TCPH-meso-tetra(4-COOMe-phenyl)-Pd This page summarizes the optical absorption and emission data of TCPH-meso-tetra(4-COOMe-phenyl)-Pd that is available in the PhotochemCAD package, version 2.1a (Du 1998, Dixon 2005). I reworked their data to produce these interactive graphs and to provide direct links to text files containing the raw and manipulated data. Although I have tried to be careful, I may have introduced some errors; the cautious user is advised to compare these results with the original sources.

You can resize any of the graphs by clicking and dragging a rectangle. If you hover the mouse over the graph, you will see a pop-up showing the coordinates. One of the icons in the upper right corner will let you export the graph in other formats.

Absorption

This optical absorption measurement of TCPH-meso-tetra(4-COOMe-phenyl)-Pd were made by O. Finikova on 10-24-2004 using a PerkinElmer Lambda 35.

These measurements were scaled to make the molar extinction coefficient match the value of 200,000cm-1/M at 428.0nm (Finikova, 2004).

Original Data | Extinction Data

Notes

No emission spectrum was provided owing to the low quantum yield. See (Finikova, 2004) for photophysical properties of tetrabenzoporphyrins.

References

Dixon, J. M., M. Taniguchi and J. S. Lindsey (2005), "PhotochemCAD 2. A Refined Program with Accompanying Spectral Databases for Photochemical Calculations, Photochem. Photobiol., 81, 212-213.

Du, H., R.-C. A. Fuh, J. Li, L. A. Corkan and J. S. Lindsey (1998) PhotochemCAD: A computer-aided design and research tool in photochemistry. Photochem. Photobiol. 68, 141-142.

Finikova, O. S., A. V. Cheprakov, I. P. Beletskaya, P. J. Carroll and S. A. Vinogradov (2004) Novel versatile synthesis of substituted tetrabenzoporphyrins. J. Org. Chem. 69, 522-535.