# Emission spectrum of in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on on 10-01-2004 # using a PTI QM-4/2003 SE. The excitation and emission monochromators were set at 0.25 mm, giving a spectral bandwidth of 1 nm. The data interval was 1 nm and the integration time was 1 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 500 22000 501 24300 502 28100 503 31700 504 36800 505 43300 506 51300 507 59700 508 70200 509 82400 510 97700 511 115000 512 137000 513 161000 514 194000 515 229000 516 273000 517 323000 518 387000 519 451000 520 532000 521 618000 522 726000 523 835000 524 965000 525 1090000 526 1250000 527 1400000 528 1580000 529 1770000 530 1990000 531 2200000 532 2460000 533 2710000 534 3010000 535 3310000 536 3660000 537 4040000 538 4490000 539 4930000 540 5460000 541 6010000 542 6610000 543 7190000 544 7850000 545 8500000 546 9220000 547 9900000 548 10600000 549 11300000 550 12100000 551 12700000 552 13400000 553 14100000 554 14700000 555 15200000 556 15800000 557 16200000 558 16600000 559 17000000 560 17300000 561 17600000 562 17800000 563 17900000 564 18100000 565 18100000 566 18200000 567 18200000 568 18100000 569 18100000 570 18000000 571 17800000 572 17700000 573 17500000 574 17300000 575 17100000 576 16900000 577 16700000 578 16400000 579 16200000 580 16000000 581 15900000 582 15700000 583 15600000 584 15500000 585 15400000 586 15300000 587 15300000 588 15300000 589 15300000 590 15400000 591 15500000 592 15600000 593 15700000 594 15900000 595 16100000 596 16200000 597 16400000 598 16600000 599 16800000 600 17000000 601 17200000 602 17400000 603 17500000 604 17700000 605 17800000 606 17900000 607 18000000 608 18100000 609 18100000 610 18100000 611 18100000 612 18100000 613 18000000 614 17900000 615 17800000 616 17600000 617 17500000 618 17300000 619 17100000 620 16900000 621 16700000 622 16500000 623 16300000 624 16000000 625 15700000 626 15300000 627 15000000 628 14600000 629 14300000 630 14000000 631 13700000 632 13400000 633 13200000 634 12900000 635 12600000 636 12300000 637 12100000 638 11800000 639 11600000 640 11400000 641 11200000 642 11000000 643 10900000 644 10700000 645 10600000 646 10500000 647 10400000 648 10300000 649 10200000 650 10100000 651 10000000 652 9980000 653 9930000 654 9870000 655 9850000 656 9790000 657 9750000 658 9690000 659 9670000 660 9580000 661 9540000 662 9450000 663 9410000 664 9330000 665 9270000 666 9190000 667 9140000 668 9040000 669 8970000 670 8850000 671 8780000 672 8660000 673 8550000 674 8420000 675 8290000 676 8140000 677 8010000 678 7850000 679 7700000 680 7570000 681 7420000 682 7250000 683 7120000 684 6950000 685 6790000 686 6630000 687 6480000 688 6310000 689 6190000 690 6040000 691 5900000 692 5770000 693 5640000 694 5490000 695 5370000 696 5230000 697 5100000 698 4970000 699 4830000 700 4720000 701 4620000 702 4510000 703 4420000 704 4320000 705 4230000 706 4130000 707 4040000 708 3960000 709 3880000 710 3810000 711 3730000 712 3660000 713 3620000 714 3550000 715 3500000 716 3460000 717 3390000 718 3360000 719 3300000 720 3260000 721 3220000 722 3150000 723 3130000 724 3090000 725 3040000 726 3010000 727 2970000 728 2930000 729 2910000 730 2860000 731 2820000 732 2780000 733 2760000 734 2710000 735 2670000 736 2630000 737 2600000 738 2550000 739 2520000 740 2490000 741 2450000 742 2400000 743 2370000 744 2320000 745 2280000 746 2230000 747 2210000 748 2150000 749 2100000 750 2070000 751 2020000 752 1980000 753 1940000 754 1890000 755 1850000 756 1810000 757 1760000 758 1730000 759 1680000 760 1640000 761 1600000 762 1580000 763 1540000 764 1510000 765 1460000 766 1440000 767 1420000 768 1380000 769 1340000 770 1310000 771 1290000 772 1250000 773 1220000 774 1200000 775 1160000 776 1140000 777 1120000 778 1090000 779 1070000 780 1050000 781 1030000 782 999000 783 982000 784 955000 785 937000 786 920000 787 894000 788 886000 789 865000 790 844000 791 837000 792 822000 793 795000 794 779000 795 767000 796 755000 797 744000 798 733000 799 722000 800 701000