# Emission spectrum of in 0.05 M H2SO4 # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on in the summer of 1995 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 320 -384 320.5 -377 321 -434 321.5 -398 322 -513 322.5 -415 323 -339 323.5 -349 324 -512 324.5 -358 325 -423 325.5 -387 326 -434 326.5 -372 327 -435 327.5 -478 328 -383 328.5 -457 329 -402 329.5 -517 330 -525 330.5 -343 331 -471 331.5 -604 332 -424 332.5 -463 333 -418 333.5 -527 334 -430 334.5 -490 335 -471 335.5 -534 336 -484 336.5 -494 337 -373 337.5 -400 338 -332 338.5 -122 339 30 339.5 369 340 653 340.5 1199 341 1812 341.5 2838 342 3580 342.5 4581 343 5325 343.5 6481 344 7347 344.5 7785 345 8449 345.5 8922 346 8651 346.5 8475 347 7941 347.5 6798 348 6065 348.5 5106 349 4227 349.5 3058 350 2345 350.5 1481 351 1001 351.5 565 352 381 352.5 119 353 -77 353.5 -52 354 -113 354.5 -91 355 -72 355.5 -107 356 -88 356.5 -95 357 -154 357.5 -63 358 -80 358.5 -69 359 -23 359.5 82 360 85 360.5 173 361 190 361.5 294 362 469 362.5 597 363 605 363.5 828 364 807 364.5 1045 365 1181 365.5 1477 366 1666 366.5 2020 367 2237 367.5 2562 368 2699 368.5 3191 369 3632 369.5 4125 370 4560 370.5 5055 371 5813 371.5 6561 372 7302 372.5 8110 373 8636 373.5 9701 374 10189 374.5 11724 375 12697 375.5 14509 376 15564 376.5 17311 377 18921 377.5 21515 378 22641 378.5 25394 379 27384 379.5 30787 380 32567 380.5 36452 381 38750 381.5 43013 382 45566 382.5 50896 383 54056 383.5 60549 384 62833 384.5 69167 385 73233 385.5 81502 386 85984 386.5 93137 387 99430 387.5 108972 388 114192 388.5 123429 389 130276 389.5 140712 390 146821 390.5 157318 391 164312 391.5 176783 392 184541 392.5 195341 393 204424 393.5 218331 394 227400 394.5 240044 395 249191 395.5 265208 396 274462 396.5 288697 397 299168 397.5 315432 398 324862 398.5 340353 399 352655 399.5 372831 400 383407 400.5 400625 401 412612 401.5 432708 402 442267 402.5 462231 403 475652 403.5 499638 404 510840 404.5 533342 405 544180 405.5 574327 406 586583 406.5 612839 407 627763 407.5 657802 408 670640 408.5 696757 409 712016 409.5 745356 410 756754 410.5 781933 411 801540 411.5 828561 412 841259 412.5 862621 413 881352 413.5 903924 414 917750 414.5 940190 415 955456 415.5 982060 416 993487 416.5 1017099 417 1034032 417.5 1056864 418 1069623 418.5 1095835 419 1104922 419.5 1130182 420 1143923 420.5 1168024 421 1180250 421.5 1207616 422 1218026 422.5 1242346 423 1254818 423.5 1275185 424 1287402 424.5 1310836 425 1325955 425.5 1346968 426 1358611 426.5 1382626 427 1388892 427.5 1407897 428 1425589 428.5 1442176 429 1457206 429.5 1477762 430 1483780 430.5 1508180 431 1511974 431.5 1530889 432 1540629 432.5 1557654 433 1568740 433.5 1585475 434 1588019 434.5 1602396 435 1611198 435.5 1627607 436 1628520 436.5 1644444 437 1652395 437.5 1661937 438 1665075 438.5 1672702 439 1677834 439.5 1694231 440 1695192 440.5 1699958 441 1706900 441.5 1716996 442 1723759 442.5 1726060 443 1737296 443.5 1737599 444 1741923 444.5 1748324 445 1756194 445.5 1757279 446 1763035 446.5 1768106 447 1765968 447.5 1766696 448 1769996 448.5 1772455 449 1773129 449.5 1769854 450 1776978 450.5 1774446 451 1773421 451.5 1768763 452 1773168 452.5 1771424 453 1769058 453.5 1765048 454 1764365 454.5 1761605 455 1762848 455.5 1758096 456 1750403 456.5 1746692 457 1745029 457.5 1735104 458 1735039 458.5 1729283 459 1724250 459.5 1714990 460 1712560 460.5 1709699 461 1702578 461.5 1697784 462 1689273 462.5 1686646 463 1681550 463.5 1671861 464 1666209 464.5 1661720 465 1659089 465.5 1646319 466 1646390 466.5 1638187 467 1630936 467.5 1622607 468 1616432 468.5 1605455 469 1598248 469.5 1590227 470 1586331 470.5 1577200 471 1570191 471.5 1560968 472 1556151 472.5 1543017 473 1540507 473.5 1527355 474 1520890 474.5 1510440 475 1503814 475.5 1492424 476 1486330 476.5 1471570 477 1464468 477.5 1446506 478 1440087 478.5 1427926 479 1419442 479.5 1402809 480 1395474 480.5 1381755 481 1368358 481.5 1357845 482 1352625 482.5 1335954 483 1327092 483.5 1317355 484 1308088 484.5 1295252 485 1287988 485.5 1275934 486 1267697 486.5 1258552 487 1242152 487.5 1234405 488 1228276 488.5 1214561 489 1206907 489.5 1194748 490 1184599 490.5 1175862 491 1167822 491.5 1155068 492 1149229 492.5 1134808 493 1126909 493.5 1113425 494 1110525 494.5 1097686 495 1089682 495.5 1076248 496 1071080 496.5 1059581 497 1053469 497.5 1036086 498 1033113 498.5 1016940 499 1007957 499.5 995939 500 987206 500.5 976823 501 969370 501.5 952022 502 948247 502.5 936481 503 928109 503.5 915217 504 905335 504.5 894459 505 885018 505.5 871770 506 866235 506.5 857396 507 847425 507.5 833166 508 828492 508.5 821286 509 809167 509.5 799582 510 795803 510.5 783127 511 776641 511.5 766570 512 760685 512.5 749775 513 746528 513.5 731677 514 730564 514.5 718032 515 712826 515.5 698939 516 696440 516.5 685043 517 679177 517.5 670848 518 666358 518.5 656796 519 651878 519.5 641599 520 638577 520.5 628872 521 623069 521.5 612563 522 608963 522.5 598653 523 594054 523.5 584136 524 579025 524.5 571377 525 565046 525.5 556029 526 551939 526.5 541026 527 539468 527.5 526559 528 522828 528.5 516337 529 509109 529.5 501939 530 495614 530.5 490577 531 482335 531.5 475389 532 470338 532.5 465247 533 459710 533.5 452514 534 448658 534.5 440999 535 437297 535.5 430455 536 426261 536.5 421696 537 418534 537.5 409330 538 406822 538.5 401549 539 396513 539.5 390566 540 387403 540.5 381373 541 376154 541.5 370133 542 368921 542.5 362390 543 359038 543.5 351518 544 350125 544.5 343759 545 341919 545.5 334220 546 332562 546.5 326942 547 322455 547.5 317228 548 314826 548.5 309882 549 306945 549.5 301881 550 298185 550.5 293786 551 288630 551.5 284632 552 283840 552.5 279428 553 274564 553.5 270017 554 268456 554.5 263712 555 258769 555.5 253946 556 253393 556.5 249178 557 246203 557.5 241851 558 240343 558.5 237434 559 234261 559.5 230408 560 227658 560.5 225486 561 222047 561.5 218617 562 217056 562.5 214097 563 211003 563.5 206479 564 205125 564.5 202963 565 199306 565.5 196344 566 194240 566.5 191183 567 189512 567.5 186106 568 185226 568.5 181427 569 179241 569.5 175725 570 175465 570.5 172603 571 170245 571.5 167948 572 166164 572.5 164067 573 160888 573.5 159294 574 156542 574.5 155566 575 152212 575.5 150384 576 148368 576.5 146152 577 144422 577.5 142562 578 139778 578.5 138264 579 137073 579.5 133956 580 133122 580.5 131586 581 128759 581.5 127157 582 126211 582.5 123504 583 123111 583.5 120224 584 118708 584.5 116956 585 115457 585.5 114212 586 112730 586.5 111118 587 109921 587.5 108313 588 106309 588.5 105285 589 104010 589.5 102023 590 101218 590.5 99755 591 98131 591.5 96527 592 95143 592.5 94652 593 93821 593.5 92118 594 89590 594.5 89099 595 88238 595.5 86436 596 85681 596.5 84399 597 83869 597.5 81251 598 81158 598.5 79543 599 79310 599.5 77536 600 76759