# Emission spectrum of in water, 0.1 M phosphate buffer, pH 7 # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on in the summer of 1995 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 280 379 280.5 396 281 403 281.5 416 282 442 282.5 424 283 414 283.5 409 284 432 284.5 415 285 370 285.5 430 286 373 286.5 418 287 445 287.5 460 288 477 288.5 508 289 527 289.5 557 290 632 290.5 720 291 768 291.5 894 292 943 292.5 1295 293 1377 293.5 2052 294 2467 294.5 3209 295 3870 295.5 4803 296 5425 296.5 6351 297 6824 297.5 7433 298 7660 298.5 7641 299 7727 299.5 7285 300 7263 300.5 7255 301 7268 301.5 7432 302 7623 302.5 8090 303 8693 303.5 9739 304 10254 304.5 11501 305 12352 305.5 13921 306 14928 306.5 16663 307 18096 307.5 20485 308 21555 308.5 23645 309 25314 309.5 27908 310 29523 310.5 32163 311 34269 311.5 37922 312 39409 312.5 42613 313 44990 313.5 49273 314 50744 314.5 54641 315 57457 315.5 61212 316 64090 316.5 67997 317 70131 317.5 75455 318 77674 318.5 81040 319 84165 319.5 88325 320 90751 320.5 94733 321 98186 321.5 102177 322 105321 322.5 109571 323 111977 323.5 118016 324 119032 324.5 123212 325 125788 325.5 131231 326 134738 326.5 138456 327 141768 327.5 145593 328 148634 328.5 153189 329 155833 329.5 160680 330 163387 330.5 168822 331 171175 331.5 176722 332 179630 332.5 182396 333 186145 333.5 190161 334 192823 334.5 195587 335 198721 335.5 203456 336 205051 336.5 208987 337 211072 337.5 214710 338 216726 338.5 218880 339 222081 339.5 225721 340 226914 340.5 228886 341 231350 341.5 233034 342 235798 342.5 236873 343 239537 343.5 241085 344 243189 344.5 243862 345 245335 345.5 247548 346 248921 346.5 250208 347 252162 347.5 252628 348 253884 348.5 256520 349 256209 349.5 257894 350 257871 350.5 258861 351 259502 351.5 260861 352 260311 352.5 261741 353 260990 353.5 260924 354 262289 354.5 262018 355 261037 355.5 261868 356 262119 356.5 261996 357 260807 357.5 259837 358 259908 358.5 258775 359 258397 359.5 257845 360 257404 360.5 256122 361 255261 361.5 253927 362 253013 362.5 252154 363 250195 363.5 248499 364 248505 364.5 245916 365 244155 365.5 242616 366 242706 366.5 239691 367 238970 367.5 237405 368 235412 368.5 234503 369 231420 369.5 231041 370 228944 370.5 227221 371 225671 371.5 223224 372 221417 372.5 219714 373 219273 373.5 215815 374 214516 374.5 212658 375 211358 375.5 208654 376 207140 376.5 205531 377 204858 377.5 202255 378 199905 378.5 197366 379 196149 379.5 193610 380 190610 380.5 186649 381 185334 381.5 182264 382 181406 382.5 176248 383 175121 383.5 171710 384 168685 384.5 166880 385 164760 385.5 161211 386 159570 386.5 156142 387 153966 387.5 151149 388 149600 388.5 146840 389 145219 389.5 142960 390 140896 390.5 138920 391 136926 391.5 134294 392 132837 392.5 130199 393 128851 393.5 126336 394 124243 394.5 123009 395 121788 395.5 119779 396 117699 396.5 116728 397 114612 397.5 111899 398 110989 398.5 109012 399 107550 399.5 105210 400 104144 400.5 102838 401 100580 401.5 99092 402 98062 402.5 96647 403 94821 403.5 91867 404 91074 404.5 88917 405 88376 405.5 85760 406 85394 406.5 83195 407 81957 407.5 79923 408 78956 408.5 76839 409 76075 409.5 74033 410 73214 410.5 71765 411 70141 411.5 68899 412 68468 412.5 66480 413 65471 413.5 64060 414 63114 414.5 62293 415 61090 415.5 59989 416 59240 416.5 58572 417 57442 417.5 55783 418 55004 418.5 53870 419 53177 419.5 51953 420 51417 420.5 50097 421 49208 421.5 48283 422 47749 422.5 46646 423 46498 423.5 45420 424 44609 424.5 43598 425 43060 425.5 41494 426 41150 426.5 40306 427 39696 427.5 38760 428 37724 428.5 37002 429 36245 429.5 35417 430 35507 430.5 34035 431 33713 431.5 32578 432 32134 432.5 31528 433 31151 433.5 30154 434 29452 434.5 29130 435 28559 435.5 27702 436 27260 436.5 26560 437 26477 437.5 25606 438 24827 438.5 24876 439 24198 439.5 23456 440 23339 440.5 23194 441 22480 441.5 22077 442 21685 442.5 21045 443 20668 443.5 20185 444 20018 444.5 19528 445 19362 445.5 18711 446 18328 446.5 18009 447 17764 447.5 17386 448 17349 448.5 16630 449 16511 449.5 16099 450 15797 450.5 15466 451 14906 451.5 14657 452 14567 452.5 14192 453 13799 453.5 13643 454 13335 454.5 13132 455 12795 455.5 12282 456 12308 456.5 11933 457 11846 457.5 11352 458 11090 458.5 11035 459 10793 459.5 10339 460 10329 460.5 10255 461 9999 461.5 9507 462 9497 462.5 9388 463 9258 463.5 8936 464 8766 464.5 8491 465 8482 465.5 8297 466 8168 466.5 8006 467 8137 467.5 7647 468 7454 468.5 7284 469 7174 469.5 7203 470 7002 470.5 6964 471 6840 471.5 6562 472 6430 472.5 6454 473 6128 473.5 6057 474 6020 474.5 5919 475 5678 475.5 5683 476 5578 476.5 5387 477 5154 477.5 5167 478 5024 478.5 4950 479 4813 479.5 4655 480 4745 480.5 4463 481 4431 481.5 4270 482 4187 482.5 4163 483 4137 483.5 3880 484 3936 484.5 3923 485 3791 485.5 3658 486 3651 486.5 3615 487 3469 487.5 3454 488 3435 488.5 3227 489 3245 489.5 3162 490 3113 490.5 3194 491 3064 491.5 3039 492 2987 492.5 2932 493 2858 493.5 2667 494 2690 494.5 2689 495 2696 495.5 2573 496 2563 496.5 2433 497 2357 497.5 2396 498 2411 498.5 2402 499 2333 499.5 2288 500 2092