 439.5 9507 439.75 8529 440 8989 440.25 7948 440.5 8366 440.75 7006 441 7390 441.25 7955 441.5 5934 441.75 6068 442 5397 442.25 5893 442.5 4971 442.75 4817 443 5241 443.25 4794 443.5 4656 443.75 4180 444 3825 444.25 4371 444.5 3504 444.75 4931 445 4349 445.25 3094 445.5 3009 445.75 3247 446 3390 446.25 2842 446.5 3035 446.75 2338 447 2604 447.25 2525 447.5 2609 447.75 2859 448 1213 448.25 2660 448.5 1802 448.75 2867 449 2039 449.25 1557 449.5 2396 449.75 1579 450 1769 450.25 1933 450.5 1236 450.75 1449 451 1447 451.25 2106 451.5 1883 451.75 1666 452 1999 452.25 1542 452.5 1676 452.75 1955 453 1149 453.25 918 453.5 547 453.75 1328 454 1834 454.25 1033 454.5 884 454.75 354 455 105 455.25 782 455.5 953 455.75 1441 456 1371 456.25 875 456.5 788 456.75 938 457 295 457.25 692 457.5 1045 457.75 779 458 650 458.25 1732 458.5 -69 458.75 2238 459 1028 459.25 478 459.5 1014 459.75 1149 460 777 460.25 829 460.5 722 460.75 747 461 764 461.25 1133 461.5 970 461.75 426 462 473 462.25 1019 462.5 1857 462.75 1062 463 1399 463.25 1446 463.5 1523 463.75 295 464 891 464.25 1485 464.5 236 464.75 313 465 809 465.25 4 465.5 1137 465.75 610 466 477 466.25 681 466.5 1244 466.75 1393 467 600 467.25 1836 467.5 1210 467.75 1003 468 999 468.25 559 468.5 -392 468.75 375 469 872 469.25 782 469.5 1016 469.75 1338 470 783 470.25 897 470.5 1325 470.75 103 471 1910 471.25 903 471.5 938 471.75 552 472 831 472.25 1196 472.5 1898 472.75 748 473 1331 473.25 355 473.5 1536 473.75 661 474 841 474.25 655 474.5 1514 474.75 518 475 1240 475.25 246 475.5 1497 475.75 977 476 629 476.25 1487 476.5 1383 476.75 1574 477 656 477.25 1353 477.5 1476 477.75 932 478 2189 478.25 1236 478.5 1670 478.75 1179 479 998 479.25 866 479.5 1351 479.75 1593 480 944 480.25 1540 480.5 577 480.75 922 481 1589 481.25 609 481.5 2162 481.75 1242 482 1651 482.25 697 482.5 1275 482.75 1962 483 1510 483.25 1258 483.5 816 483.75 1358 484 1326 484.25 1278 484.5 474 484.75 1217 485 1601 485.25 1280 485.5 1107 485.75 454 486 2041 486.25 1071 486.5 1909 486.75 1639 487 1179 487.25 1300 487.5 1505 487.75 583 488 939 488.25 620 488.5 1601 488.75 1547 489 1965 489.25 1351 489.5 1078 489.75 1850 490 1562 490.25 1134 490.5 1628 490.75 1094 491 593 491.25 1347 491.5 722 491.75 763 492 1061 492.25 1673 492.5 1918 492.75 1580 493 1429 493.25 1477 493.5 1642 493.75 1762 494 853 494.25 987 494.5 949 494.75 1787 495 2195 495.25 1401 495.5 1510 495.75 2065 496 1871 496.25 2203 496.5 1301 496.75 1292 497 1936 497.25 1260 497.5 826 497.75 1679 498 891 498.25 1899 498.5 1667 498.75 1831 499 1665 499.25 2413 499.5 2167 499.75 2064 500 1985 500.25 1670 500.5 1309 500.75 1608 501 2169 501.25 2039 501.5 2555 501.75 1202 502 1701 502.25 2533 502.5 1812 502.75 2349 503 1371 503.25 2270 503.5 1908 503.75 2350 504 1068 504.25 2837 504.5 1559 504.75 1246 505 1870 505.25 2302 505.5 1786 505.75 2270 506 2073 506.25 2598 506.5 2700 506.75 2205 507 2152 507.25 2952 507.5 2411 507.75 2905 508 2814 508.25 2928 508.5 2431 508.75 2837 509 2646 509.25 1395 509.5 3257 509.75 1760 510 2309 510.25 1726 510.5 2217 510.75 2658 511 2049 511.25 2698 511.5 3123 511.75 2716 512 1539 512.25 1687 512.5 2968 512.75 2167 513 1912 513.25 2692 513.5 2298 513.75 2547 514 2550 514.25 2406 514.5 2323 514.75 1429 515 1814 515.25 3235 515.5 2132 515.75 2305 516 1616 516.25 2990 516.5 1726 516.75 2402 517 571 517.25 2271 517.5 2312 517.75 2019 518 2218 518.25 2240 518.5 2654 518.75 1794 519 2181 519.25 1993 519.5 2568 519.75 2521 520 1484 520.25 2013 520.5 2111 520.75 2124 521 1831 521.25 3015 521.5 2099 521.75 809 522 2370 522.25 2102 522.5 1592 522.75 1923 523 2404 523.25 2077 523.5 1728 523.75 2608 524 2622 524.25 3179 524.5 2280 524.75 1707 525 2698 525.25 2796 525.5 2592 525.75 2427 526 2561 526.25 2341 526.5 3110 526.75 2602 527 2504 527.25 2590 527.5 3144 527.75 3635 528 3007 528.25 3698 528.5 3182 528.75 3074 529 3082 529.25 2959 529.5 3766 529.75 3668 530 3510 530.25 3633 530.5 4119 530.75 4097 531 4149 531.25 5440 531.5 4465 531.75 4249 532 4822 532.25 4903 532.5 5096 532.75 5192 533 6402 533.25 5840 533.5 5925 533.75 5718 534 5909 534.25 5747 534.5 6520 534.75 5288 535 7007 535.25 6531 535.5 6738 535.75 7239 536 7745 536.25 7070 536.5 7957 536.75 7694 537 6957 537.25 8434 537.5 9301 537.75 8792 538 9065 538.25 9842 538.5 9490 538.75 9850 539 9782 539.25 10171 539.5 11082 539.75 10813 540 11355 540.25 10728 540.5 11511 540.75 11360 541 12056 541.25 12744 541.5 13311 541.75 13434 542 13207 542.25 13700 542.5 13299 542.75 13695 543 13534 543.25 15255 543.5 14221 543.75 15007 544 15617 544.25 16381 544.5 15989 544.75 15807 545 15731 545.25 16859 545.5 16952 545.75 15762 546 17180 546.25 16881 546.5 16654 546.75 17758 547 18183 547.25 17602 547.5 17625 547.75 18349 548 17817 548.25 18575 548.5 19214 548.75 19336 549 18454 549.25 18277 549.5 18732 549.75 18193 550 18210 550.25 19078 550.5 17295 550.75 17829 551 17794 551.25 17787 551.5 17029 551.75 17303 552 17194 552.25 17421 552.5 16349 552.75 16559 553 16158 553.25 16229 553.5 15216 553.75 14977 554 14572 554.25 14674 554.5 14610 554.75 15139 555 13954 555.25 13397 555.5 13901 555.75 12795 556 12801 556.25 11885 556.5 11739 556.75 10652 557 11763 557.25 10936 557.5 9752 557.75 10136 558 10066 558.25 9427 558.5 9374 558.75 8511 559 9424 559.25 9001 559.5 8322 559.75 8610 560 8426 560.25 7547 560.5 8376 560.75 7410 561 7557 561.25 6888 561.5 6602 561.75 5866 562 7119 562.25 5876 562.5 6062 562.75 5963 563 5727 563.25 5670 563.5 4526 563.75 5357 564 5427 564.25 4994 564.5 5144 564.75 3874 565 4428 565.25 4541 565.5 3527 565.75 4175 566 3579 566.25 3210 566.5 4278 566.75 3273 567 2387 567.25 3567 567.5 2947 567.75 3196 568 3068 568.25 2700 568.5 2650 568.75 3070 569 1460 569.25 2082 569.5 3338 569.75 2911 570 2992 570.25 2316 570.5 2571 570.75 1324 571 2191 571.25 2887 571.5 2215 571.75 1743 572 1721 572.25 2089 572.5 1781 572.75 1526 573 2164 573.25 2353 573.5 1656 573.75 821 574 1597 574.25 2275 574.5 1094 574.75 1079 575 1716 575.25 2291 575.5 1323 575.75 111 576 1408 576.25 1893 576.5 1980 576.75 1928 577 1938 577.25 1333 577.5 1800 577.75 1481 578 1732 578.25 1128 578.5 195 578.75 1373 579 927 579.25 1876 579.5 1118 579.75 879 580 1962 580.25 849 580.5 1622 580.75 513 581 1368 581.25 2006 581.5 936 581.75 1618 582 1955 582.25 1005 582.5 1656 582.75 1183 583 2110 583.25 1997 583.5 1592 583.75 987 584 1376 584.25 2836 584.5 2497 584.75 3143 585 1402 585.25 1467 585.5 2279 585.75 1308 586 1107 586.25 1545 586.5 1190 586.75 1928 587 575 587.25 1564 587.5 2483 587.75 1017 588 1300 588.25 1536 588.5 1805 588.75 2040 589 1769 589.25 1959 589.5 895 589.75 1802 590 1474 590.25 1440 590.5 1162 590.75 1891 591 1774 591.25 1245 591.5 1457 591.75 2212 592 2128 592.25 1487 592.5 1089 592.75 1467 593 496 593.25 1475 593.5 2099 593.75 2007 594 548 594.25 2281 594.5 1096 594.75 1218 595 1596 595.25 782 595.5 678 595.75 278 596 -188 596.25 345 596.5 -252 596.75 1070 597 330 597.25 1300 597.5 390 597.75 623 598 1151 598.25 394 598.5 952 598.75 43 599 838 599.25 1453 599.5 881 599.75 774 600 867 600.25 169 600.5 833 600.75 714 601 792 601.25 1243 601.5 612 601.75 286 602 -399 602.25 -123 602.5 -216 602.75 343 603 944 603.25 841 603.5 463 603.75 137 604 888 604.25 149 604.5 971 604.75 1311 605 474 605.25 500 605.5 -450 605.75 701 606 975 606.25 439 606.5 89 606.75 710 607 906 607.25 160 607.5 232 607.75 544 608 -95 608.25 90 608.5 765 608.75 643 609 475 609.25 221 609.5 193 609.75 563 610 1550 610.25 813 610.5 326 610.75 551 611 -198 611.25 -779 611.5 216 611.75 -305 612 331 612.25 -248 612.5 112 612.75 159 613 871 613.25 429 613.5 879 613.75 188 614 -449 614.25 1195 614.5 233 614.75 140 615 -84 615.25 830 615.5 56 615.75 48 616 -687 616.25 -1193 616.5 143 616.75 -534 617 300 617.25 -63 617.5 -1101 617.75 536 618 957 618.25 157 618.5 288 618.75 -395 619 548 619.25 -594 619.5 -57 619.75 465 620 604 620.25 685 620.5 933 620.75 -668 621 -531 621.25 -1241 621.5 474 621.75 848 622 -1253 622.25 0 622.5 541 622.75 -659 623 490 623.25 -850 623.5 -666 623.75 448 624 127 624.25 -1183 624.5 229 624.75 -270 625 36 625.25 625 625.5 1013 625.75 -504 626 371 626.25 -49 626.5 892 626.75 170 627 -512 627.25 1055 627.5 1056 627.75 -380 628 584 628.25 -38 628.5 -136 628.75 -326 629 507 629.25 104 629.5 -513 629.75 64 630 171 630.25 44 630.5 610 630.75 -154 631 -174 631.25 1018 631.5 853 631.75 -95 632 -78 632.25 -129 632.5 -50 632.75 445 633 56 633.25 -516 633.5 400 633.75 822 634 270 634.25 1628 634.5 1118 634.75 1001 635 478 635.25 -121 635.5 43 635.75 547 636 544 636.25 931 636.5 609 636.75 678 637 270 637.25 498 637.5 -185 637.75 -156 638 58 638.25 467 638.5 636 638.75 -1073 639 -356 639.25 235 639.5 241 639.75 1010 640 -73 640.25 460 640.5 1087 640.75 -26 641 -839 641.25 672 641.5 -600 641.75 -172 642 -343 642.25 -185 642.5 15 642.75 418 643 -322 643.25 378 643.5 336 643.75 97 644 -157 644.25 575 644.5 1056 644.75 -281 645 336 645.25 -818 645.5 1180 645.75 86 646 1480 646.25 -189 646.5 665 646.75 -118 647 554 647.25 486 647.5 871 647.75 -765 648 938 648.25 -992 648.5 -591 648.75 130 649 683 649.25 -644 649.5 -144 649.75 -91 650 861 650.25 606 650.5 222 650.75 822 651 -701 651.25 -47 651.5 785 651.75 -26 652 381 652.25 632 652.5 165 652.75 -805 653 96 653.25 91 653.5 -465 653.75 -38 654 586 654.25 -43 654.5 469 654.75 -267 655 785 655.25 -134 655.5 795 655.75 -133 656 1063 656.25 1201 656.5 -30 656.75 354 657 59 657.25 250 657.5 -404 657.75 172 658 381 658.25 170 658.5 -195 658.75 715 659 524 659.25 913 659.5 215 659.75 580 660 -622 660.25 333 660.5 981 660.75 465 661 312 661.25 747 661.5 -455 661.75 741 662 -544 662.25 1238 662.5 256 662.75 -791 663 208 663.25 -560 663.5 178 663.75 416 664 -1029 664.25 572 664.5 1843 664.75 1123 665 731 665.25 -475 665.5 221 665.75 -887 666 1294 666.25 687 666.5 1234 666.75 852 667 -233 667.25 980 667.5 272 667.75 211 668 1052 668.25 -303 668.5 1802 668.75 -821 669 -93 669.25 -752 669.5 -139 669.75 -360 670 165 670.25 44 670.5 -256 670.75 147 671 -407 671.25 282 671.5 -687 671.75 413 672 -846 672.25 39 672.5 -134 672.75 680 673 9 673.25 61 673.5 -976 673.75 519 674 -835 674.25 752 674.5 334 674.75 923 675 -971 675.25 -154 675.5 -434 675.75 -424 676 414 676.25 -115 676.5 -1301 676.75 797 677 56 677.25 1229 677.5 1306 677.75 565 678 -573 678.25 -79 678.5 808 678.75 -580 679 -54 679.25 86 679.5 452 679.75 154 680 111 680.25 -721 680.5 578 680.75 -265 681 14 681.25 56 681.5 -170 681.75 502 682 81 682.25 545 682.5 -42 682.75 405 683 418 683.25 -378 683.5 51 683.75 -577 684 56 684.25 -102 684.5 -113 684.75 448 685 231 685.25 -831 685.5 58 685.75 142 686 429 686.25 -230 686.5 790 686.75 -293 687 371 687.25 18 687.5 373 687.75 582 688 374 688.25 -660 688.5 462 688.75 181 689 47 689.25 288 689.5 139 689.75 572 690 -465 690.25 156 690.5 -305 690.75 651 691 492 691.25 -256 691.5 -409 691.75 998 692 -427 692.25 -223 692.5 -440 692.75 255 693 -653 693.25 247 693.5 1096 693.75 636 694 725 694.25 554 694.5 -1044 694.75 147 695 1073 695.25 751 695.5 -212 695.75 35 696 1341 696.25 349 696.5 1198 696.75 -545 697 575 697.25 492 697.5 329 697.75 1781 698 -813 698.25 1381 698.5 -1680 698.75 -1246 699 540 699.25 440 699.5 122 699.75 217 700 1245