# Emission spectrum of in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on in 1994 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 570 117414 571 127138 572 138303 573 150620 574 173439 575 200957 576 239938 577 288582 578 354987 579 432663 580 518222 581 625813 582 754242 583 887096 584 1043283 585 1191908 586 1362479 587 1519010 588 1682142 589 1823023 590 1933119 591 2038088 592 2115775 593 2170668 594 2192058 595 2207565 596 2196096 597 2182915 598 2150959 599 2128987 600 2065534 601 2014407 602 1963899 603 1889277 604 1837656 605 1772373 606 1723475 607 1663467 608 1623001 609 1570506 610 1531637 611 1492239 612 1471387 613 1437166 614 1423640 615 1421793 616 1415272 617 1424184 618 1443073 619 1458551 620 1488555 621 1539991 622 1582993 623 1645190 624 1739126 625 1825188 626 1907114 627 2041655 628 2174101 629 2302632 630 2463441 631 2636584 632 2807793 633 3024437 634 3200719 635 3422646 636 3644890 637 3808960 638 4035838 639 4187568 640 4357808 641 4484053 642 4609353 643 4700377 644 4716840 645 4741249 646 4721183 647 4702064 648 4590178 649 4481643 650 4329332 651 4181141 652 3977811 653 3811487 654 3597555 655 3412367 656 3203974 657 2999231 658 2811616 659 2620596 660 2429475 661 2262125 662 2085010 663 1941673 664 1789955 665 1665352 666 1536776 667 1427489 668 1309124 669 1229114 670 1124867 671 1046743 672 954909 673 882957 674 820092 675 752821 676 694328 677 655995 678 608273 679 576886 680 531430 681 509218 682 481130 683 455785 684 429430 685 416584 686 398226 687 384436 688 371496 689 363151 690 349396 691 344967 692 337743 693 330809 694 324999 695 319851 696 319171 697 317215 698 311189 699 310831 700 307461 701 309289 702 310468 703 307114 704 308597 705 305917 706 303191 707 301415 708 299293 709 299251 710 299631 711 292778 712 290434 713 289433 714 281810 715 282020 716 275385 717 270356 718 264780 719 256854 720 249246 721 236748 722 227570 723 217281 724 207275 725 195535 726 186725 727 176808 728 163274 729 155148 730 148474 731 137247 732 132360 733 124149 734 118409 735 110568 736 106395 737 98722 738 93834 739 88214 740 82930 741 77866 742 75834 743 68893 744 67742 745 62722 746 58872 747 56161 748 54288 749 51881 750 49680 751 48326 752 44738 753 44852 754 42378 755 39073 756 41658 757 39256 758 37176 759 34586 760 36129 761 34718 762 34702 763 31902 764 32142 765 30781 766 32441 767 29100 768 29520 769 32120 770 28599 771 29518 772 29794 773 28259 774 28077 775 27952 776 28184 777 27168 778 27436 779 27722 780 26560 781 25441 782 25480 783 26030 784 24861 785 24078 786 25075 787 24735 788 22868 789 23929 790 24418 791 22065 792 22446 793 21808 794 20042 795 20629 796 21069 797 19929 798 19709 799 20140 800 20704