# Optical absorption spectrum of Pyrene in cyclohexane # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by R.-C. A. Fuh in the summer of 1995 using a Cary 3. # The absorption values were collected using a spectral bandwidth of 1.0 nm, a signal averaging time of 0.133 sec, a data interval of 0.25 nm, and a scan rate of 112.5 nm/min. # # These measurements were scaled to make the molar extinction coefficient match # the value of 54000 cm-1/M at 335.2 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Berlman, I. B. (1971) “Handbook of Fluorescence Spectra of Aromatic Molecules,” Academic Press, N.Y. # ##Wavelength (nm) Molar Extinction (cm-1/M) 219 11471 220 12561 221 13947 222 15424 223 16711 224 17835 225 18988 226 20438 227 23013 228 26903 229 30867 230 35844 231 42207 232 45403 233 43246 234 40277 235 39210 236 40640 237 46893 238 55138 239 60545 240 70257 241 83200 242 77416 243 53869 244 33388 245 21181 246 14722 247 11488 248 10196 249 10053 250 10620 251 11586 252 12349 253 12428 254 11845 255 11224 256 11245 257 12110 258 13972 259 16872 260 20458 261 24060 262 26670 263 26380 264 22532 265 18355 266 15781 267 15155 268 17191 269 20933 270 24675 271 29965 272 41883 273 52884 274 45431 275 27902 276 15557 277 9189 278 6063 279 4482 280 3659 281 3259 282 3057 283 2952 284 2912 285 2890 286 2916 287 3016 288 3158 289 3294 290 3540 291 3922 292 4312 293 4625 294 4830 295 4871 296 4834 297 4789 298 4807 299 4986 300 5429 301 6183 302 7189 303 8565 304 10360 305 11832 306 12382 307 12164 308 11471 309 10502 310 9562 311 9006 312 9176 313 10285 314 12119 315 14208 316 16833 317 21290 318 26935 319 30861 320 31318 321 28413 322 23885 323 19353 324 15291 325 12352 326 10823 327 10389 328 11489 329 15280 330 20667 331 23833 332 25113 333 30464 334 43226 335 55008 336 50973 337 35220 338 20847 339 12183 340 7580 341 4894 342 3266 343 2297 344 1768 345 1407 346 1095 347 914 348 823 349 780 350 792 351 825 352 776 353 676 354 600 355 543 356 568 357 617 358 569 359 475 360 426 361 494 362 552 363 531 364 484 365 473 366 449 367 417 368 376 369 352 370 319 371 315 372 324 373 313 374 291 375 271 376 263 377 256 378 233 379 246 380 246 381 236 382 244 383 224 384 232 385 247 386 252 387 244 388 263 389 266 390 283 391 300 392 297 393 301 394 288 395 304 396 299 397 311 398 304 399 285 400 281 401 292 402 305 403 310 404 316 405 332 406 366 407 389 408 429 409 469 410 526 411 601 412 674 413 750 414 797 415 826 416 784 417 749 418 684 419 584 420 509 421 452 422 379 423 344 424 309 425 276 426 269 427 248 428 238 429 242 430 215 431 211 432 214 433 209 434 221 435 209 436 215 437 217 438 211 439 221 440 212 441 208 442 214 443 212 444 210 445 210 446 213 447 196 448 211 449 218 450 213 451 216 452 210 453 230 454 231 455 220 456 226 457 215 458 216 459 222 460 223 461 216 462 210 463 208 464 215 465 223 466 214 467 215 468 220 469 225 470 239 471 237 472 216 473 227 474 225 475 218 476 216 477 222 478 226 479 224 480 240 481 234 482 223 483 234 484 222 485 215 486 207 487 204 488 210 489 212 490 213 491 218 492 233 493 215 494 218 495 216 496 229 497 240 498 229 499 223 500 227 501 244 502 246 503 229 504 221 505 213 506 220 507 252 508 236 509 228 510 232 511 228 512 247 513 244 514 240 515 221 516 234 517 247 518 239 519 233 520 235 521 242 522 239 523 254 524 260 525 236 526 236 527 250 528 251 529 240 530 224 531 218 532 229 533 235 534 240 535 237 536 229 537 237 538 253 539 225 540 230 541 225 542 240 543 245 544 223 545 222 546 221 547 232 548 218 549 237 550 237 551 244 552 228 553 240 554 243 555 237 556 219 557 238 558 237 559 252 560 238 561 232 562 231 563 251 564 248 565 243 566 236 567 237 568 237 569 227 570 227 571 218 572 213 573 209 574 218 575 209 576 209 577 204 578 208 579 199 580 216 581 212 582 207 583 195 584 210 585 216 586 200 587 208 588 207 589 207 590 219 591 223 592 220 593 216 594 223 595 221 596 223 597 220 598 229 599 231 600 241 601 245 602 253 603 266 604 301 605 327 606 340 607 339 608 318 609 303 610 284 611 274 612 256 613 233 614 244 615 236 616 229 617 225 618 220 619 224 620 232 621 234 622 224 623 220 624 225 625 221 626 222 627 221 628 226 629 226 630 226 631 224 632 223 633 222 634 221 635 221 636 222 637 219 638 218 639 226 640 232 641 234 642 230 643 218 644 209 645 230 646 240 647 228 648 232 649 221 650 199 651 231 652 232 653 208 654 213 655 206 656 181 657 153 658 181 659 212 660 222 661 224 662 227 663 223 664 217 665 216 666 213 667 218 668 223 669 212 670 222 671 220 672 215 673 214 674 219 675 222 676 217 677 214 678 213 679 218 680 225 681 215 682 220 683 214 684 210 685 214 686 215 687 216 688 215 689 215 690 215 691 218 692 214 693 212 694 216 695 224 696 220 697 213 698 210 699 213 700 217