# Emission spectrum of in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on on 06-25-1997 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 555 269843 556 287038 557 301831 558 314258 559 324569 560 341409 561 359413 562 388058 563 431256 564 498845 565 592210 566 718008 567 900627 568 1141609 569 1466188 570 1917508 571 2522309 572 3348988 573 4439311 574 5862229 575 7699607 576 9901777 577 12234620 578 14502280 579 16361840 580 17708490 581 18431170 582 18624200 583 18269360 584 17359860 585 16165130 586 14621640 587 12955150 588 11262840 589 9740855 590 8382265 591 7266171 592 6332396 593 5568210 594 4901998 595 4360440 596 3906444 597 3547106 598 3275796 599 3083476 600 2980128 601 2963352 602 3036745 603 3176153 604 3360622 605 3552755 606 3752551 607 3923115 608 4059149 609 4160564 610 4232794 611 4295229 612 4358635 613 4432785 614 4540882 615 4679012 616 4868760 617 5089453 618 5355076 619 5643178 620 5983917 621 6359929 622 6802471 623 7276225 624 7772841 625 8296524 626 8840263 627 9320689 628 9792576 629 10222030 630 10658220 631 11051010 632 11463300 633 11898740 634 12367620 635 12801090 636 13142470 637 13355440 638 13379930 639 13196480 640 12777350 641 12176700 642 11327220 643 10413210 644 9373190 645 8359206 646 7356592 647 6416837 648 5524658 649 4747431 650 4064291 651 3522315 652 3058142 653 2691850 654 2376570 655 2122737 656 1895605 657 1712223 658 1546808 659 1402993 660 1280289 661 1186801 662 1105837 663 1047320 664 993923 665 957764 666 924653 667 900735 668 881532 669 863319 670 848462 671 832176 672 816366 673 794721 674 775485 675 756063 676 738964 677 721658 678 707873 679 690853 680 681220 681 675632 682 664394 683 661649 684 652419 685 644857 686 641409 687 635868 688 630437 689 620171 690 611401 691 599071 692 584087 693 568261 694 551230 695 536848 696 514730 697 495225 698 476431 699 454864 700 438069