TBP-meso-tetraphenyl-beta-octa(COOMe)-Pd This page summarizes the optical absorption and emission data of TBP-meso-tetraphenyl-beta-octa(COOMe)-Pd that is available in the PhotochemCAD package, version 2.1a (Du 1998, Dixon 2005). I reworked their data to produce these interactive graphs and to provide direct links to text files containing the raw and manipulated data. Although I have tried to be careful, I may have introduced some errors; the cautious user is advised to compare these results with the original sources.

You can resize any of the graphs by clicking and dragging a rectangle. If you hover the mouse over the graph, you will see a pop-up showing the coordinates. One of the icons in the upper right corner will let you export the graph in other formats.

Absorption

This optical absorption measurement of TBP-meso-tetraphenyl-beta-octa(COOMe)-Pd were made by O. Finikova on 10-16-2004 using a PerkinElmer Lambda 35.

These measurements were scaled to make the molar extinction coefficient match the value of 250,000cm-1/M at 460.0nm (Finikova, 2004).

Original Data | Extinction Data

Notes

See (Finikova, 2004) for photophysical properties of tetrabenzoporphyrins.

References

Dixon, J. M., M. Taniguchi and J. S. Lindsey (2005), "PhotochemCAD 2. A Refined Program with Accompanying Spectral Databases for Photochemical Calculations, Photochem. Photobiol., 81, 212-213.

Du, H., R.-C. A. Fuh, J. Li, L. A. Corkan and J. S. Lindsey (1998) PhotochemCAD: A computer-aided design and research tool in photochemistry. Photochem. Photobiol. 68, 141-142.

Finikova, O. S., A. V. Cheprakov, I. P. Beletskaya, P. J. Carroll and S. A. Vinogradov (2004) Novel versatile synthesis of substituted tetrabenzoporphyrins. J. Org. Chem. 69, 522-535.