# Optical absorption spectrum of Tetramesitylporphyrin, [TMP] in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by R. W. Wagner in 1994 using a Cary 3. # The absorption values were collected using a spectral bandwidth of 1.0 nm, a signal averaging time of 0.133 sec, a data interval of 0.25 nm, and a scan rate of 112.5 nm/min. # # These measurements were scaled to make the molar extinction coefficient match # the value of 427000 cm-1/M at 426.5 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Lindsey, J. S. and R. W. Wagner (1989) Investigation of the synthesis of ortho-substituted tetraphenylporphyrins. J. Org. Chem. 54, 828-836. # ##Wavelength (nm) Molar Extinction (cm-1/M) 349.75 8451 350 4849 350.25 4545 350.5 4102 350.75 5813 351 6954 351.25 4970 351.5 4575 351.75 8160 352 4169 352.25 5550 352.5 5854 352.75 8199 353 3841 353.25 7003 353.5 7388 353.75 7747 354 6657 354.25 7082 354.5 7011 354.75 4871 355 6888 355.25 5959 355.5 6634 355.75 6730 356 5186 356.25 5050 356.5 3704 356.75 5487 357 4477 357.25 6046 357.5 4768 357.75 5615 358 4127 358.25 5953 358.5 5923 358.75 7066 359 4441 359.25 5346 359.5 3338 359.75 4534 360 6919 360.25 6012 360.5 5440 360.75 5724 361 5480 361.25 5163 361.5 5817 361.75 4511 362 5517 362.25 2917 362.5 4616 362.75 5436 363 4383 363.25 3902 363.5 3356 363.75 5900 364 4417 364.25 4526 364.5 6303 364.75 5779 365 7192 365.25 4008 365.5 3532 365.75 4667 366 5371 366.25 2442 366.5 5094 366.75 6104 367 4757 367.25 6609 367.5 4288 367.75 5172 368 5279 368.25 4165 368.5 5210 368.75 4702 369 6116 369.25 4274 369.5 3931 369.75 4753 370 4814 370.25 5569 370.5 2862 370.75 4677 371 4957 371.25 5250 371.5 6554 371.75 5243 372 5367 372.25 3758 372.5 6817 372.75 5453 373 5519 373.25 6783 373.5 4987 373.75 5690 374 5107 374.25 3225 374.5 5257 374.75 4255 375 3831 375.25 5393 375.5 4816 375.75 2800 376 6273 376.25 4352 376.5 4497 376.75 5870 377 3892 377.25 5097 377.5 6573 377.75 4448 378 3512 378.25 4781 378.5 4685 378.75 3783 379 3193 379.25 4555 379.5 6391 379.75 4075 380 3416 380.25 5177 380.5 3170 380.75 4998 381 4647 381.25 4732 381.5 3088 381.75 4984 382 4755 382.25 4856 382.5 4570 382.75 4844 383 4923 383.25 4611 383.5 4403 383.75 4806 384 4023 384.25 4391 384.5 5402 384.75 5336 385 5288 385.25 6316 385.5 6461 385.75 4917 386 4252 386.25 6391 386.5 5683 386.75 5976 387 5387 387.25 5092 387.5 8066 387.75 6427 388 5567 388.25 5862 388.5 5362 388.75 4841 389 6095 389.25 6203 389.5 7523 389.75 6671 390 7349 390.25 6343 390.5 5988 390.75 5767 391 6425 391.25 6637 391.5 5383 391.75 5884 392 5988 392.25 4877 392.5 7323 392.75 6811 393 7901 393.25 6540 393.5 6290 393.75 5987 394 6837 394.25 7628 394.5 6371 394.75 7480 395 6920 395.25 10086 395.5 8293 395.75 7853 396 9104 396.25 8967 396.5 9684 396.75 9776 397 10739 397.25 11981 397.5 11943 397.75 12443 398 14039 398.25 13435 398.5 12613 398.75 14229 399 16220 399.25 16894 399.5 16131 399.75 16942 400 17086 400.25 18324 400.5 18584 400.75 21849 401 22924 401.25 23130 401.5 22354 401.75 25359 402 25100 402.25 26412 402.5 27606 402.75 27782 403 26721 403.25 28102 403.5 28967 403.75 30156 404 30886 404.25 30964 404.5 30892 404.75 30555 405 30048 405.25 30106 405.5 29159 405.75 30705 406 29446 406.25 29396 406.5 28130 406.75 28427 407 27702 407.25 27806 407.5 27669 407.75 28273 408 26279 408.25 27543 408.5 26639 408.75 25636 409 24506 409.25 25692 409.5 23911 409.75 24052 410 25243 410.25 24087 410.5 24415 410.75 22507 411 22794 411.25 23428 411.5 21676 411.75 23929 412 21236 412.25 22429 412.5 23005 412.75 22570 413 24166 413.25 24976 413.5 25380 413.75 25077 414 26623 414.25 26610 414.5 26148 414.75 28379 415 29066 415.25 30861 415.5 30209 415.75 32793 416 36419 416.25 38745 416.5 41022 416.75 44309 417 48655 417.25 50157 417.5 54153 417.75 58357 418 63280 418.25 67155 418.5 73360 418.75 78902 419 83010 419.25 86657 419.5 93878 419.75 97387 420 102663 420.25 108056 420.5 113980 420.75 119910 421 126860 421.25 134474 421.5 140695 421.75 151110 422 160258 422.25 171428 422.5 184626 422.75 198889 423 214985 423.25 231625 423.5 248987 423.75 268410 424 287555 424.25 308938 424.5 328283 424.75 346076 425 365120 425.25 381375 425.5 394597 425.75 408664 426 417269 426.25 422987 426.5 427000 426.75 426642 427 424429 427.25 419333 427.5 410484 427.75 400026 428 387185 428.25 372934 428.5 355577 428.75 337992 429 317911 429.25 298731 429.5 282228 429.75 261910 430 242428 430.25 224039 430.5 204857 430.75 190426 431 174047 431.25 157928 431.5 145893 431.75 130586 432 121001 432.25 106557 432.5 99676 432.75 88656 433 81346 433.25 73869 433.5 66575 433.75 60225 434 56507 434.25 50473 434.5 46911 434.75 41962 435 37211 435.25 34296 435.5 29726 435.75 27251 436 23364 436.25 21627 436.5 19330 436.75 18477 437 17873 437.25 16416 437.5 14926 437.75 14543 438 12924 438.25 12163 438.5 10498 438.75 9724 439 9884 439.25 9651 439.5 9213 439.75 8015 440 7902 440.25 8081 440.5 7508 440.75 8303 441 6781 441.25 7101 441.5 7551 441.75 7259 442 7194 442.25 6648 442.5 6989 442.75 5363 443 5578 443.25 5601 443.5 6518 443.75 5234 444 5273 444.25 5920 444.5 4713 444.75 5476 445 5581 445.25 4798 445.5 4779 445.75 4548 446 3963 446.25 4727 446.5 5509 446.75 3372 447 3052 447.25 5239 447.5 4392 447.75 5440 448 3660 448.25 3968 448.5 4192 448.75 4457 449 4553 449.25 2937 449.5 3639 449.75 2500 450 3348 450.25 2188 450.5 2675 450.75 2479 451 2267 451.25 3153 451.5 2301 451.75 1917 452 2456 452.25 2263 452.5 1971 452.75 2353 453 2136 453.25 2062 453.5 2344 453.75 1943 454 870 454.25 2167 454.5 1342 454.75 1222 455 640 455.25 1218 455.5 1524 455.75 2039 456 1025 456.25 2430 456.5 1609 456.75 1725 457 1690 457.25 1966 457.5 1154 457.75 1069 458 705 458.25 1040 458.5 31 458.75 -77 459 1119 459.25 784 459.5 1162 459.75 1677 460 761 460.25 1416 460.5 2410 460.75 184 461 958 461.25 1187 461.5 2034 461.75 955 462 862 462.25 198 462.5 1132 462.75 1228 463 818 463.25 901 463.5 1335 463.75 1505 464 1046 464.25 874 464.5 634 464.75 467 465 1373 465.25 868 465.5 141 465.75 622 466 999 466.25 674 466.5 721 466.75 1052 467 1111 467.25 570 467.5 1595 467.75 1126 468 920 468.25 36 468.5 947 468.75 178 469 771 469.25 106 469.5 1592 469.75 1289 470 1277 470.25 186 470.5 320 470.75 881 471 1185 471.25 124 471.5 1365 471.75 791 472 857 472.25 401 472.5 641 472.75 1223 473 684 473.25 255 473.5 691 473.75 977 474 1133 474.25 13 474.5 532 474.75 43 475 1037 475.25 760 475.5 1533 475.75 1147 476 1160 476.25 1319 476.5 -58 476.75 932 477 840 477.25 495 477.5 1312 477.75 482 478 866 478.25 443 478.5 483 478.75 1499 479 289 479.25 454 479.5 1266 479.75 1864 480 865 480.25 371 480.5 296 480.75 1720 481 516 481.25 595 481.5 134 481.75 122 482 389 482.25 1786 482.5 1104 482.75 190 483 1025 483.25 2189 483.5 518 483.75 950 484 1433 484.25 1312 484.5 -44 484.75 323 485 1124 485.25 753 485.5 224 485.75 1267 486 1536 486.25 257 486.5 679 486.75 647 487 1842 487.25 1104 487.5 1450 487.75 897 488 753 488.25 1008 488.5 801 488.75 1734 489 1049 489.25 499 489.5 1298 489.75 277 490 904 490.25 117 490.5 1210 490.75 1168 491 1334 491.25 -91 491.5 1198 491.75 1336 492 1480 492.25 689 492.5 1701 492.75 1486 493 1312 493.25 1467 493.5 1956 493.75 705 494 1031 494.25 2117 494.5 1204 494.75 606 495 -169 495.25 611 495.5 766 495.75 1165 496 1573 496.25 510 496.5 1002 496.75 1644 497 1174 497.25 977 497.5 1763 497.75 730 498 829 498.25 2015 498.5 1553 498.75 1058 499 451 499.25 456 499.5 -94 499.75 1218 500 1758 500.25 1814 500.5 1886 500.75 2417 501 491 501.25 734 501.5 1091 501.75 1104 502 1521 502.25 999 502.5 450 502.75 1363 503 1184 503.25 325 503.5 1724 503.75 799 504 1154 504.25 1320 504.5 1641 504.75 2268 505 1101 505.25 1795 505.5 616 505.75 1754 506 1656 506.25 1035 506.5 1420 506.75 1515 507 1398 507.25 1808 507.5 1422 507.75 1672 508 1579 508.25 1876 508.5 1818 508.75 60 509 2074 509.25 1858 509.5 1295 509.75 1802 510 1226 510.25 529 510.5 922 510.75 1601 511 1606 511.25 1984 511.5 1460 511.75 2044 512 1682 512.25 1578 512.5 2492 512.75 1805 513 1946 513.25 1366 513.5 922 513.75 2045 514 1483 514.25 2662 514.5 2188 514.75 2432 515 2523 515.25 3094 515.5 985 515.75 2673 516 2540 516.25 1005 516.5 1299 516.75 1577 517 1397 517.25 1656 517.5 1317 517.75 2666 518 2371 518.25 2662 518.5 1837 518.75 2107 519 2708 519.25 2202 519.5 2655 519.75 1315 520 1868 520.25 1480 520.5 2563 520.75 2548 521 2205 521.25 1420 521.5 1712 521.75 2124 522 2352 522.25 2880 522.5 1859 522.75 2754 523 2248 523.25 2321 523.5 2963 523.75 2564 524 2315 524.25 1768 524.5 1810 524.75 1171 525 1582 525.25 2573 525.5 2039 525.75 1621 526 2045 526.25 2697 526.5 3447 526.75 2448 527 3153 527.25 1812 527.5 2430 527.75 1889 528 1305 528.25 1776 528.5 2578 528.75 1220 529 2591 529.25 1753 529.5 2489 529.75 1477 530 2143 530.25 2607 530.5 2977 530.75 2384 531 2286 531.25 1189 531.5 2223 531.75 1938 532 2376 532.25 1894 532.5 1960 532.75 1203 533 990 533.25 2041 533.5 1356 533.75 1434 534 1555 534.25 2312 534.5 2351 534.75 1937 535 1913 535.25 1881 535.5 1158 535.75 1464 536 1788 536.25 1424 536.5 1313 536.75 1205 537 741 537.25 1738 537.5 1509 537.75 2142 538 2162 538.25 2404 538.5 1393 538.75 1946 539 1791 539.25 1598 539.5 1866 539.75 1454 540 2089 540.25 1332 540.5 2114 540.75 1738 541 2003 541.25 1884 541.5 1769 541.75 2096 542 1569 542.25 2539 542.5 1985 542.75 1057 543 2627 543.25 2809 543.5 2400 543.75 2084 544 3315 544.25 1947 544.5 1349 544.75 2431 545 1750 545.25 2432 545.5 2187 545.75 3261 546 2422 546.25 3424 546.5 2297 546.75 2974 547 3316 547.25 3023 547.5 2529 547.75 3161 548 3273 548.25 2278 548.5 3341 548.75 2928 549 3468 549.25 3052 549.5 4217 549.75 3468 550 3036 550.25 3936 550.5 4120 550.75 4482 551 4386 551.25 4612 551.5 4407 551.75 5134 552 5181 552.25 5576 552.5 5294 552.75 5819 553 5766 553.25 6221 553.5 6598 553.75 7209 554 6078 554.25 6536 554.5 6794 554.75 7152 555 8474 555.25 8151 555.5 7279 555.75 7557 556 8572 556.25 8449 556.5 9019 556.75 8867 557 9502 557.25 9571 557.5 9628 557.75 9562 558 10458 558.25 10093 558.5 9907 558.75 10276 559 10386 559.25 10051 559.5 10877 559.75 10278 560 11726 560.25 11000 560.5 12173 560.75 11951 561 11286 561.25 11915 561.5 11614 561.75 12155 562 11724 562.25 12375 562.5 13462 562.75 13352 563 13626 563.25 12491 563.5 14347 563.75 13800 564 12695 564.25 13614 564.5 14754 564.75 14343 565 14681 565.25 14439 565.5 14576 565.75 14346 566 13960 566.25 13978 566.5 14254 566.75 14249 567 13502 567.25 12767 567.5 13388 567.75 12895 568 14073 568.25 13520 568.5 12191 568.75 11404 569 12420 569.25 11652 569.5 11997 569.75 11097 570 12239 570.25 10371 570.5 10375 570.75 11059 571 9642 571.25 9636 571.5 9665 571.75 8942 572 9231 572.25 8925 572.5 7966 572.75 6901 573 7888 573.25 8293 573.5 8012 573.75 7690 574 7139 574.25 6588 574.5 7162 574.75 6140 575 6121 575.25 6518 575.5 6887 575.75 6440 576 5572 576.25 6565 576.5 5628 576.75 5402 577 6044 577.25 5382 577.5 5246 577.75 4877 578 4705 578.25 4953 578.5 4814 578.75 4478 579 4058 579.25 3794 579.5 3351 579.75 4192 580 3500 580.25 2884 580.5 3818 580.75 4191 581 2320 581.25 3445 581.5 3461 581.75 3257 582 2962 582.25 1891 582.5 1610 582.75 3035 583 3053 583.25 3682 583.5 2574 583.75 2789 584 2812 584.25 2295 584.5 2979 584.75 2686 585 1837 585.25 2303 585.5 3206 585.75 1507 586 1993 586.25 2000 586.5 1302 586.75 1316 587 1893 587.25 2039 587.5 2355 587.75 2363 588 1842 588.25 2069 588.5 2333 588.75 1411 589 2205 589.25 2100 589.5 2722 589.75 1466 590 1374 590.25 2172 590.5 1820 590.75 2432 591 1652 591.25 2389 591.5 1682 591.75 2283 592 2480 592.25 2099 592.5 1802 592.75 2117 593 1513 593.25 1498 593.5 1594 593.75 2570 594 2477 594.25 1903 594.5 1576 594.75 2760 595 3193 595.25 1319 595.5 2735 595.75 3431 596 2555 596.25 2510 596.5 1035 596.75 2488 597 2597 597.25 3029 597.5 2577 597.75 3543 598 3326 598.25 4027 598.5 3406 598.75 3541 599 3872 599.25 3617 599.5 5270 599.75 4503 600 3528 600.25 3868 600.5 5079 600.75 5057 601 5255 601.25 4733 601.5 5396 601.75 5045 602 5566 602.25 4935 602.5 5981 602.75 5546 603 5110 603.25 5969 603.5 4956 603.75 5401 604 4852 604.25 4847 604.5 5666 604.75 5217 605 6009 605.25 5479 605.5 4636 605.75 4397 606 4283 606.25 4895 606.5 5372 606.75 4145 607 3853 607.25 4630 607.5 4473 607.75 3083 608 3610 608.25 3479 608.5 4301 608.75 3568 609 3197 609.25 2588 609.5 2782 609.75 2987 610 3126 610.25 2394 610.5 896 610.75 2033 611 2635 611.25 2800 611.5 2115 611.75 1609 612 3052 612.25 2106 612.5 1262 612.75 1963 613 825 613.25 2379 613.5 1372 613.75 1417 614 1969 614.25 2153 614.5 1596 614.75 2333 615 1091 615.25 1848 615.5 1108 615.75 1513 616 1840 616.25 2052 616.5 503 616.75 329 617 784 617.25 1776 617.5 1252 617.75 781 618 1106 618.25 694 618.5 1593 618.75 161 619 445 619.25 239 619.5 758 619.75 1504 620 475 620.25 1650 620.5 1120 620.75 1595 621 417 621.25 792 621.5 281 621.75 653 622 85 622.25 774 622.5 245 622.75 1664 623 -21 623.25 474 623.5 838 623.75 338 624 1530 624.25 1246 624.5 633 624.75 1219 625 89 625.25 1079 625.5 -262 625.75 558 626 -85 626.25 144 626.5 565 626.75 740 627 904 627.25 489 627.5 250 627.75 713 628 343 628.25 265 628.5 772 628.75 626 629 1377 629.25 459 629.5 763 629.75 193 630 1035 630.25 590 630.5 1362 630.75 1618 631 2165 631.25 -261 631.5 706 631.75 -676 632 502 632.25 716 632.5 860 632.75 325 633 -238 633.25 -40 633.5 1035 633.75 915 634 920 634.25 108 634.5 854 634.75 943 635 272 635.25 690 635.5 -46 635.75 362 636 -519 636.25 961 636.5 803 636.75 50 637 401 637.25 1098 637.5 1671 637.75 964 638 1486 638.25 1570 638.5 119 638.75 194 639 907 639.25 1731 639.5 -97 639.75 229 640 -355 640.25 103 640.5 986 640.75 880 641 1619 641.25 1286 641.5 1044 641.75 1166 642 -122 642.25 -212 642.5 827 642.75 580 643 639 643.25 584 643.5 47 643.75 368 644 729 644.25 1776 644.5 1239 644.75 1848 645 -165 645.25 -85 645.5 1550 645.75 1310 646 737 646.25 1128 646.5 38 646.75 120 647 519 647.25 362 647.5 731 647.75 -356 648 -171 648.25 342 648.5 2103 648.75 884 649 828 649.25 -454 649.5 1101 649.75 555 650 969 650.25 1181 650.5 -192 650.75 -555 651 794 651.25 1202 651.5 -167 651.75 881 652 92 652.25 445 652.5 -164 652.75 -72 653 832 653.25 2051 653.5 -843 653.75 301 654 -690 654.25 463 654.5 535 654.75 875 655 1784 655.25 -50 655.5 351 655.75 769 656 -177 656.25 1439 656.5 604 656.75 995 657 183 657.25 994 657.5 -248 657.75 1245 658 472 658.25 1288 658.5 -628 658.75 1164 659 1328 659.25 1140 659.5 287 659.75 262 660 1691 660.25 0 660.5 -503 660.75 1292 661 1411 661.25 -193 661.5 -676 661.75 419 662 938 662.25 -146 662.5 90 662.75 742 663 -32 663.25 438 663.5 227 663.75 798 664 709 664.25 298 664.5 280 664.75 691 665 891 665.25 405 665.5 138 665.75 170 666 -18 666.25 -92 666.5 751 666.75 1202 667 -769 667.25 1679 667.5 904 667.75 806 668 -146 668.25 459 668.5 772 668.75 7 669 1229 669.25 1231 669.5 -205 669.75 1496 670 863 670.25 343 670.5 960 670.75 1989 671 12 671.25 -1039 671.5 1911 671.75 1144 672 -415 672.25 287 672.5 608 672.75 -1081 673 67 673.25 -333 673.5 1139 673.75 1780 674 1167 674.25 1228 674.5 1006 674.75 458 675 789 675.25 1606 675.5 341 675.75 67 676 454 676.25 237 676.5 861 676.75 115 677 -214 677.25 537 677.5 216 677.75 474 678 228 678.25 508 678.5 -632 678.75 488 679 190 679.25 1001 679.5 992 679.75 285 680 571 680.25 194 680.5 1725 680.75 417 681 810 681.25 1242 681.5 1117 681.75 446 682 780 682.25 391 682.5 -312 682.75 -120 683 1090 683.25 -40 683.5 -329 683.75 -121 684 255 684.25 895 684.5 1317 684.75 369 685 327 685.25 394 685.5 685 685.75 -581 686 12 686.25 165 686.5 -174 686.75 -139 687 284 687.25 574 687.5 669 687.75 1598 688 858 688.25 51 688.5 242 688.75 219 689 788 689.25 442 689.5 1391 689.75 -66 690 575 690.25 385 690.5 1166 690.75 1324 691 830 691.25 953 691.5 172 691.75 48 692 579 692.25 118 692.5 399 692.75 726 693 1489 693.25 2254 693.5 504 693.75 541 694 522 694.25 -12 694.5 903 694.75 2111 695 708 695.25 932 695.5 488 695.75 -91 696 -28 696.25 1327 696.5 -194 696.75 -951 697 537 697.25 -145 697.5 839 697.75 912 698 260 698.25 1289 698.5 1228 698.75 -894 699 -872 699.25 776 699.5 -864 699.75 1062 700 -1333