# Optical absorption spectrum of Perylene-monoimide(OR), [PMI(OR)] in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by M. Taniguchi on 10-01-2004 using a HP 8453. #The absorption values were collected using a spectral bandwidth of 1.0 nm. # # These measurements were scaled to make the molar extinction coefficient match # the value of 40000 cm-1/M at 507.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Tomizaki, K., R. S. Loewe, C. Kirmaier, J. K. Schwartz, J. L. Retsek, D. F. Bocian, D. Holten and J. S. Lindsey (2002) Synthesis and photophysical properties of light-harvesting arrays comprised of a porphyrin bearing multiple perylene-monoimide accessory pigments. J. Org. Chem. 67, 6519-6534. # ##Wavelength (nm) Molar Extinction (cm-1/M) 300 4873 301 4767 302 4659 303 4552 304 4446 305 4337 306 4225 307 4127 308 4032 309 3934 310 3859 311 3790 312 3722 313 3662 314 3604 315 3547 316 3512 317 3460 318 3418 319 3369 320 3329 321 3293 322 3259 323 3225 324 3189 325 3150 326 3110 327 3069 328 3036 329 3006 330 2991 331 2996 332 3021 333 3058 334 3104 335 3148 336 3201 337 3264 338 3325 339 3391 340 3433 341 3465 342 3456 343 3414 344 3342 345 3275 346 3225 347 3190 348 3184 349 3186 350 3200 351 3233 352 3269 353 3300 354 3330 355 3358 356 3372 357 3363 358 3341 359 3275 360 3160 361 2992 362 2775 363 2550 364 2348 365 2194 366 2065 367 1998 368 1967 369 1941 370 1883 371 1804 372 1727 373 1675 374 1647 375 1596 376 1547 377 1476 378 1389 379 1298 380 1250 381 1219 382 1223 383 1253 384 1314 385 1369 386 1401 387 1405 388 1390 389 1373 390 1360 391 1349 392 1326 393 1309 394 1292 395 1266 396 1223 397 1181 398 1152 399 1138 400 1155 401 1194 402 1238 403 1284 404 1335 405 1400 406 1486 407 1579 408 1688 409 1808 410 1940 411 2074 412 2192 413 2301 414 2394 415 2477 416 2549 417 2620 418 2700 419 2799 420 2912 421 3041 422 3166 423 3311 424 3464 425 3645 426 3823 427 4014 428 4211 429 4420 430 4646 431 4870 432 5095 433 5350 434 5616 435 5898 436 6188 437 6483 438 6803 439 7134 440 7474 441 7844 442 8193 443 8560 444 8934 445 9329 446 9731 447 10121 448 10513 449 10928 450 11357 451 11770 452 12187 453 12609 454 13050 455 13488 456 13937 457 14427 458 14906 459 15396 460 15905 461 16444 462 16994 463 17574 464 18198 465 18800 466 19388 467 20004 468 20662 469 21282 470 21936 471 22603 472 23230 473 23866 474 24446 475 25057 476 25632 477 26149 478 26660 479 27149 480 27639 481 28097 482 28546 483 28939 484 29325 485 29812 486 30267 487 30573 488 31060 489 31532 490 32009 491 32580 492 33114 493 33650 494 34240 495 34759 496 35419 497 35988 498 36559 499 37116 500 37707 501 38248 502 38665 503 38998 504 39355 505 39625 506 39879 507 40000 508 39981 509 39986 510 39817 511 39603 512 39338 513 39025 514 38648 515 38218 516 37717 517 37301 518 36895 519 36366 520 35951 521 35561 522 35175 523 34827 524 34517 525 34236 526 34013 527 33840 528 33640 529 33451 530 33327 531 33178 532 33083 533 32882 534 32705 535 32416 536 32161 537 31779 538 31354 539 30813 540 30201 541 29518 542 28719 543 27836 544 26827 545 25761 546 24613 547 23404 548 22167 549 20886 550 19566 551 18232 552 16890 553 15573 554 14300 555 13045 556 11832 557 10704 558 9644 559 8613 560 7652 561 6797 562 6011 563 5281 564 4613 565 4029 566 3506 567 3033 568 2612 569 2234 570 1925 571 1650 572 1409 573 1213 574 1012 575 874 576 749 577 625 578 524 579 460 580 379 581 315 582 268 583 247 584 203 585 156 586 145 587 124 588 100 589 89 590 72 591 59 592 47 593 36 594 34 595 31 596 26 597 18 598 13 599 6 600 1 601 3 602 5 603 2 604 -4 605 -5 606 -4 607 -7 608 -16 609 -6 610 -16 611 -11 612 -16 613 -11 614 -20 615 -10 616 -13 617 -13 618 -20 619 -19 620 -21 621 -15 622 -19 623 -18 624 -18 625 -11 626 -11 627 -17 628 -24 629 -18 630 -12 631 -11 632 -9 633 -11 634 -10 635 -7 636 -10 637 -21 638 -25 639 -25 640 -23 641 -16 642 -29 643 -20 644 -17 645 -10 646 -16 647 -21 648 -19 649 -15 650 -14 651 -12 652 -22 653 -19 654 -16 655 -4 656 -18 657 15 658 15 659 -7 660 0 661 -15 662 -14 663 -10 664 -5 665 -10 666 -7 667 -13 668 -16 669 -8 670 -12 671 -15 672 -13 673 -16 674 -11 675 -9 676 -12 677 -10 678 -6 679 -14 680 -9 681 -13 682 -11 683 -10 684 -11 685 -10 686 -6 687 -11 688 -8 689 -9 690 -8 691 -6 692 -6 693 -6 694 -10 695 -6 696 -6 697 -4 698 -5 699 -3 700 -6 701 -5 702 -2 703 -4 704 -5 705 -7 706 -5 707 -1 708 -6 709 -2 710 -9 711 -3 712 -4 713 -1 714 -5 715 -8 716 -8 717 -6 718 -1 719 -6 720 -4 721 -1 722 -4 723 -5 724 -4 725 -6 726 -5 727 -4 728 0 729 -6 730 -3 731 0 732 -3 733 -1 734 0 735 0 736 -2 737 0 738 -1 739 -1 740 -1 741 -1 742 0 743 -3 744 0 745 2 746 1 747 5 748 2 749 0 750 -2 751 -1 752 0 753 -3 754 0 755 1 756 0 757 3 758 0 759 0 760 4 761 0 762 -5 763 0 764 2 765 2 766 -2 767 -1 768 1 769 4 770 4 771 3 772 0 773 1 774 1 775 2 776 1 777 1 778 7 779 6 780 3 781 4 782 2 783 2 784 5 785 7 786 3 787 6 788 5 789 3 790 0 791 1 792 0 793 2 794 2 795 2 796 -1 797 2 798 5 799 4 800 3