# Emission spectrum of in N,N-dimethylformamide # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on in the summer of 1995 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 335 6895 335.5 7190 336 7359 336.5 8031 337 8510 337.5 9996 338 10666 338.5 11861 339 12687 339.5 13300 340 13496 340.5 12806 341 12335 341.5 11167 342 10608 342.5 9912 343 9359 343.5 8944 344 8598 344.5 8377 345 8249 345.5 8013 346 8037 346.5 8055 347 8298 347.5 8455 348 8503 348.5 8594 349 8740 349.5 8810 350 8879 350.5 9126 351 9203 351.5 9788 352 9763 352.5 10495 353 10878 353.5 11211 354 11704 354.5 12928 355 14254 355.5 17032 356 18612 356.5 21584 357 23724 357.5 26203 358 26623 358.5 26819 359 26337 359.5 23669 360 22994 360.5 20105 361 17895 361.5 15737 362 15041 362.5 14234 363 14231 363.5 14100 364 13834 364.5 14224 365 14075 365.5 14661 366 14603 366.5 14917 367 15150 367.5 15873 368 16008 368.5 16192 369 16688 369.5 17113 370 17258 370.5 17555 371 18130 371.5 18319 372 18391 372.5 18671 373 18978 373.5 19530 374 19510 374.5 19599 375 19708 375.5 20351 376 20701 376.5 20996 377 21149 377.5 21057 378 21733 378.5 21809 379 22073 379.5 22456 380 22803 380.5 22949 381 23516 381.5 24075 382 24571 382.5 25562 383 26284 383.5 27182 384 27138 384.5 28578 385 28931 385.5 30251 386 31261 386.5 32408 387 33871 387.5 35055 388 36243 388.5 37626 389 39108 389.5 40683 390 42216 390.5 43715 391 45590 391.5 48115 392 49679 392.5 50929 393 52731 393.5 55426 394 56962 394.5 59925 395 61758 395.5 64618 396 66570 396.5 69085 397 71336 397.5 74677 398 76759 398.5 79892 399 82279 399.5 87115 400 89407 400.5 93484 401 95920 401.5 100726 402 104253 402.5 109178 403 113168 403.5 117910 404 121432 404.5 127852 405 131814 405.5 139405 406 142392 406.5 150095 407 155893 407.5 165029 408 169496 408.5 177650 409 183215 409.5 193684 410 198469 410.5 208101 411 213802 411.5 224185 412 229376 412.5 238151 413 244078 413.5 256307 414 260805 414.5 271280 415 279127 415.5 291567 416 295199 416.5 305484 417 314153 417.5 326986 418 331887 418.5 342499 419 350554 419.5 363502 420 370985 420.5 381782 421 390255 421.5 404143 422 411470 422.5 423345 423 433245 423.5 447960 424 454622 424.5 467214 425 477841 425.5 493015 426 498970 426.5 516323 427 526060 427.5 542817 428 549673 428.5 568588 429 579450 429.5 594802 430 603878 430.5 619401 431 632896 431.5 648740 432 658337 432.5 675468 433 686947 433.5 701716 434 713913 434.5 728347 435 739845 435.5 757877 436 766206 436.5 779867 437 791958 437.5 808137 438 821048 438.5 833086 439 843090 439.5 861820 440 869297 440.5 885088 441 893991 441.5 909191 442 919846 442.5 935968 443 947041 443.5 963105 444 973893 444.5 988595 445 1000548 445.5 1014053 446 1021788 446.5 1039177 447 1049441 447.5 1065406 448 1073704 448.5 1086533 449 1097652 449.5 1115536 450 1124034 450.5 1138390 451 1147893 451.5 1166240 452 1178831 452.5 1192509 453 1198035 453.5 1215294 454 1225056 454.5 1238442 455 1249754 455.5 1263073 456 1272918 456.5 1283150 457 1296904 457.5 1303664 458 1316667 458.5 1325991 459 1333914 459.5 1346035 460 1354458 460.5 1364140 461 1373973 461.5 1383696 462 1387725 462.5 1403602 463 1408656 463.5 1415719 464 1427476 464.5 1433210 465 1443652 465.5 1449723 466 1457372 466.5 1465865 467 1471286 467.5 1478839 468 1485092 468.5 1492828 469 1494972 469.5 1506207 470 1511491 470.5 1515817 471 1523874 471.5 1533313 472 1536084 472.5 1541203 473 1548582 473.5 1554458 474 1560658 474.5 1564568 475 1565338 475.5 1573293 476 1578749 476.5 1578531 477 1583117 477.5 1583921 478 1589647 478.5 1594101 479 1589528 479.5 1592559 480 1594823 480.5 1599487 481 1601764 481.5 1601588 482 1602373 482.5 1608224 483 1604907 483.5 1602564 484 1606902 484.5 1608375 485 1604972 485.5 1603785 486 1614387 486.5 1610699 487 1608478 487.5 1606639 488 1604786 488.5 1610259 489 1605031 489.5 1603958 490 1604350 490.5 1606210 491 1604346 491.5 1603863 492 1600579 492.5 1599233 493 1598227 493.5 1589987 494 1590535 494.5 1589045 495 1587815 495.5 1586880 496 1579463 496.5 1577721 497 1577649 497.5 1571193 498 1572833 498.5 1564744 499 1564884 499.5 1556430 500 1555862 500.5 1552604 501 1549407 501.5 1540654 502 1536996 502.5 1530289 503 1526776 503.5 1520916 504 1517479 504.5 1512111 505 1507041 505.5 1500696 506 1494758 506.5 1488345 507 1484000 507.5 1473524 508 1469172 508.5 1462748 509 1457153 509.5 1451834 510 1450974 510.5 1443318 511 1436257 511.5 1433128 512 1424767 512.5 1419949 513 1414746 513.5 1406882 514 1403754 514.5 1396967 515 1393397 515.5 1381303 516 1378619 516.5 1373097 517 1367365 517.5 1358201 518 1351759 518.5 1346347 519 1339544 519.5 1333650 520 1325439 520.5 1319427 521 1311289 521.5 1306662 522 1300333 522.5 1290361 523 1284577 523.5 1279337 524 1272750 524.5 1262271 525 1257563 525.5 1247372 526 1239375 526.5 1233406 527 1226083 527.5 1217280 528 1209314 528.5 1204901 529 1196633 529.5 1180871 530 1179840 530.5 1170502 531 1161201 531.5 1150456 532 1146306 532.5 1140462 533 1132351 533.5 1120532 534 1118419 534.5 1108737 535 1096091 535.5 1092951 536 1087273 536.5 1079592 537 1072886 537.5 1067557 538 1061356 538.5 1052010 539 1044627 539.5 1035597 540 1032930 540.5 1022227 541 1014660 541.5 1006484 542 1004203 542.5 993668 543 989577 543.5 977219 544 973966 544.5 964190 545 959349 545.5 947509 546 945065 546.5 935770 547 929718 547.5 920971 548 917834 548.5 909707 549 898312 549.5 890341 550 888524 550.5 880437 551 873721 551.5 865481 552 860608 552.5 850752 553 843032 553.5 835956 554 830023 554.5 821457 555 815914 555.5 809173 556 804884 556.5 794463 557 791713 557.5 782710 558 777631 558.5 770722 559 767411 559.5 756685 560 754484 560.5 746776 561 742771 561.5 733647 562 730196 562.5 720246 563 717973 563.5 706550 564 705543 564.5 697279 565 692926 565.5 684190 566 680521 566.5 672971 567 671173 567.5 662563 568 658714 568.5 650049 569 644268 569.5 637768 570 635572 570.5 630138 571 625351 571.5 616490 572 613918 572.5 609236 573 602940 573.5 595384 574 592140 574.5 585547 575 581178 575.5 575380 576 570338 576.5 563339 577 559776 577.5 554208 578 551196 578.5 543078 579 537187 579.5 533364 580 527626 580.5 523537 581 520589 581.5 512685 582 509390 582.5 505739 583 500275 583.5 496976 584 492459 584.5 486558 585 482367 585.5 478237 586 472936 586.5 467422 587 464736 587.5 462178 588 455794 588.5 452346 589 447757 589.5 442765 590 440106 590.5 435391 591 431243 591.5 427227 592 425512 592.5 420023 593 415918 593.5 409673 594 406806 594.5 402876 595 401318 595.5 395134 596 394427 596.5 388836 597 385906 597.5 380360 598 377219 598.5 375304 599 368400 599.5 364976 600 363414 600.5 357923 601 354491 601.5 349583 602 348274 602.5 342787 603 339615 603.5 336852 604 335657 604.5 330338 605 326074 605.5 322138 606 320797 606.5 317455 607 315592 607.5 310613 608 309503 608.5 308077 609 302656 609.5 299472 610 297873 610.5 293672 611 293221 611.5 287213 612 285854 612.5 283210 613 280680 613.5 276632 614 273285 614.5 271379 615 268409 615.5 263805 616 264492 616.5 262079 617 259770 617.5 254642 618 254000 618.5 251325 619 249661 619.5 246312 620 244627