# Optical absorption spectrum of Zinc tetraphenylporphyrin, [ZnTPP] in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by R. W. Wagner in 1994 using a Cary 3. # The absorption values were collected using a spectral bandwidth of 1.0 nm, a signal averaging time of 0.133 sec, a data interval of 0.25 nm, and a scan rate of 112.5 nm/min. # # These measurements were scaled to make the molar extinction coefficient match # the value of 574000 cm-1/M at 422.8 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Barnett, G. H., M. F. Hudson and K. M. Smith (1975) Concerning meso-tetraphenylporphyrin purification. J. Chem. Soc. Perkin Trans. I 1401-1403. # ##Wavelength (nm) Molar Extinction (cm-1/M) 349.74 14096 349.99 15480 350.24 16563 350.49 14953 350.74 16097 350.99 15785 351.24 15114 351.49 15964 351.74 14659 351.99 14566 352.24 14207 352.49 15244 352.74 14978 352.99 14372 353.24 14756 353.49 13773 353.74 13884 353.99 14436 354.24 14953 354.49 15229 354.74 14519 354.99 15165 355.24 16183 355.49 15276 355.74 13235 355.99 13812 356.24 13048 356.49 14354 356.74 14408 356.99 13985 357.24 14476 357.49 14257 357.74 13762 357.99 13518 358.24 14196 358.49 14989 358.74 13561 358.99 14049 359.24 12500 359.49 12600 359.74 12790 359.99 13895 360.24 12087 360.49 13812 360.74 13461 360.99 13766 361.24 12568 361.49 12091 361.74 14429 361.99 12417 362.24 13009 362.49 13077 362.74 13389 362.99 12134 363.24 12302 363.49 11743 363.74 11531 363.99 11524 364.24 11553 364.49 12015 364.74 11029 364.99 12170 365.24 11685 365.49 12474 365.74 10947 365.99 11728 366.24 11144 366.49 12270 366.74 11187 366.99 12076 367.24 10943 367.49 11273 367.74 12205 367.99 12277 368.24 9863 368.49 12008 368.74 10043 368.99 10588 369.24 10950 369.49 9375 369.74 10498 369.99 9616 370.24 10233 370.49 11051 370.74 10498 370.99 10412 371.24 9490 371.49 11750 371.74 10243 371.99 9942 372.24 10480 372.49 9702 372.74 10401 372.99 9343 373.24 8834 373.49 9419 373.74 10358 373.99 9799 374.24 9501 374.49 10330 374.74 9472 374.99 9121 375.24 8687 375.49 10512 375.74 9526 375.99 8798 376.24 8985 376.49 9132 376.74 9139 376.99 9806 377.24 8507 377.49 9307 377.74 9713 377.99 10290 378.24 8988 378.49 10617 378.74 10778 378.99 10534 379.24 9985 379.49 10391 379.74 9842 379.99 10724 380.24 10469 380.49 9454 380.74 11391 380.99 10308 381.24 9562 381.49 10649 381.74 9870 381.99 11406 382.24 10997 382.49 9680 382.74 10154 382.99 10563 383.24 10233 383.49 10168 383.74 10093 383.99 10990 384.24 10412 384.49 9845 384.74 10882 384.99 10118 385.24 10803 385.49 12066 385.74 10950 385.99 10954 386.24 10520 386.49 11047 386.74 11947 386.99 11470 387.24 12155 387.49 12535 387.74 11915 387.99 11477 388.24 12378 388.49 13805 388.74 12765 388.99 12819 389.24 14289 389.49 14820 389.74 15240 389.99 14580 390.24 15136 390.49 15315 390.74 16054 390.99 16305 391.24 16248 391.49 16452 391.74 17998 391.99 19107 392.24 20663 392.49 21205 392.74 21302 392.99 22220 393.24 21524 393.49 24548 393.74 24806 393.99 25294 394.24 26700 394.49 27887 394.74 29548 394.99 29429 395.24 31252 395.49 33601 395.74 32891 395.99 34021 396.24 36678 396.49 37790 396.74 38569 396.99 38622 397.24 40796 397.49 40211 397.74 42428 397.99 43404 398.24 44641 398.49 45531 398.74 44996 398.99 47787 399.24 47138 399.49 47360 399.74 48651 399.99 48282 400.24 49408 400.49 49544 400.74 49290 400.99 50075 401.24 51316 401.49 52339 401.74 50559 401.99 51087 402.24 50638 402.49 51460 402.74 51033 402.99 51305 403.24 50807 403.49 51549 403.74 50638 403.99 52866 404.24 51779 404.49 51865 404.74 51169 404.99 52475 405.24 51940 405.49 52342 405.74 52432 405.99 52012 406.24 53275 406.49 54638 406.74 55405 406.99 57009 407.24 56779 407.49 58350 407.74 61051 407.99 61133 408.24 62973 408.49 66420 408.74 67170 408.99 69258 409.24 73278 409.49 75904 409.74 79731 409.99 82873 410.24 86715 410.49 90355 410.74 95538 410.99 99993 411.24 104462 411.49 111335 411.74 117766 411.99 123440 412.24 131288 412.49 139846 412.74 145865 412.99 156037 413.24 165194 413.49 175284 413.74 184969 413.99 196020 414.24 206303 414.49 216077 414.74 217759 414.99 224897 415.24 237358 415.49 250468 415.74 264327 415.99 278477 416.24 294894 416.49 309586 416.74 325386 416.99 339676 417.24 355630 417.49 371265 417.74 386412 417.99 402915 418.24 418747 418.49 435197 418.74 449275 418.99 462399 419.24 476323 419.49 491015 419.74 502772 419.99 512658 420.24 523745 420.49 531471 420.74 541277 420.99 547497 421.24 554946 421.49 559265 421.74 564799 421.99 567719 422.24 568752 422.49 569850 422.74 574000 422.99 572741 423.24 572572 423.49 569480 423.74 564742 423.99 560061 424.24 555872 424.49 549014 424.74 538300 424.99 531987 425.24 522256 425.49 507561 425.74 494946 425.99 480764 426.24 467356 426.49 451961 426.74 434555 426.99 417273 427.24 398012 427.49 381254 427.74 361168 427.99 344296 428.24 325931 428.49 306028 428.74 288754 428.99 270296 429.24 254808 429.49 236996 429.74 221648 429.99 207727 430.24 192404 430.49 178286 430.74 166271 430.99 152415 431.24 142594 431.49 130890 431.74 120417 431.99 111880 432.24 103483 432.49 95484 432.74 87898 432.99 81030 433.24 74814 433.49 68669 433.74 63651 433.99 57597 434.24 53092 434.49 50746 434.74 45864 434.99 41886 435.24 37263 435.49 33662 435.74 31356 435.99 27665 436.24 25584 436.49 24627 436.74 22392 436.99 20649 437.24 19426 437.49 17919 437.74 16911 437.99 16201 438.24 15462 438.49 13472 438.74 13827 438.99 12521 439.24 12370 439.49 12916 439.74 11054 439.99 10437 440.24 9910 440.49 8414 440.74 10430 440.99 8938 441.24 8131 441.49 8482 441.74 8482 441.99 6879 442.24 6542 442.49 7173 442.74 6323 442.99 6592 443.24 6818 443.49 5391 443.74 6144 443.99 5258 444.24 5591 444.49 5796 444.74 5186 444.99 5566 445.24 4479 445.49 4522 445.74 5078 445.99 4239 446.24 5028 446.49 5251 446.74 4121 446.99 4289 447.24 3497 447.49 4530 447.74 3780 447.99 3909 448.24 3400 448.49 3540 448.74 3963 448.99 3805 449.24 3891 449.49 3181 449.74 2815 449.99 3482 450.24 2794 450.49 4053 450.74 3002 450.99 2912 451.24 2736 451.49 2761 451.74 2173 451.99 2625 452.24 2033 452.49 1538 452.74 1861 452.99 2216 453.24 2317 453.49 1761 453.74 2650 453.99 2352 454.24 1244 454.49 1721 454.74 2388 454.99 1592 455.24 1857 455.49 1990 455.74 1524 455.99 1474 456.24 1434 456.49 1513 456.74 1685 456.99 1169 457.24 1599 457.49 1058 457.74 1119 457.99 1797 458.24 1527 458.49 1800 458.74 1728 458.99 1854 459.24 1129 459.49 1495 459.74 1969 459.99 1545 460.24 1825 460.49 1632 460.74 1696 460.99 1452 461.24 1771 461.49 1162 461.74 1115 461.99 1137 462.24 1058 462.49 1725 462.74 1599 462.99 1545 463.24 2015 463.49 1779 463.74 1119 463.99 1994 464.24 1861 464.49 1488 464.74 1302 464.99 1951 465.24 1474 465.49 928 465.74 1520 465.99 2152 466.24 1431 466.49 1499 466.74 1151 466.99 1180 467.24 1743 467.49 1373 467.74 1961 467.99 1775 468.24 1391 468.49 1585 468.74 1574 468.99 2044 469.24 1581 469.49 972 469.74 2080 469.99 1822 470.24 1413 470.49 1241 470.74 1603 470.99 1779 471.24 2503 471.49 1739 471.74 1388 471.99 2715 472.24 1183 472.49 1757 472.74 1883 472.99 1592 473.24 1603 473.49 1606 473.74 1818 473.99 2313 474.24 2137 474.49 2037 474.74 2105 474.99 2381 475.24 1560 475.49 1875 475.74 3045 475.99 2069 476.24 1926 476.49 2019 476.74 2525 476.99 1750 477.24 2582 477.49 1664 477.74 2500 477.99 2284 478.24 2600 478.49 2270 478.74 2464 478.99 2865 479.24 2417 479.49 2546 479.74 2647 479.99 2331 480.24 2977 480.49 2259 480.74 2507 480.99 3249 481.24 2270 481.49 3206 481.74 2675 481.99 2729 482.24 2198 482.49 2496 482.74 2126 482.99 2966 483.24 3120 483.49 2614 483.74 3170 483.99 2751 484.24 2833 484.49 2668 484.74 2740 484.99 2704 485.24 2991 485.49 2148 485.74 2119 485.99 2184 486.24 2471 486.49 3246 486.74 2923 486.99 2338 487.24 2281 487.49 1922 487.74 3633 487.99 3070 488.24 2227 488.49 2338 488.74 2381 488.99 1951 489.24 2324 489.49 2474 489.74 2969 489.99 2937 490.24 3332 490.49 2604 490.74 2055 490.99 2697 491.24 2621 491.49 2937 491.74 3414 491.99 1883 492.24 2675 492.49 2697 492.74 3027 492.99 2553 493.24 2177 493.49 2521 493.74 2266 493.99 2385 494.24 3192 494.49 2510 494.74 3116 494.99 2801 495.24 2234 495.49 2281 495.74 2808 495.99 3174 496.24 2944 496.49 3113 496.74 3328 496.99 2650 497.24 3378 497.49 3048 497.74 3310 497.99 3145 498.24 3314 498.49 2747 498.74 3364 498.99 3848 499.24 3368 499.49 2772 499.74 3715 499.99 3235 500.24 3837 500.49 2855 500.74 3525 500.99 4024 501.24 3927 501.49 3550 501.74 3748 501.99 3547 502.24 3766 502.49 3321 502.74 3877 502.99 3497 503.24 2873 503.49 3977 503.74 4203 503.99 3407 504.24 4056 504.49 4878 504.74 4096 504.99 4002 505.24 3859 505.49 4257 505.74 3633 505.99 4268 506.24 4311 506.49 4282 506.74 3906 506.99 4218 507.24 3895 507.49 4566 507.74 3665 507.99 4397 508.24 4458 508.49 4566 508.74 4573 508.99 4447 509.24 3995 509.49 4673 509.74 4110 509.99 4203 510.24 4182 510.49 4497 510.74 3949 510.99 5100 511.24 4279 511.49 4616 511.74 4210 511.99 4164 512.24 4792 512.49 4103 512.74 4655 512.99 4852 513.24 4365 513.49 4939 513.74 4616 513.99 4989 514.24 4996 514.49 4429 514.74 4314 514.99 4766 515.24 4383 515.49 3898 515.74 4236 515.99 3891 516.24 4132 516.49 4497 516.74 4038 516.99 4178 517.24 4505 517.49 4795 517.74 3898 517.99 4788 518.24 3941 518.49 5039 518.74 2937 518.99 4526 519.24 3848 519.49 4078 519.74 4655 519.99 4472 520.24 4361 520.49 4580 520.74 4078 520.99 4906 521.24 4246 521.49 3949 521.74 4142 521.99 3963 522.24 4203 522.49 4085 522.74 3773 522.99 4071 523.24 4322 523.49 4286 523.74 4365 523.99 4784 524.24 3676 524.49 4404 524.74 4842 524.99 4347 525.24 4404 525.49 4623 525.74 5172 525.99 5200 526.24 4924 526.49 4992 526.74 4949 526.99 5215 527.24 5660 527.49 5760 527.74 5236 527.99 5545 528.24 5692 528.49 5588 528.74 5781 528.99 5179 529.24 6033 529.49 6829 529.74 6929 529.99 5792 530.24 7320 530.49 7510 530.74 7162 530.99 7535 531.24 7553 531.49 8213 531.74 7966 531.99 8149 532.24 8418 532.49 9630 532.74 8267 532.99 8411 533.24 9221 533.49 10014 533.74 10258 533.99 10602 534.24 10566 534.49 10846 534.74 11266 534.99 10731 535.24 11710 535.49 11599 535.74 12037 535.99 12683 536.24 12865 536.49 13350 536.74 12941 536.99 13533 537.24 14842 537.49 14447 537.74 14853 537.99 15857 538.24 16112 538.49 16126 538.74 16800 538.99 17475 539.24 17783 539.49 18088 539.74 19024 539.99 18877 540.24 18604 540.49 19698 540.74 20326 540.99 21079 541.24 20739 541.49 21958 541.74 22130 541.99 22428 542.24 22959 542.49 23235 542.74 22783 542.99 24985 543.24 23561 543.49 24810 543.74 25172 543.99 25383 544.24 26309 544.49 25635 544.74 27120 544.99 26911 545.24 27331 545.49 28020 545.74 28282 545.99 28522 546.24 27966 546.49 28802 546.74 28902 546.99 29164 547.24 29584 547.49 29698 547.74 29921 547.99 29616 548.24 30201 548.49 30158 548.74 29845 548.99 30430 549.24 29630 549.49 29566 549.74 29695 549.99 29508 550.24 29806 550.49 30028 550.74 29914 550.99 29681 551.24 29659 551.49 29049 551.74 28712 551.99 28422 552.24 28407 552.49 28070 552.74 27277 552.99 27241 553.24 26929 553.49 26990 553.74 25649 553.99 25122 554.24 25097 554.49 25079 554.74 24125 554.99 23490 555.24 23418 555.49 22105 555.74 21937 555.99 22145 556.24 20857 556.49 19975 556.74 19817 556.99 19720 557.24 18332 557.49 18461 557.74 17801 557.99 18662 558.24 17948 558.49 16244 558.74 16721 558.99 16398 559.24 15957 559.49 15706 559.74 15114 559.99 14193 560.24 14566 560.49 13952 560.74 13540 560.99 12930 561.24 12733 561.49 12145 561.74 11660 561.99 11119 562.24 11284 562.49 10825 562.74 10312 562.99 10810 563.24 10333 563.49 9433 563.74 9307 563.99 8891 564.24 8658 564.49 8307 564.74 8231 564.99 8278 565.24 8016 565.49 8594 565.74 7697 565.99 6893 566.24 6689 566.49 7639 566.74 5972 566.99 6276 567.24 6212 567.49 6406 567.74 6291 567.99 5925 568.24 5774 568.49 5581 568.74 5233 568.99 4587 569.24 5125 569.49 4566 569.74 4637 569.99 4332 570.24 3920 570.49 4695 570.74 3755 570.99 4261 571.24 3981 571.49 4002 571.74 3647 571.99 3748 572.24 3529 572.49 3099 572.74 4228 572.99 3443 573.24 3206 573.49 3762 573.74 3238 573.99 4304 574.24 2984 574.49 2855 574.74 3866 574.99 3321 575.24 2736 575.49 3170 575.74 3303 575.99 2926 576.24 3066 576.49 3385 576.74 3507 576.99 3959 577.24 2948 577.49 3142 577.74 3576 577.99 2593 578.24 3023 578.49 3414 578.74 3601 578.99 3353 579.24 3328 579.49 3224 579.74 2783 579.99 3454 580.24 3511 580.49 3662 580.74 3536 580.99 3411 581.24 2858 581.49 3931 581.74 4332 581.99 3859 582.24 4178 582.49 3608 582.74 4178 582.99 4591 583.24 3579 583.49 4709 583.74 4379 583.99 5139 584.24 3884 584.49 4522 584.74 4827 584.99 5028 585.24 5075 585.49 4210 585.74 4931 585.99 4888 586.24 4860 586.49 4383 586.74 4802 586.99 4426 587.24 4713 587.49 4429 587.74 5096 587.99 5111 588.24 4870 588.49 4799 588.74 5172 588.99 4261 589.24 4992 589.49 4856 589.74 5175 589.99 5111 590.24 4426 590.49 5071 590.74 4343 590.99 4716 591.24 4881 591.49 3683 591.74 5061 591.99 4282 592.24 4580 592.49 3945 592.74 3999 592.99 3949 593.24 3698 593.49 3712 593.74 4167 593.99 3723 594.24 2894 594.49 3665 594.74 3048 594.99 2349 595.24 2593 595.49 2507 595.74 3281 595.99 3195 596.24 2725 596.49 2926 596.74 1940 596.99 1786 597.24 1779 597.49 2460 597.74 2166 597.99 2187 598.24 1495 598.49 1603 598.74 2456 598.99 1438 599.24 1474 599.49 1811 599.74 1416 599.99 1904 600.24 1172 600.49 1954 600.74 1761 600.99 1624 601.24 1789 601.49 1104 601.74 814 601.99 1642 602.24 538 602.49 1291 602.74 1574 602.99 853 603.24 1800 603.49 997 603.74 1079 603.99 778 604.24 1649 604.49 1208 604.74 860 604.99 821 605.24 412 605.49 1423 605.74 1108 605.99 1058 606.24 1137 606.49 319 606.74 652 606.99 817 607.24 1531 607.49 1165 607.74 304 607.99 581 608.24 1384 608.49 491 608.74 1244 608.99 35 609.24 763 609.49 541 609.74 -43 609.99 -46 610.24 -261 610.49 405 610.74 -225 610.99 835 611.24 441 611.49 606 611.74 444 611.99 911 612.24 -82 612.49 -426 612.74 785 612.99 -251 613.24 416 613.49 347 613.74 774 613.99 530 614.24 -200 614.49 469 614.74 710 614.99 853 615.24 -455 615.49 -774 615.74 523 615.99 -21 616.24 599 616.49 455 616.74 118 616.99 308 617.24 168 617.49 333 617.74 408 617.99 803 618.24 1065 618.49 344 618.74 810 618.99 312 619.24 620 619.49 781 619.74 236 619.99 1262 620.24 1097 620.49 -695 620.74 218 620.99 552 621.24 53 621.49 807 621.74 390 621.99 416 622.24 455 622.49 860 622.74 595 622.99 -104 623.24 175 623.49 466 623.74 111 623.99 763 624.24 828 624.49 914 624.74 1000 624.99 602 625.24 1334 625.49 -193 625.74 308 625.99 1061 626.24 710 626.49 247 626.74 638 626.99 390 627.24 946 627.49 -60 627.74 792 627.99 -93 628.24 -121 628.49 1025 628.74 423 628.99 645 629.24 868 629.49 946 629.74 1707 629.99 853 630.24 1029 630.49 993 630.74 423 630.99 -477 631.24 555 631.49 337 631.74 523 631.99 573 632.24 -93 632.49 164 632.74 724 632.99 276 633.24 430 633.49 477 633.74 283 633.99 1248 634.24 487 634.49 401 634.74 -251 634.99 1215 635.24 1215 635.49 1133 635.74 1029 635.99 624 636.24 1133 636.49 552 636.74 1033 636.99 896 637.24 408 637.49 577 637.74 1162 637.99 25 638.24 832 638.49 430 638.74 175 638.99 824 639.24 358 639.49 401 639.74 735 639.99 441 640.24 416 640.49 175 640.74 -455 640.99 50 641.24 279 641.49 139 641.74 695 641.99 903 642.24 613 642.49 -35 642.74 1187 642.99 548 643.24 -21 643.49 703 643.74 799 643.99 154 644.24 32 644.49 552 644.74 1033 644.99 419 645.24 1101 645.49 -746 645.74 -297 645.99 175 646.24 821 646.49 -82 646.74 322 646.99 251 647.24 -193 647.49 -376 647.74 455 647.99 -100 648.24 900 648.49 340 648.74 78 648.99 -35 649.24 75 649.49 190 649.74 -469 649.99 -1169 650.24 283 650.49 243 650.74 -86 650.99 340 651.24 304 651.49 337 651.74 993 651.99 839 652.24 491 652.49 -717 652.74 -172 652.99 114 653.24 32 653.49 -104 653.74 444 653.99 68 654.24 -875 654.49 319 654.74 -380 654.99 1291 655.24 -376 655.49 502 655.74 -179 655.99 258 656.24 279 656.49 -333 656.74 -208 656.99 -466 657.24 376 657.49 -502 657.74 -373 657.99 -746 658.25 -451 658.5 444 658.75 136 659 652 659.25 652 659.5 355 659.75 968 660 -875 660.25 -570 660.5 -129 660.75 -272 661 -204 661.25 -222 661.5 -190 661.75 -243 662 340 662.25 104 662.5 182 662.75 -104 663 599 663.25 -3 663.5 21 663.75 -279 664 315 664.25 484 664.5 620 664.75 279 665 692 665.25 -563 665.5 143 665.75 -616 666 -168 666.25 -329 666.5 918 666.75 347 667 -412 667.25 437 667.5 304 667.75 32 668 -1682 668.25 193 668.5 710 668.75 -1018 669 -100 669.25 609 669.5 416 669.75 -1036 670 674 670.25 616 670.5 32 670.75 509 671 -638 671.25 412 671.5 663 671.75 -677 672 -254 672.25 -315 672.5 272 672.75 -1258 673 -279 673.25 -362 673.5 -624 673.75 -204 674 -57 674.25 921 674.5 1079 674.75 419 675 286 675.25 1137 675.5 720 675.75 -1481 676 -78 676.25 211 676.5 -430 676.75 -555 677 1255 677.25 642 677.5 803 677.75 225 678 -401 678.25 -218 678.5 -315 678.75 505 679 107 679.25 -638 679.5 32 679.75 233 680 14 680.25 294 680.5 645 680.75 408 681 -286 681.25 243 681.5 -444 681.75 -1 682 -286 682.25 710 682.5 -175 682.75 -609 683 -240 683.25 301 683.5 555 683.75 118 684 -667 684.25 -441 684.5 738 684.75 39 685 480 685.25 -111 685.5 251 685.75 -416 686 236 686.25 0 686.5 236 686.75 32 687 437 687.25 821 687.5 290 687.75 602 688 -792 688.25 559 688.5 308 688.75 -487 689 -17 689.25 -272 689.5 -477 689.75 100 690 401 690.25 154 690.5 -448 690.75 -810 691 -376 691.25 -634 691.5 -484 691.75 430 692 -835 692.25 394 692.5 742 692.75 -437 693 408 693.25 -1305 693.5 -882 693.75 -946 694 -412 694.25 53 694.5 -254 694.75 35 695 -717 695.25 161 695.5 -333 695.75 -32 696 64 696.25 -286 696.5 -344 696.75 -423 697 279 697.25 -997 697.5 -243 697.75 -606 698 125 698.25 190 698.5 -390 698.75 215 699 -240 699.25 -405 699.5 -136 699.75 7 700 82