# Emission spectrum of in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on in 1994 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 490 151812 491 94086 492 75876 493 80623 494 98198 495 124143 496 153944 497 197906 498 253104 499 325931 500 419870 501 546688 502 687585 503 889955 504 1122484 505 1441104 506 1774134 507 2197779 508 2631065 509 3157745 510 3634115 511 4220791 512 4747340 513 5349803 514 5889683 515 6499018 516 7023176 517 7572073 518 8022878 519 8467663 520 8825569 521 9179608 522 9433822 523 9651184 524 9812214 525 9903684 526 9929101 527 9929035 528 9851342 529 9730125 530 9573513 531 9340179 532 9116576 533 8830296 534 8598068 535 8290872 536 8027534 537 7710228 538 7450854 539 7128757 540 6866148 541 6558695 542 6316880 543 6049664 544 5822797 545 5583564 546 5390722 547 5191651 548 5009453 549 4846236 550 4686523 551 4543303 552 4433795 553 4299554 554 4184613 555 4076616 556 3983801 557 3898336 558 3825880 559 3730627 560 3666168 561 3586675 562 3515243 563 3426210 564 3356121 565 3271065 566 3193600 567 3104617 568 3025716 569 2936827 570 2850990 571 2759385 572 2671273 573 2577663 574 2486887 575 2397874 576 2314957 577 2212109 578 2125227 579 2031112 580 1952325 581 1858250 582 1791246 583 1710669 584 1646589 585 1570960 586 1510626 587 1442271 588 1387820 589 1318046 590 1269401 591 1212249 592 1170826 593 1120218 594 1073956 595 1033781 596 996426 597 961008 598 925041 599 887292 600 859622 601 826716 602 800572 603 768976 604 745764 605 721532 606 698303 607 678055 608 659461 609 636034 610 623117 611 601200 612 585432 613 564282 614 550211 615 529921 616 517046 617 504561 618 488633 619 473022 620 458522 621 447091 622 434230 623 422623 624 411863 625 394921 626 380801 627 368913 628 353545 629 338446 630 329214 631 318282 632 307571 633 295253 634 287644 635 276279 636 266157 637 255648 638 246275 639 237879 640 230623 641 222466 642 215185 643 207123 644 200743 645 193714 646 187841 647 182124 648 176276 649 171163 650 165305 651 157948 652 154301 653 148954 654 145845 655 141158 656 136557 657 133161 658 130381 659 125302 660 121448 661 118737 662 116147 663 112478 664 110298 665 108026 666 104081 667 102654 668 100227 669 98077 670 95969 671 94153 672 92148 673 88092 674 88236 675 86380 676 84768 677 82766 678 80616 679 79421 680 77482 681 76667 682 74391 683 73053 684 71699 685 69791 686 69064 687 67913 688 67609 689 65600 690 65765 691 64936 692 63317 693 61372 694 61346 695 59955 696 59792 697 57202 698 58744 699 56659 700 55862 701 55641 702 54195 703 53621 704 53915 705 53618 706 53014 707 52253 708 51262 709 51055 710 50565 711 49544 712 50038 713 49386 714 48180 715 47996 716 47992 717 45659 718 47062 719 47204 720 46056 721 45376 722 45565 723 44049 724 45196 725 43592 726 44049 727 42332 728 42175 729 43494 730 43500 731 41466 732 41536 733 40998 734 42161 735 42033 736 41803 737 40359 738 41998 739 42521 740 40079 741 41568 742 41017 743 41294 744 39718 745 39790 746 40309 747 39269 748 39517 749 40533 750 40104 751 39554 752 38490 753 37758 754 39990 755 37731 756 38026 757 36889 758 38029 759 39284 760 38287 761 36227 762 38103 763 37443 764 37771 765 37290 766 36310 767 37292 768 37657 769 37449 770 36201 771 37042 772 35217 773 36646 774 37075 775 36690 776 36021 777 36647 778 36770 779 36534 780 36177 781 36088 782 37958 783 35463 784 34826 785 35144 786 35915 787 35818 788 36982 789 35004 790 35370 791 36604 792 36801 793 36414 794 34395 795 34784 796 36504 797 33917 798 34785 799 35770 800 36747