# Optical absorption spectrum of Zinc tetramesitylporphyrin radical cation in dichloromethane # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by R. W. Wagner on 12-11-1997 using a Cary 3. # The absorption values were collected using a spectral bandwidth of 1.0 nm, a signal averaging time of 0.133 sec, a data interval of 0.25 nm, and a scan rate of 112.5 nm/min. # # These measurements were scaled to make the molar extinction coefficient match # the value of 190000 cm-1/M at 408.5 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Fajer, J., D. C. Borg, A. Forman, D. Dolphin and R. H. Felton (1970) p-Cation radicals and dications of metalloporphyrins. J. Am. Chem. Soc. 92, 3451-3459. # ##Wavelength (nm) Molar Extinction (cm-1/M) 300 43153 302 44061 304 44933 306 45614 308 46284 310 46824 312 47234 314 47643 316 47907 318 48179 320 48503 322 48846 324 49192 326 49568 328 49966 330 50454 332 50938 334 51493 336 52051 338 52658 340 53347 342 54088 344 54863 346 55622 348 56341 350 57037 352 57648 354 58344 356 59278 358 60407 360 62361 362 63050 364 64554 366 65653 368 66453 370 67202 372 67809 374 68527 376 69261 378 69998 380 70940 382 72452 384 74890 386 78256 388 82173 390 85889 392 88756 394 90763 396 92081 398 93712 400 97815 402 107562 404 126034 406 153367 408 184680 410 205959 412 209872 414 202071 416 189282 418 173257 420 149696 422 121648 424 94620 426 72731 428 58333 430 49158 432 43927 434 40375 436 38007 438 36417 440 35098 442 34201 444 33428 446 32889 448 32485 450 32162 452 31877 454 31536 456 31258 458 30769 460 30394 462 29838 464 29099 466 28696 468 28082 470 27474 472 26764 474 26264 476 25781 478 25304 480 24787 482 24554 484 24014 486 24247 488 23759 490 23236 492 22924 494 22833 496 22446 498 22310 500 22321 502 22145 504 22077 506 22003 508 21890 510 21793 512 21844 514 21702 516 21583 518 21554 520 21600 522 21606 524 21463 526 21537 528 21537 530 21736 532 21787 534 21958 536 22196 538 22242 540 22565 542 22821 544 22980 546 23276 548 23367 550 23440 552 23355 554 23372 556 23310 558 23384 560 23191 562 23435 564 23361 566 23520 568 23634 570 23827 572 24207 574 24207 576 24230 578 24509 580 24304 582 24463 584 24571 586 25469 588 25770 590 25900 592 25781 594 26332 596 26798 598 26730 600 27134 602 27423 604 27940 606 28077 608 28093 610 28196 612 28616 614 28667 616 29054 618 29156 620 29235 622 29076 624 29270 626 29383 628 29480 630 29588 632 29542 634 29633 636 29417 638 29440 640 29548 642 29718 644 29855 646 29690 648 29633 650 29980 652 30110 654 30110 656 30548 658 30377 660 31423 662 31497 664 31820 666 32394 668 32468 670 32883 672 32894 674 33462 676 33468 678 33616 680 33695 682 33656 684 33224 686 33241 688 32860 690 32548 692 31940 694 31463 696 30377 698 29906 700 29065 702 27855 704 27383 706 26247 708 25719 710 24850 712 24207 714 23327 716 23037 718 22282 720 21998 722 21515 724 21202 726 20503 728 20350 730 20151 732 19748 734 19231 736 19378 738 19367 740 18958 742 18799 744 18583 746 18515 748 18304 750 17844 752 18685 754 18947 756 18714 758 18185 760 18015 762 18316 764 17986 766 18191 768 18106 770 18128 772 18100 774 17890 776 18163 778 18242 780 18083 782 18015 784 17901 786 17981 788 17941 790 17981 792 18145 794 17907 796 18185 798 17640 800 17964 802 18083 804 18089 806 17975 808 17952 810 17998 812 18134 814 17793 816 18333 818 18032 820 18174