# Emission spectrum of in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on in 1994 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 490 570684 491 303992 492 197898 493 185277 494 218565 495 269773 496 333205 497 414833 498 507346 499 627790 500 761797 501 925281 502 1090069 503 1303444 504 1513928 505 1775388 506 2007419 507 2274693 508 2518215 509 2784285 510 2993087 511 3230650 512 3425289 513 3629318 514 3796370 515 3947895 516 4070052 517 4169377 518 4246771 519 4308176 520 4335866 521 4340845 522 4325298 523 4305630 524 4255169 525 4182752 526 4122881 527 4028238 528 3937901 529 3824207 530 3723109 531 3613248 532 3499504 533 3394659 534 3304500 535 3202590 536 3120383 537 3030634 538 2953213 539 2866991 540 2803375 541 2711600 542 2654250 543 2584831 544 2523282 545 2456963 546 2405605 547 2347517 548 2293169 549 2236152 550 2183974 551 2125397 552 2081934 553 2019276 554 1974709 555 1911268 556 1864371 557 1811002 558 1768459 559 1712508 560 1670985 561 1619411 562 1578470 563 1530976 564 1490548 565 1438095 566 1398635 567 1352280 568 1314351 569 1273762 570 1228130 571 1186137 572 1145353 573 1104020 574 1063855 575 1020964 576 986645 577 946785 578 912837 579 879237 580 849435 581 817133 582 791732 583 764257 584 740357 585 711654 586 695964 587 669490 588 649063 589 628750 590 609340 591 585762 592 571476 593 552197 594 534774 595 518473 596 502814 597 487250 598 473230 599 458103 600 444935 601 430880 602 416612 603 404503 604 393023 605 381665 606 369160 607 361107 608 351131 609 340381 610 328564 611 319434 612 310744 613 302818 614 293083 615 285369 616 278742 617 269361 618 263125 619 256345 620 249467 621 243217 622 237009 623 231824 624 225337 625 219234 626 212298 627 205495 628 200672 629 194601 630 190856 631 185170 632 182238 633 177335 634 173571 635 170381 636 164453 637 161787 638 157283 639 154275 640 150939 641 149395 642 144721 643 142561 644 139762 645 138157 646 134932 647 133411 648 132814 649 127866 650 128327 651 124526 652 123857 653 120343 654 120024 655 117977 656 118045 657 114412 658 113642 659 111768 660 110033 661 108293 662 108811 663 106804 664 106088 665 104981 666 103865 667 103737 668 100877 669 100904 670 99789 671 99322 672 100261 673 98097 674 98273 675 96674 676 95067 677 95154 678 93137 679 93016 680 93076 681 91884 682 91970 683 91540 684 91168 685 89806 686 89803 687 90007 688 88480 689 86814 690 88606 691 87216 692 87403 693 86941 694 86142 695 86302 696 85726 697 82499 698 84092 699 84860 700 82850 701 83937 702 82967 703 82858 704 81195 705 80695 706 80431 707 81072 708 80396 709 80107 710 79885 711 78476 712 80409 713 78414 714 79105 715 78475 716 78449 717 75303 718 76690 719 76050 720 76626 721 75450 722 76414 723 75867 724 76151 725 74355 726 75153 727 74586 728 74618 729 73618 730 74417 731 72568 732 71162 733 71483 734 72239 735 71508 736 70856 737 71449 738 72114 739 70749 740 69458 741 67253 742 67809 743 67842 744 67736 745 68234 746 66178 747 69050 748 67223 749 68078 750 64354 751 65041 752 63654 753 63835 754 63014 755 63946 756 62499 757 61791 758 60614 759 63894 760 61560 761 59779 762 56926 763 58538 764 61287 765 61201 766 56599 767 57410 768 57847 769 57391 770 58150 771 57270 772 57490 773 55311 774 56125 775 55705 776 54350 777 55863 778 55086 779 52865 780 56144 781 52799 782 53387 783 51127 784 51730 785 52072 786 50778 787 52329 788 50617 789 50669 790 49427 791 49156 792 48952 793 46991 794 49924 795 48901 796 47836 797 48344 798 47464 799 48129 800 46179