# Emission spectrum of in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on on 06-25-1997 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 575 129691 575.5 132049 576 130922 576.5 131555 577 131126 577.5 132738 578 132586 578.5 132606 579 134241 579.5 136103 580 135675 580.5 137950 581 139799 581.5 141526 582 144336 582.5 147725 583 150279 583.5 156719 584 159090 584.5 168256 585 172743 585.5 182080 586 190378 586.5 204544 587 212113 587.5 230496 588 244177 588.5 271118 589 286854 589.5 319045 590 343105 590.5 388537 591 418734 591.5 476093 592 520985 592.5 603086 593 655549 593.5 758744 594 839422 594.5 975906 595 1058340 595.5 1228936 596 1348729 596.5 1560566 597 1680354 597.5 1920970 598 2087807 598.5 2389035 599 2561276 599.5 2847346 600 3063728 600.5 3402947 601 3575302 601.5 3871994 602 4087840 602.5 4400033 603 4563771 603.5 4799001 604 4955461 604.5 5169544 605 5271015 605.5 5419086 606 5504384 606.5 5609286 607 5664264 607.5 5710922 608 5738815 608.5 5740408 609 5730631 609.5 5700219 610 5670926 610.5 5580521 611 5537126 611.5 5429258 612 5365702 612.5 5222384 613 5157032 613.5 4999583 614 4929152 614.5 4759817 615 4687326 615.5 4531535 616 4443722 616.5 4281363 617 4207821 617.5 4045249 618 3960930 618.5 3801824 619 3733512 619.5 3589567 620 3502769 620.5 3363606 621 3310128 621.5 3179371 622 3109504 622.5 2974157 623 2917571 623.5 2806318 624 2733299 624.5 2614446 625 2559120 625.5 2464245 626 2403546 626.5 2301852 627 2264577 627.5 2186532 628 2143820 628.5 2065831 629 2040738 629.5 1992931 630 1964101 630.5 1913229 631 1898960 631.5 1859253 632 1846695 632.5 1819618 633 1808841 633.5 1793865 634 1791225 634.5 1782134 635 1778253 635.5 1768808 636 1779750 636.5 1783076 637 1785939 637.5 1799337 638 1806442 638.5 1829568 639 1847164 639.5 1875556 640 1896753 640.5 1932720 641 1962139 641.5 2004476 642 2037743 642.5 2100859 643 2135196 643.5 2202640 644 2250118 644.5 2336028 645 2387193 645.5 2486680 646 2542701 646.5 2664581 647 2731581 647.5 2852846 648 2942408 648.5 3092736 649 3176011 649.5 3322879 650 3440558 650.5 3610591 651 3710543 651.5 3886235 652 3999747 652.5 4194214 653 4306432 653.5 4482261 654 4584732 654.5 4770565 655 4885896 655.5 5048945 656 5152430 656.5 5342340 657 5435170 657.5 5592497 658 5692381 658.5 5837159 659 5913610 659.5 6040760 660 6119463 660.5 6213443 661 6265812 661.5 6332969 662 6352176 662.5 6392993 663 6410029 663.5 6400301 664 6397067 664.5 6344803 665 6312347 665.5 6249892 666 6215929 666.5 6120568 667 6053972 667.5 5947301 668 5870204 668.5 5697241 669 5634181 669.5 5468052 670 5374227 670.5 5189103 671 5107303 671.5 4903653 672 4787855 672.5 4585747 673 4462802 673.5 4277034 674 4151617 674.5 3935331 675 3834475 675.5 3658423 676 3547435 676.5 3344496 677 3261964 677.5 3100093 678 3007482 678.5 2833301 679 2765696 679.5 2620110 680 2538231 680.5 2386033 681 2336579 681.5 2200087 682 2134449 682.5 2007663 683 1947360 683.5 1832832 684 1778099 684.5 1661513 685 1618988 685.5 1527445 686 1479055 686.5 1398400 687 1345224 687.5 1283295 688 1238051 688.5 1166258 689 1132813 689.5 1070862 690 1037361 690.5 983763 691 961234 691.5 909512 692 878113 692.5 830694 693 818739 693.5 770859 694 748041 694.5 709883 695 694106 695.5 665690 696 648942 696.5 609961 697 597159 697.5 574386 698 558127 698.5 531497 699 522971 699.5 502378 700 493152 700.5 473184 701 468882 701.5 451832 702 446347 702.5 434662 703 429700 703.5 419652 704 412022 704.5 401652 705 393707 705.5 390208 706 385383 706.5 378244 707 372857 707.5 368312 708 367733 708.5 360725 709 360922 709.5 356283 710 350912 710.5 351255 711 348222 711.5 347201 712 350118 712.5 342154 713 343141 713.5 341019 714 342160 714.5 344417 715 342703 715.5 338000 716 340855 716.5 340977 717 340842 717.5 341965 718 337505 718.5 337793 719 341424 719.5 339216 720 333321 720.5 336429 721 337700 721.5 337216 722 336355 722.5 331766 723 335360 723.5 332962 724 331910 724.5 328012 725 331209 725.5 330256 726 325170 726.5 320659 727 321507 727.5 324293 728 320291 728.5 315604 729 315163 729.5 310532 730 309638 730.5 305448 731 303854 731.5 298862 732 295353 732.5 290630 733 289614 733.5 283048 734 284183 734.5 276349 735 273800 735.5 270970 736 264752 736.5 259034 737 255637 737.5 255144 738 249019 738.5 241675 739 237622 739.5 230165 740 231586 740.5 221302 741 223041 741.5 211035 742 208845 742.5 200777 743 203440 743.5 197219 744 188869 744.5 184551 745 180931 745.5 174665 746 173101 746.5 163578 747 161958 747.5 157158 748 153400 748.5 146390 749 147064 749.5 139181 750 137981 750.5 133433 751 126854 751.5 123965 752 122249 752.5 118529 753 113701 753.5 110963 754 108353 754.5 103226 755 101621 755.5 98180 756 95821 756.5 91130 757 91949 757.5 89037 758 86089 758.5 82352 759 77683 759.5 77969 760 76200 760.5 75445 761 72616 761.5 71400 762 68275 762.5 64743 763 64036 763.5 64413 764 63418 764.5 58742 765 58859 765.5 58428 766 58159 766.5 54260 767 53569 767.5 51319 768 53195 768.5 50486 769 50273 769.5 48202 770 46604 770.5 43875 771 46522 771.5 44965 772 45178 772.5 42155 773 40624 773.5 39958 774 40474 774.5 41145 775 40702 775.5 38790 776 38586 776.5 37067 777 37125 777.5 36885 778 35958 778.5 35881 779 35731 779.5 34884 780 35706 780.5 33990 781 34421 781.5 33641 782 32651 782.5 32200 783 33783 783.5 32388 784 32258 784.5 31698 785 31318 785.5 30643 786 30546 786.5 29860 787 30556 787.5 29308 788 29276 788.5 30226 789 31609 789.5 29718 790 30054 790.5 30998 791 30569 791.5 28296 792 28584 792.5 29873 793 28684 793.5 28310 794 30380 794.5 28117 795 27731 795.5 28716 796 28388 796.5 27766 797 27385 797.5 27901 798 28230 798.5 26446 799 26280 799.5 26474 800 26840