# Optical absorption spectrum of TBP-beta-octa(COOBu)-Fb in DMF # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by O. Finikova on 10-23-2004 using a PerkinElmer Lambda 35. # # # These measurements were scaled to make the molar extinction coefficient match # the value of 325000 cm-1/M at 447.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Finikova, O. S., A. V. Cheprakov, I. P. Beletskaya, P. J. Carroll and S. A. Vinogradov (2004) Novel versatile synthesis of substituted tetrabenzoporphyrins. J. Org. Chem. 69, 522-535. # ##Wavelength (nm) Molar Extinction (cm-1/M) 350 14257 351 14209 352 14071 353 14044 354 13902 355 13839 356 13790 357 13674 358 13645 359 13618 360 13458 361 13454 362 13312 363 13252 364 13136 365 13136 366 13054 367 12938 368 12987 369 12923 370 13043 371 13155 372 13308 373 13562 374 13742 375 13981 376 14186 377 14478 378 14463 379 14564 380 14553 381 14553 382 14474 383 14519 384 14500 385 14870 386 15173 387 15730 388 16463 389 17221 390 18357 391 19512 392 21059 393 22895 394 24980 395 27391 396 30108 397 33146 398 36106 399 38872 400 41155 401 42949 402 44179 403 44893 404 45173 405 45177 406 45064 407 44680 408 44231 409 43670 410 43431 411 43592 412 44403 413 46047 414 48693 415 52259 416 56931 417 62649 418 69458 419 77038 420 84983 421 92970 422 100755 423 108839 424 117696 425 128676 426 142501 427 159771 428 179531 429 200265 430 219475 431 233715 432 241021 433 239085 434 228860 435 211803 436 191714 437 171776 438 155047 439 144381 440 141918 441 150293 442 169574 443 199970 444 237673 445 276556 446 308578 447 324999 448 322495 449 300180 450 264077 451 220862 452 177075 453 137299 454 103049 455 76096 456 55208 457 40180 458 29237 459 21762 460 16418 461 12875 462 10229 463 8465 464 7160 465 6192 466 5445 467 4955 468 4428 469 4092 470 3756 471 3554 472 3344 473 3191 474 3008 475 2903 476 2773 477 2675 478 2608 479 2586 480 2414 481 2444 482 2406 483 2373 484 2332 485 2324 486 2272 487 2272 488 2257 489 2223 490 2276 491 2272 492 2238 493 2249 494 2283 495 2365 496 2362 497 2399 498 2421 499 2436 500 2470 501 2504 502 2496 503 2563 504 2533 505 2526 506 2623 507 2608 508 2646 509 2724 510 2795 511 2885 512 2974 513 3023 514 3135 515 3273 516 3367 517 3445 518 3550 519 3599 520 3733 521 3853 522 4013 523 4114 524 4256 525 4357 526 4484 527 4581 528 4776 529 4929 530 5090 531 5224 532 5355 533 5400 534 5482 535 5508 536 5493 537 5497 538 5475 539 5449 540 5407 541 5392 542 5392 543 5385 544 5374 545 5407 546 5441 547 5572 548 5583 549 5714 550 5830 551 6065 552 6308 553 6637 554 7000 555 7325 556 7642 557 7964 558 8311 559 8872 560 9410 561 10221 562 10916 563 11537 564 12041 565 12523 566 13091 567 13745 568 14530 569 15386 570 16033 571 16586 572 16829 573 17098 574 17348 575 17752 576 18193 577 18739 578 19138 579 19344 580 19415 581 19206 582 18888 583 18537 584 18077 585 17647 586 17184 587 16672 588 16078 589 15491 590 14941 591 14437 592 14011 593 13917 594 14145 595 14799 596 15820 597 17053 598 18410 599 19961 600 21504 601 23302 602 25582 603 28616 604 32589 605 37358 606 42157 607 46044 608 48361 609 49127 610 49183 611 49441 612 50652 613 53481 614 57644 615 62208 616 65702 617 66289 618 64514 619 61333 620 58508 621 57390 622 58343 623 61438 624 65403 625 68640 626 69615 627 66823 628 60855 629 52367 630 43371 631 34783 632 27484 633 21624 634 17113 635 13749 636 11260 637 9425 638 8143 639 7149 640 6502 641 5957 642 5579 643 5273 644 5052 645 4873 646 4776 647 4667 648 4585 649 4593 650 4694 651 4780 652 4940 653 5071 654 5299 655 5441 656 5695 657 5968 658 6372 659 6895 660 7657 661 8700 662 10195 663 12067 664 14530 665 17565 666 21224 667 25425 668 29984 669 34559 670 38801 671 42284 672 44691 673 45752 674 45285 675 43424 676 40415 677 36558 678 32238 679 27779 680 23403 681 19482 682 15906 683 12949 684 10359 685 8360 686 6693 687 5370 688 4312 689 3561 690 2967 691 2586 692 2182 693 1939 694 1719 695 1580 696 1450 697 1405 698 1281 699 1259 700 1255 701 1203 702 1124 703 1195 704 1151 705 1087 706 1057 707 1091 708 1024 709 1050 710 1016 711 971 712 900 713 930 714 837 715 893 716 814 717 833 718 818 719 796 720 736 721 698 722 732 723 710 724 702 725 665 726 639 727 586 728 631 729 571 730 583 731 534 732 504 733 519 734 549 735 519 736 489 737 538 738 512 739 437 740 433 741 407 742 429 743 411 744 403 745 373 746 369 747 351 748 388 749 328 750 336 751 332 752 328 753 265 754 347 755 272 756 313 757 246 758 284 759 269 760 328 761 280 762 261 763 280 764 280 765 235 766 250 767 209 768 194 769 250 770 209 771 213 772 198 773 224 774 168 775 224 776 160 777 164 778 220 779 160 780 123 781 164 782 175 783 164 784 168 785 119 786 130 787 119 788 130 789 145 790 89 791 100 792 67 793 108 794 97 795 85 796 89 797 78 798 48 799 100 800 22 801 82 802 82 803 71 804 14 805 33 806 37 807 52 808 29 809 59 810 52 811 59 812 44 813 56 814 44 815 56 816 52 817 56 818 26 819 18 820 37 821 37 822 37 823 0 824 0 825 29 826 7 827 26 828 26 829 0 830 14 831 0 832 -14 833 3 834 11 835 -11 836 -14 837 -7 838 3 839 3 840 11 841 0 842 -29 843 -37 844 -33 845 3 846 -33 847 0 848 -56 849 -44 850 -37