# Optical absorption spectrum of Bis(5-mesityldipyrrinato)zinc in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by D. Holten on 09-15-2004 using a . # # # These measurements were scaled to make the molar extinction coefficient match # the value of 115000 cm-1/M at 487.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Sazanovich, I. V., C. Kirmaier, E. Hindin, L. Yu, D. Bocian, J. S. Lindsey and D. Holten (2004) Structural control of the excited-state dynamics of bis(dipyrrinato)zinc complexes: self-assembling chromophores for light-harvesting architecture. J. Am. Chem. Soc. 126, 2664-2665. # ##Wavelength (nm) Molar Extinction (cm-1/M) 300 6763 300.5 6513 301 6288 301.5 6031 302 5839 302.5 5677 303 5513 303.5 5387 304 5261 304.5 5131 305 5057 305.5 5011 306 4941 306.5 4904 307 4873 307.5 4831 308 4812 308.5 4827 309 4842 309.5 4791 310 4776 310.5 4783 311 4806 311.5 4813 312 4820 312.5 4859 313 4855 313.5 4914 314 4922 314.5 4954 315 4977 315.5 5040 316 5056 316.5 5146 317 5154 317.5 5206 318 5284 318.5 5337 319 5364 319.5 5407 320 5467 320.5 5527 321 5604 321.5 5659 322 5695 322.5 5743 323 5819 323.5 5886 324 5976 324.5 6023 325 6049 325.5 6159 326 6204 326.5 6294 327 6337 327.5 6416 328 6481 328.5 6550 329 6658 329.5 6717 330 6765 330.5 6846 331 6897 331.5 6965 332 7050 332.5 7109 333 7170 333.5 7244 334 7304 334.5 7382 335 7418 335.5 7465 336 7534 336.5 7556 337 7645 337.5 7682 338 7731 338.5 7773 339 7810 339.5 7825 340 7864 340.5 7923 341 7896 341.5 7950 342 7943 342.5 7946 343 7977 343.5 8004 344 8022 344.5 8033 345 7978 345.5 8055 346 8056 346.5 8065 347 8030 347.5 8056 348 8063 348.5 8039 349 8061 349.5 8088 350 8068 350.5 8062 351 8090 351.5 8025 352 8050 352.5 7969 353 7939 353.5 7886 354 7852 354.5 7865 355 7819 355.5 7735 356 7698 356.5 7629 357 7580 357.5 7498 358 7389 358.5 7322 359 7265 359.5 7147 360 7073 360.5 7000 361 6973 361.5 6836 362 6754 362.5 6673 363 6582 363.5 6486 364 6378 364.5 6305 365 6201 365.5 6088 366 5991 366.5 5914 367 5827 367.5 5723 368 5644 368.5 5573 369 5528 369.5 5416 370 5348 370.5 5258 371 5209 371.5 5157 372 5101 372.5 5047 373 4975 373.5 4921 374 4845 374.5 4814 375 4752 375.5 4690 376 4617 376.5 4566 377 4514 377.5 4450 378 4372 378.5 4327 379 4260 379.5 4186 380 4132 380.5 4043 381 3975 381.5 3907 382 3835 382.5 3727 383 3658 383.5 3569 384 3500 384.5 3410 385 3328 385.5 3254 386 3168 386.5 3076 387 2998 387.5 2911 388 2821 388.5 2746 389 2665 389.5 2571 390 2497 390.5 2422 391 2353 391.5 2277 392 2206 392.5 2143 393 2075 393.5 2023 394 1970 394.5 1909 395 1861 395.5 1807 396 1776 396.5 1726 397 1690 397.5 1660 398 1635 398.5 1602 399 1589 399.5 1557 400 1554 400.5 1537 401 1531 401.5 1535 402 1518 402.5 1527 403 1526 403.5 1542 404 1546 404.5 1565 405 1580 405.5 1605 406 1617 406.5 1645 407 1678 407.5 1700 408 1735 408.5 1778 409 1802 409.5 1843 410 1887 410.5 1926 411 1971 411.5 2022 412 2066 412.5 2115 413 2167 413.5 2201 414 2265 414.5 2312 415 2371 415.5 2439 416 2512 416.5 2573 417 2652 417.5 2728 418 2801 418.5 2882 419 2969 419.5 3057 420 3150 420.5 3233 421 3337 421.5 3440 422 3555 422.5 3655 423 3775 423.5 3902 424 4028 424.5 4169 425 4314 425.5 4459 426 4620 426.5 4775 427 4945 427.5 5118 428 5300 428.5 5497 429 5701 429.5 5912 430 6125 430.5 6353 431 6586 431.5 6826 432 7079 432.5 7328 433 7600 433.5 7881 434 8162 434.5 8440 435 8733 435.5 9025 436 9330 436.5 9624 437 9936 437.5 10245 438 10561 438.5 10869 439 11182 439.5 11515 440 11825 440.5 12156 441 12479 441.5 12814 442 13146 442.5 13479 443 13828 443.5 14196 444 14576 444.5 14966 445 15372 445.5 15812 446 16272 446.5 16756 447 17280 447.5 17822 448 18411 448.5 19041 449 19711 449.5 20433 450 21198 450.5 21996 451 22877 451.5 23808 452 24755 452.5 25855 453 26965 453.5 28162 454 29410 454.5 30718 455 32107 455.5 33568 456 35071 456.5 36624 457 38241 457.5 39890 458 41565 458.5 43226 459 44919 459.5 46577 460 48186 460.5 49753 461 51237 461.5 52657 462 53952 462.5 55134 463 56189 463.5 57111 464 57901 464.5 58567 465 59121 465.5 59575 466 59925 466.5 60227 467 60450 467.5 60619 468 60771 468.5 60882 469 60997 469.5 61138 470 61269 470.5 61443 471 61671 471.5 61988 472 62407 472.5 62926 473 63602 473.5 64475 474 65503 474.5 66737 475 68179 475.5 69879 476 71776 476.5 73875 477 76224 477.5 78768 478 81446 478.5 84261 479 87177 479.5 90175 480 93100 480.5 96037 481 98893 481.5 101631 482 104157 482.5 106467 483 108533 483.5 110356 484 111907 484.5 113153 485 114103 485.5 114736 486 115104 486.5 115177 487 114999 487.5 114536 488 113790 488.5 112801 489 111580 489.5 110065 490 108309 490.5 106311 491 104043 491.5 101542 492 98801 492.5 95839 493 92619 493.5 89201 494 85637 494.5 81912 495 78030 495.5 74048 496 70025 496.5 65993 497 61951 497.5 57926 498 54022 498.5 50235 499 46525 499.5 42960 500 39593 500.5 36389 501 33361 501.5 30479 502 27813 502.5 25348 503 23015 503.5 20882 504 18908 504.5 17128 505 15460 505.5 13933 506 12567 506.5 11320 507 10173 507.5 9137 508 8198 508.5 7358 509 6592 509.5 5897 510 5283 510.5 4724 511 4228 511.5 3773 512 3378 512.5 3011 513 2690 513.5 2399 514 2135 514.5 1936 515 1709 515.5 1542 516 1372 516.5 1233 517 1094 517.5 979 518 864 518.5 771 519 684 519.5 612 520 549 520.5 484 521 435 521.5 380 522 342 522.5 301 523 259 523.5 232 524 199 524.5 186 525 157 525.5 131 526 116 526.5 99 527 85 527.5 72 528 51 528.5 48 529 40 529.5 38 530 29 530.5 13 531 17 531.5 6 532 -8 532.5 -6 533 -13 533.5 -11 534 -20 534.5 -26 535 -20 535.5 -23 536 -30 536.5 -33 537 -34 537.5 -35 538 -34 538.5 -34 539 -39 539.5 -37 540 -36 540.5 -42 541 -42 541.5 -37 542 -45 542.5 -42 543 -48 543.5 -39 544 -35 544.5 -37 545 -40 545.5 -38 546 -37 546.5 -37 547 -37 547.5 -38 548 -39 548.5 -38 549 -35 549.5 -40 550 -40