# Emission spectrum of in dimethylsulfoxide # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on in the summer of 1997 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 320 3699 320.5 3369 321 3364 321.5 3109 322 3179 322.5 3146 323 3112 323.5 3396 324 3267 324.5 3075 325 2907 325.5 2795 326 2573 326.5 2368 327 2144 327.5 2159 328 2104 328.5 2099 329 2157 329.5 2038 330 2164 330.5 2150 331 2127 331.5 2116 332 2053 332.5 2171 333 2253 333.5 2198 334 2281 334.5 2201 335 2281 335.5 2350 336 2517 336.5 2655 337 3143 337.5 4324 338 5464 338.5 7619 339 9809 339.5 12312 340 13297 340.5 14025 341 13835 341.5 12307 342 11355 342.5 9142 343 7395 343.5 5418 344 4354 344.5 3497 345 3202 345.5 2847 346 2736 346.5 2569 347 2594 347.5 2518 348 2480 348.5 2563 349 2522 349.5 2333 350 2496 350.5 2469 351 2371 351.5 2469 352 2414 352.5 2334 353 2490 353.5 2464 354 2502 354.5 2598 355 2477 355.5 2446 356 2460 356.5 2400 357 2385 357.5 2455 358 2334 358.5 2352 359 2451 359.5 2398 360 2418 360.5 2375 361 2249 361.5 2285 362 2334 362.5 2309 363 2361 363.5 2291 364 2280 364.5 2272 365 2239 365.5 2222 366 2209 366.5 2279 367 2199 367.5 2287 368 2357 368.5 2445 369 2371 369.5 2528 370 2617 370.5 2712 371 2768 371.5 2677 372 2774 372.5 2694 373 2763 373.5 2761 374 2671 374.5 2812 375 2800 375.5 2925 376 2911 376.5 3056 377 3183 377.5 3260 378 3363 378.5 3459 379 3644 379.5 3801 380 4112 380.5 4355 381 4524 381.5 4933 382 5172 382.5 5505 383 5759 383.5 6548 384 6642 384.5 7319 385 7907 385.5 8582 386 9122 386.5 10237 387 11270 387.5 12291 388 13187 388.5 14386 389 15688 389.5 17200 390 18160 390.5 20030 391 21762 391.5 23588 392 25074 392.5 27225 393 28839 393.5 31841 394 34082 394.5 36893 395 39014 395.5 42132 396 45083 396.5 48383 397 51528 397.5 55655 398 58552 398.5 63181 399 66318 399.5 72366 400 75578 400.5 80741 401 85275 401.5 91817 402 95701 402.5 102969 403 106312 403.5 115617 404 119690 404.5 127625 405 133061 405.5 143585 406 147960 406.5 159034 407 165834 407.5 177682 408 181834 408.5 193195 409 201791 409.5 213691 410 220222 410.5 231879 411 239045 411.5 252207 412 257842 412.5 269892 413 278683 413.5 290586 414 297708 414.5 306837 415 316224 415.5 328655 416 336247 416.5 348965 417 356155 417.5 369944 418 376041 418.5 389350 419 397864 419.5 410714 420 417196 420.5 429888 421 438927 421.5 453792 422 459769 422.5 472711 423 481125 423.5 496521 424 504248 424.5 518324 425 526044 425.5 541935 426 547557 426.5 560628 427 573098 427.5 588402 428 594865 428.5 609920 429 621429 429.5 635557 430 640844 430.5 655947 431 666982 431.5 679277 432 687810 432.5 700713 433 711034 433.5 726526 434 730810 434.5 743760 435 752982 435.5 763924 436 772333 436.5 781502 437 790760 437.5 801072 438 810504 438.5 816720 439 826807 439.5 837623 440 843908 440.5 852228 441 859071 441.5 868893 442 877512 442.5 886545 443 894667 443.5 904241 444 908239 444.5 918124 445 922493 445.5 931659 446 938868 446.5 945602 447 954037 447.5 960569 448 963099 448.5 973512 449 979966 449.5 983119 450 988538 450.5 996616 451 999131 451.5 1007121 452 1010509 452.5 1014813 453 1019271 453.5 1028905 454 1030742 454.5 1035210 455 1039029 455.5 1041657 456 1044757 456.5 1047779 457 1052013 457.5 1056219 458 1056166 458.5 1058407 459 1061487 459.5 1063569 460 1063880 460.5 1067097 461 1070231 461.5 1071297 462 1071246 462.5 1071852 463 1073791 463.5 1073335 464 1075470 464.5 1075452 465 1078704 465.5 1077201 466 1077415 466.5 1076834 467 1078104 467.5 1075944 468 1076260 468.5 1077398 469 1076176 469.5 1076726 470 1074691 470.5 1075461 471 1073842 471.5 1072729 472 1072820 472.5 1071263 473 1071179 473.5 1068717 474 1066578 474.5 1067001 475 1062468 475.5 1060679 476 1058134 476.5 1054506 477 1053572 477.5 1047538 478 1046547 478.5 1039323 479 1034314 479.5 1031704 480 1029801 480.5 1023694 481 1023167 481.5 1015910 482 1014585 482.5 1009151 483 1002659 483.5 998229 484 997512 484.5 993500 485 991360 485.5 984213 486 980985 486.5 976119 487 973185 487.5 966281 488 961424 488.5 958298 489 957436 489.5 947060 490 946808 490.5 938410 491 938412 491.5 928953 492 929265 492.5 919888 493 919736 493.5 909973 494 908834 494.5 902060 495 899057 495.5 892289 496 888701 496.5 884315 497 877627 497.5 871771 498 865269 498.5 856780 499 855680 499.5 847554 500 844816 500.5 837733 501 832086 501.5 826051 502 820447 502.5 813172 503 807377 503.5 797750 504 798374 504.5 787583 505 784432 505.5 774582 506 769878 506.5 765814 507 760911 507.5 752940 508 746303 508.5 740941 509 735976 509.5 729193 510 721469 510.5 718808 511 716908 511.5 706846 512 703143 512.5 697610 513 691903 513.5 684783 514 679951 514.5 673268 515 670954 515.5 663140 516 659793 516.5 653394 517 649760 517.5 641935 518 638880 518.5 631344 519 625604 519.5 621947 520 618559 520.5 610179 521 608383 521.5 599271 522 595275 522.5 589353 523 586191 523.5 578261 524 573456 524.5 567943 525 563816 525.5 556454 526 551309 526.5 545412 527 542894 527.5 534668 528 531955 528.5 525744 529 521455 529.5 514188 530 511413 530.5 503901 531 498285 531.5 491517 532 489598 532.5 484923 533 478771 533.5 471412 534 469418 534.5 463697 535 461968 535.5 452853 536 451838 536.5 448966 537 444751 537.5 438007 538 435982 538.5 430502 539 426806 539.5 421008 540 419718 540.5 412417 541 409671 541.5 404177 542 402298 542.5 396680 543 393499 543.5 386907 544 386189 544.5 381149 545 379610 545.5 369801 546 370285 546.5 364125 547 361308 547.5 355369 548 352281 548.5 348969 549 345996 549.5 341861 550 338876 550.5 333963 551 330710 551.5 326092 552 323820 552.5 318580 553 316841 553.5 311142 554 308515 554.5 305667 555 301071 555.5 296689 556 294553 556.5 290804 557 289305 557.5 284556 558 283261 558.5 280404 559 275433 559.5 271525 560 272005 560.5 266271 561 264733 561.5 260414 562 258020 562.5 256402 563 253456 563.5 249789 564 245657 564.5 243015 565 241131 565.5 237688 566 235785 566.5 234111 567 231462 567.5 228233 568 225502 568.5 223185 569 219754 569.5 217379 570 217406 570.5 212493 571 211304 571.5 208103 572 206731 572.5 203881 573 201659 573.5 200475 574 197032 574.5 194855 575 192697 575.5 189656 576 187467 576.5 185270 577 182641 577.5 180788 578 178721 578.5 176510 579 173372 579.5 171530 580 170887 580.5 168160 581 166807 581.5 164643 582 163287 582.5 161765 583 158711 583.5 157554 584 155812 584.5 153354 585 152563 585.5 150021 586 148570 586.5 146882 587 146121 587.5 142402 588 141985 588.5 139690 589 138481 589.5 135878 590 135241 590.5 133541 591 132134 591.5 129308 592 129677 592.5 127663 593 126426 593.5 124864 594 122245 594.5 121146 595 120770 595.5 119308 596 117076 596.5 116625 597 113830 597.5 112657 598 111823 598.5 110814 599 108602 599.5 107400 600 106338