# Optical absorption spectrum of 5,10-Diaryl Cu-chlorin in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by M. Taniguchi on 10-02-2004 using a HP 8453. #The absorption values were collected using a spectral bandwidth of 1.0 nm. # # These measurements were scaled to make the molar extinction coefficient match # the value of 162000 cm-1/M at 408.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Taniguchi, M., H.-J. Kim, D. Ra, J. K. Schwartz, C. Kirmaier, E. Hindin, J. R. Diers, S. Prathapan, D. F. Bocian, D. Holten and J. S. Lindsey (2002) Synthesis and electronic properties of regioisomerically pure oxochlorins. J. Org. Chem. 67, 7329-7342. # ##Wavelength (nm) Molar Extinction (cm-1/M) 350 8703 351 8641 352 8506 353 8400 354 8333 355 8459 356 8403 357 8372 358 8519 359 8390 360 8681 361 8987 362 9134 363 9348 364 9482 365 9780 366 10110 367 10573 368 10856 369 11384 370 11897 371 12444 372 13185 373 14064 374 14944 375 16010 376 17241 377 18660 378 20066 379 21623 380 23332 381 25197 382 27034 383 28909 384 30544 385 32204 386 33595 387 34613 388 35582 389 36626 390 37535 391 38683 392 39967 393 41491 394 43309 395 45870 396 49150 397 53371 398 58640 399 65293 400 73129 401 82205 402 92619 403 104513 404 118251 405 132536 406 145343 407 155536 408 161999 409 163677 410 160235 411 152529 412 141074 413 127322 414 112429 415 98042 416 82872 417 69635 418 58090 419 47894 420 39310 421 32243 422 26601 423 22055 424 18461 425 15686 426 13719 427 12299 428 10613 429 9382 430 8168 431 7250 432 6445 433 5786 434 5139 435 4773 436 4216 437 4036 438 3708 439 3513 440 3404 441 3197 442 2995 443 2803 444 2722 445 2606 446 2545 447 2407 448 2360 449 2268 450 2258 451 2409 452 2191 453 2186 454 2183 455 2129 456 2123 457 2241 458 2231 459 2242 460 2174 461 2203 462 2257 463 2258 464 2223 465 2173 466 2241 467 2197 468 2325 469 2356 470 2349 471 2345 472 2246 473 2308 474 2305 475 2283 476 2338 477 2255 478 2261 479 2363 480 2321 481 2339 482 2400 483 2393 484 2504 485 2616 486 2738 487 2744 488 2860 489 3012 490 3175 491 3272 492 3540 493 3620 494 3774 495 3907 496 4114 497 4262 498 4386 499 4396 500 4510 501 4499 502 4475 503 4489 504 4406 505 4451 506 4304 507 4275 508 4126 509 4044 510 3939 511 3804 512 3664 513 3567 514 3479 515 3438 516 3424 517 3182 518 3174 519 3141 520 3069 521 3062 522 2944 523 2911 524 2922 525 2837 526 2812 527 2799 528 2756 529 2629 530 2595 531 2529 532 2657 533 2550 534 2615 535 2629 536 2564 537 2590 538 2558 539 2556 540 2551 541 2577 542 2506 543 2576 544 2583 545 2682 546 2643 547 2746 548 2897 549 3003 550 3299 551 3477 552 3810 553 4128 554 4350 555 4593 556 4961 557 5248 558 5391 559 5606 560 5776 561 5897 562 5856 563 5816 564 5779 565 5886 566 5782 567 5774 568 5838 569 5775 570 5670 571 5523 572 5477 573 5382 574 5288 575 5256 576 5205 577 5101 578 5059 579 5062 580 5120 581 5132 582 5127 583 5150 584 5323 585 5565 586 5697 587 5913 588 6200 589 6476 590 6860 591 7369 592 7989 593 8718 594 9771 595 10986 596 12539 597 14553 598 16693 599 19125 600 21750 601 24276 602 26448 603 27994 604 28817 605 28581 606 27557 607 26053 608 24232 609 22311 610 20278 611 18290 612 16393 613 14615 614 12993 615 11549 616 10325 617 9199 618 8358 619 7747 620 7179 621 6584 622 5972 623 5547 624 5104 625 4638 626 4289 627 4003 628 3695 629 3403 630 3189 631 3016 632 2798 633 2523 634 2379 635 2250 636 2066 637 1940 638 1809 639 1710 640 1559 641 1486 642 1459 643 1307 644 1319 645 1175 646 1089 647 1068 648 1030 649 958 650 910 651 884 652 789 653 901 654 866 655 857 656 798 657 871 658 645 659 774 660 694 661 765 662 607 663 645 664 584 665 600 666 625 667 509 668 506 669 513 670 545 671 613 672 555 673 540 674 535 675 508 676 492 677 496 678 475 679 469 680 344 681 487 682 414 683 443 684 435 685 417 686 509 687 405 688 364 689 395 690 478 691 436 692 345 693 421 694 401 695 389 696 285 697 481 698 381 699 452 700 428 701 496 702 415 703 471 704 433 705 375 706 388 707 386 708 402 709 377 710 333 711 365 712 396 713 411 714 406 715 420 716 339 717 445 718 372 719 367 720 367 721 280 722 325 723 349 724 317 725 376 726 338 727 471 728 448 729 341 730 437 731 372 732 397 733 348 734 340 735 297 736 386 737 305 738 277 739 389 740 422 741 384 742 347 743 426 744 356 745 429 746 353 747 344 748 426 749 377 750 302 751 354 752 301 753 270 754 433 755 359 756 318 757 364 758 433 759 363 760 436 761 442 762 413 763 350 764 364 765 438 766 445 767 420 768 334 769 271 770 330 771 312 772 312 773 338 774 333 775 362 776 549 777 257 778 467 779 392 780 325 781 300 782 337 783 456 784 327 785 323 786 434 787 426 788 446 789 479 790 386 791 267 792 491 793 441 794 324 795 374 796 424 797 497 798 434 799 456 800 411