# Emission spectrum of in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on on 12-11-1997 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 550 2021 551 2228 552 2184 553 2265 554 2597 555 2890 556 3363 557 4016 558 4804 559 5642 560 6766 561 7884 562 8724 563 9486 564 10322 565 11120 566 12589 567 14059 568 15717 569 17447 570 18939 571 19421 572 21032 573 21408 574 22447 575 23160 576 23986 577 25367 578 26317 579 27222 580 29112 581 29561 582 30499 583 31498 584 32379 585 34727 586 37095 587 39984 588 43171 589 45726 590 48960 591 49009 592 49353 593 49364 594 49118 595 50031 596 52576 597 56583 598 64648 599 74583 600 90350 601 108503 602 133609 603 157966 604 183973 605 211485 606 243786 607 282691 608 330569 609 399178 610 499068 611 616961 612 784925 613 954126 614 1136711 615 1270191 616 1370004 617 1389650 618 1331927 619 1226651 620 1075787 621 930746 622 772633 623 650726 624 545975 625 467131 626 415155 627 385576 628 363171 629 347540 630 329938 631 311188 632 293056 633 271807 634 254159 635 242148 636 235904 637 240197 638 253607 639 273899 640 310182 641 350096 642 397514 643 440711 644 481409 645 516582 646 543013 647 563907 648 582855 649 605142 650 638589 651 681995 652 737408 653 798378 654 859609 655 910310 656 959959 657 1000135 658 1029209 659 1061030 660 1090933 661 1131820 662 1175066 663 1227842 664 1292147 665 1372191 666 1469097 667 1579992 668 1694185 669 1826154 670 1963470 671 2076404 672 2187243 673 2266882 674 2323469 675 2375050 676 2443652 677 2521743 678 2636277 679 2769717 680 2924571 681 3063474 682 3165590 683 3211527 684 3170262 685 3043590 686 2832151 687 2610817 688 2338300 689 2075645 690 1795502 691 1601777 692 1409270 693 1254831 694 1123216 695 1033905 696 944968 697 871749 698 813731 699 753237 700 691576 701 631122 702 569642 703 513397 704 462017 705 414034 706 368691 707 330594 708 302361 709 275288 710 256955 711 241960 712 228490 713 218792 714 210727 715 202616 716 199644 717 194331 718 189104 719 186125 720 182218 721 178932 722 170455 723 166405 724 160209 725 157070 726 152560 727 147333 728 144032 729 141580 730 142063 731 142244 732 141412 733 139645 734 136210 735 135194 736 136978 737 136096 738 135489 739 137309 740 133877 741 132441 742 134797 743 129175 744 131946 745 127065 746 125577 747 122699 748 123055 749 121045 750 120767