# Emission spectrum of in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on in 1994 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 570 2105 571 2162 572 2401 573 2695 574 2827 575 3300 576 3527 577 3749 578 4690 579 5400 580 6228 581 7520 582 8629 583 10834 584 12544 585 14271 586 16651 587 19535 588 21900 589 24448 590 27185 591 29920 592 32996 593 35678 594 38043 595 41571 596 45240 597 46567 598 48742 599 51789 600 53337 601 56562 602 59156 603 62748 604 66271 605 68519 606 72215 607 74261 608 77053 609 78350 610 78244 611 77352 612 77458 613 76822 614 75662 615 75401 616 76879 617 78361 618 80813 619 83524 620 89018 621 97239 622 105442 623 117606 624 135910 625 162157 626 193682 627 235527 628 292871 629 359637 630 448056 631 554548 632 697450 633 874577 634 1098383 635 1385381 636 1780123 637 2233085 638 2845464 639 3568762 640 4397512 641 5391379 642 6370073 643 7437968 644 8394428 645 9243642 646 9996511 647 10549240 648 10962830 649 11177050 650 11065300 651 11065290 652 10707150 653 10477680 654 10023080 655 9623491 656 9244648 657 8789952 658 8369260 659 7951128 660 7519445 661 7124839 662 6742333 663 6363512 664 5919053 665 5563337 666 5215950 667 4866296 668 4552797 669 4271980 670 3988350 671 3757356 672 3524572 673 3340419 674 3179566 675 3051291 676 2922002 677 2836655 678 2743432 679 2729183 680 2679843 681 2667901 682 2661087 683 2679094 684 2692248 685 2744230 686 2779080 687 2804676 688 2856865 689 2906964 690 2973207 691 3009554 692 3119110 693 3195052 694 3320163 695 3483106 696 3656266 697 3885742 698 4159752 699 4440896 700 4794377 701 5109471 702 5461524 703 5846272 704 6192120 705 6502283 706 6859436 707 7151314 708 7450498 709 7767247 710 8029236 711 8358734 712 8616248 713 8792434 714 9093546 715 9204709 716 9371053 717 9385807 718 9348190 719 9216655 720 8929841 721 8629754 722 8325765 723 7886176 724 7504669 725 7031468 726 6619329 727 6209028 728 5845184 729 5415953 730 5036176 731 4664731 732 4341919 733 4026814 734 3740315 735 3452786 736 3189554 737 2989127 738 2733284 739 2560772 740 2371006 741 2172679 742 2030480 743 1869299 744 1733007 745 1584089 746 1466757 747 1355844 748 1251223 749 1170726 750 1089346 751 1020363 752 956924 753 908243 754 862815 755 813412 756 766352 757 726570 758 693782 759 673247 760 639442 761 625507 762 603066 763 589464 764 574755 765 563624 766 544923 767 544588 768 530731 769 525141 770 526050 771 522680 772 524181 773 518701 774 514489 775 518175 776 514043 777 521173 778 518744 779 519335 780 516574 781 513093 782 511476 783 517108 784 518991 785 506370 786 509147 787 514507 788 504603 789 503794 790 505263 791 495945 792 486906 793 483195 794 470938 795 462570 796 457698 797 434602 798 431050 799 425936 800 405885