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Pyrrole

Scott Prahl

Pyrrole This page summarizes the optical absorption and emission data of Pyrrole that is available in the PhotochemCAD package, version 2.1a (Du 1998, Dixon 2005). I reworked their data to produce these interactive graphs and to provide direct links to text files containing the raw and manipulated data. Although I have tried to be careful, I may have introduced some errors; the cautious user is advised to compare these results with the original sources.

The JavaScript libraries that I used to graph the data do not work with IE7 and earlier — you will not see the cool interactive graphs. Chrome seems to work best. You can resize any of the graphs by clicking and dragging a rectangle. If you hover the mouse over the graph, you will see a pop-up showing the coordinates. One of the icons in the upper right corner will let you export the graph in other formats.

Absorption

This optical absorption measurement of Pyrrole were made by J. Li on 12-11-1997 using a Cary 3. The absorption values were collected using a spectral bandwidth of 1.0 nm, a signal averaging time of 0.133 sec, a data interval of 0.25 nm, and a scan rate of 112.5 nm/min.

These measurements were scaled to make the molar extinction coefficient match the value of 15,000cm-1/M at 210.5nm (Bowden, 1946).

Original Data | Extinction Data

Notes

No fluorescence was observed, thus no file is included.

References

Bowden, K., E. A. Braude and E. R. H. Jones (1946) Studies in light absorption. Part III. Auxochromic properties and the periodic system. J. Chem. Soc. 948-952.

Dixon, J. M., M. Taniguchi and J. S. Lindsey (2005), "PhotochemCAD 2. A Refined Program with Accompanying Spectral Databases for Photochemical Calculations, Photochem. Photobiol., 81, 212-213.

Du, H., R.-C. A. Fuh, J. Li, L. A. Corkan and J. S. Lindsey (1998) PhotochemCAD: A computer-aided design and research tool in photochemistry. Photochem. Photobiol. 68, 141-142.


© 5 March 2012 Scott Prahl